970-06-9Relevant academic research and scientific papers
Cross-coupling of aryl/alkenyl silyl ethers with grignard reagents through nickel-catalyzed CO bond activation
Zhao, Fei,Yu, Da-Gang,Zhu, Ru-Yi,Xi, Zhenfeng,Shi, Zhang-Jie
supporting information; experimental part, p. 1001 - 1003 (2011/12/05)
CO activation and its application have drawn much attention since oxygen-based electrophiles are easily available, less toxic, and more environmentally benign. This letter presents systematically results on the Ni-catalyzed KumadaTamaoCorriu coupling based on siloxy arenes/alkenes, which provides a new strategy of silyl protection/CC bond formation sequence in organic synthesis.
Polycondensation of naphthalene and its alkyl derivatives
Golounin,Marakushina,Khramenko
experimental part, p. 2137 - 2140 (2009/06/05)
Polycondensation of naphthalene and its alkyl derivatives (stripping oil, 2,5-dimethylnaphthalene) in the presence of aluminum halides was performed. Under the action of an ultrasonic field on a benzene solution of naphthalene in the presence of the catalyst, intermolecular condensation and benzene addition are observed.
