96227-91-7Relevant academic research and scientific papers
Diastereoselective Fluorocyclopropanation of Chiral Allylic Alcohols Using an α-Fluoroiodomethylzinc Carbenoid
Navuluri, Chandrasekhar,Charette, André B.
, p. 4288 - 4291 (2015)
Chiral fluorocyclopropyl carbinols were synthesized in high diastereoselectivities via a zinc mediated cyclopropanation reaction, using sec-allylic alcohols as simple building blocks. An enantioselective version of this transformation was achieved through
Effect of a proximal oxygen substituent on the efficacy of ruthenium-catalyzed cross-metathesis and RCM
Maishal, Tarun K,Sinha-Mahapatra, Dilip K,Paranjape, Kavita,Sarkar, Amitabha
, p. 2263 - 2267 (2007/10/03)
Ruthenium-catalyzed cross-metathesis of various derivatives of 1,2-dihydroxy-3-butene reveals that cyclic acetals are best suited as substrates compared to acyclic diethers or diacetates, while RCM is relatively insensitive to the presence of allylic or homoallylic hydroxy or acetoxy groups.
Synthesis and Reactivity of Novel ?-Allylcyclopentadienyl Cobaltolactone Complexes
Christie, Steven D. R.,Cosset, Christophe,Hamilton, David R.,Kerr, William J.,O'Callaghan, John M.
, p. 2051 - 2052 (2007/10/02)
A range of novel cobaltolactone complexes are prepared under photolytic conditions from dicarbonylcyclopentadienylcobalt and vinyl epoxides; their subsequent reactivity under a selected series of reaction conditions is described.
Stereoselective Syntheses of Alkenyl-Substituted 1,3-Dioxolanes or 4,7-Dihydro-1,3-dioxepins or an (E)-α,β-Unsaturated Aldehyde from (Z)-2-Butane-1,4-diols
Zweifel, George,Leung, Teresa,Najafi, M. Ramin,Najdi, Samir
, p. 2004 - 2006 (2007/10/02)
Treatment of (Z)-2-butene-1,4-diols with boron trifluoride etherate in acetone solvent affords stereodefined alkenyl-substituted 1,3-dioxolanes or 4,7-dihydro-1,3-dioxepins or an (E)-α,β-unsaturated aldehyde, depending on the reaction temperature and time
