96258-65-0

Basic information

• Product Name: Phosphonic acid, [(4-methylphenyl)[(trimethylsilyl)oxy]methyl]-, diethyl ester
• CAS NO: 96258-65-0
• Molecular Formula: C15H27O4PSi
• Molecular Weight: 330.436
• Mol File: 96258-65-0.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Phosphonic acid, [(4-methylphenyl)[(trimethylsilyl)oxy]methyl]-, diethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphonic acid, [(4-methylphenyl)[(trimethylsilyl)oxy]methyl]-, diethyl ester(96258-65-0)
• EPA Substance Registry System: Phosphonic acid, [(4-methylphenyl)[(trimethylsilyl)oxy]methyl]-, diethyl ester(96258-65-0)

Safety Data

• Hazardous Substances Data: 96258-65-0(Hazardous Substances Data)

Upstream product

• 104-87-0 4-methyl-benzaldehyde 
• 13716-45-5 diethyl trimethylsilyl phosphite 
• 107134-90-7 1-<(4-Methylphenyl)(trimethylsilyloxy)methyl>pyridinium-trifluormethansulfonat 
• 122-52-1 triethyl phosphite 
• 79158-40-0 diethyl hydroxy(p-tolyl)methylphosphonate 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 

Downstream Products

• 2942-54-3 diethyl (4-methylbenzoyl)phosphonate 
• 79158-40-0 diethyl hydroxy(p-tolyl)methylphosphonate 
• 96258-46-7 Methanesulfonic acid (diethoxy-phosphoryl)-p-tolyl-methyl ester 

Relevant articles and documents

A convenient and mild protocol for preparation of α – trimethylsilyloxyphosphonates using sulfamic acid and their oxidation to α – ketophosphonates in the presence of N-bromosuccinimide

A convenient and mild protocol was developed for the trimethylsilylation of α-hydroxyphosphonates using hexamethyldisilazane as the silylating agent in the presence of sulfamic acid (SA) as a heterogeneous solid acid catalyst in dichloromethane as the rea

Aluminium triflate [Al(OTf)3] as a recyclable catalyst for the conversion of α-hydroxyphosphonates, alcohols and phenols to their corresponding O-silylated products with hexamethyldisilazane (HMDS)

Al(OTf)3 as a recyclable catalyst conducts the efficient conversion of various types of α-hydroxyphosphonates to their corresponding α-trimethysilyloxyphosphonates with HMDS in the absence of solvent at room temperature. The general applicabili

Copper triflate [Cu(OTf)2] is an efficient and mild catalyst for the silylation of α-hydroxyphosphonates to α-trimethylsilyloxyphosphonates with HMDS at room temperature

A broad, adaptable, high yielding and convenient procedure for the fast conversion of various α-hydroxyphosphonates to α-trimethylsilyloxyphosphonates under mild conditions with HMDS in the presence of a catalytic amount of copper triflate is described. T