96720-10-4

Basic information

• Product Name: [(2R,4S)-4-(tert-Butyl-diphenyl-silanyloxy)-tetrahydro-furan-2-yl]-acetic acid ethyl ester
• Synonyms: [(2R,4S)-4-(tert-Butyl-diphenyl-silanyloxy)-tetrahydro-furan-2-yl]-acetic acid ethyl ester
• CAS NO: 96720-10-4
• Molecular Weight: 412.601
• Mol File: 96720-10-4.mol

Chemical Properties

• CAS DataBase Reference: [(2R,4S)-4-(tert-Butyl-diphenyl-silanyloxy)-tetrahydro-furan-2-yl]-acetic acid ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: [(2R,4S)-4-(tert-Butyl-diphenyl-silanyloxy)-tetrahydro-furan-2-yl]-acetic acid ethyl ester(96720-10-4)
• EPA Substance Registry System: [(2R,4S)-4-(tert-Butyl-diphenyl-silanyloxy)-tetrahydro-furan-2-yl]-acetic acid ethyl ester(96720-10-4)

Safety Data

• Hazardous Substances Data: 96720-10-4(Hazardous Substances Data)

Upstream product

• 96720-09-1 ethyl 6-<(tert-butyldiphenylsilyl)oxy>-5(S,E)-hydroxy-2-hexenoate 
• 96733-91-4 [(2S,4S)-4-(tert-Butyl-diphenyl-silanyloxy)-tetrahydro-furan-2-yl]-acetic acid ethyl ester 
• 106401-45-0 (R)-[(2R,4S)-4-(tert-Butyl-diphenyl-silanyloxy)-tetrahydro-furan-2-yl]-iodo-acetic acid ethyl ester 
• 106358-11-6 ethyl-2-<(2R,4S)(4-hydroxytetrahydrofuran-2-yl)>-2(R)-iodoacetate 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 96720-08-0 ethyl (S,E)-5,6-dihydroxy-2-hexenoate 
• 96720-07-9 (E)-ethyl 4-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)but-2-enoate 

Downstream Products

• 106346-61-6 [(2R,4S)-4-(tert-Butyl-diphenyl-silanyloxy)-tetrahydro-furan-2-yl]-acetaldehyde 
• 96720-11-5 (3R,5S)-6-Bromo-5-(tert-butyl-diphenyl-silanyloxy)-3-hydroxy-hexanoic acid ethyl ester 
• 90761-31-2 7-(2,4-Dichlorophenyl)-D-erythro-3-hydroxy-5-heptanolide 
• 96720-12-6 (3R,5S)-6-Bromo-5-(tert-butyl-diphenyl-silanyloxy)-3-methoxymethoxy-hexanoic acid ethyl ester 
• 96720-14-8 (3R,5R)-7-(2,4-Dichloro-phenyl)-5-hydroxy-3-methoxymethoxy-heptanoic acid ethyl ester 
• 96720-15-9 6(R)-[2-(2,4-dichlorophenyl)ethyl]-4(R)-(methoxymethoxy)tetrahydro-2H-pyran-2-one 
• 106346-62-7 5-[(2S,4S)-4-(tert-Butyl-diphenyl-silanyloxy)-tetrahydro-furan-2-yl]-pentan-2-one 

Relevant articles and documents

SYNTHETIC UTILITY OF CHIRAL TETRAHYDROFURANS: PREPARATION OF (1R,3R,5S)-1,3-DIMETHYL-2,9-DIOXABICYCLONONANE

The use of the iodoetherification reaction for the selective preparation of optically active trans-2,4-disubstituted tetrahydrofurans and the use of the latter compounds as precursors of syn-1,3-diols is exemplified in the synthesis of (1R,3R,5S)-Endo-1,3

PREPARATION OF ETHYL 5(S),6-EPOXY-3(R)-(METHOXYMETHOXY)HEXANOATE: A KEY CHIRAL INTERMEDIATE FOR MEVINOLIN AND COMPACTIN.

The synthesis of Ethyl 5(S),6-Epoxy-3(R)-(methoxymethoxy)hexanoate, a key chiral synthon for the β-hydroxy-δ-lactone portion of Mevinolin and Compactin, via a regiospecific ring opening of a tetrahydrofuran derivative by dimethyboron bromide, is described.