97116-47-7

Upstream product

• 186581-53-3 diazomethane 
• 19799-44-1 3,4-bis(4-methoxyphenyl)thiophene-2,5-dicarboxylic acid 
• 102599-69-9 3,4-bis-(4-methoxy-phenyl)-thiophene-2,5-dicarboxylic acid dimethyl ester 
• 60-29-7 diethyl ether 
• 3901-07-3 3-(4-methoxy-phenyl)acrylic acid methyl ester 
• 110570-52-0 racem-3,4-Bis-(4-methoxy-phenyl)-hexan-1,6-diol 
• 123-11-5 4-methoxy-benzaldehyde 
• 67-56-1 methanol 
• 19950-53-9 racem.-3.4-bis-(4-methoxy-phenyl)-adipic acid 
• 408311-59-1 meso-3,4-Bis-(4-methoxy-phenyl)-adipinsaeure 

Downstream Products

• 97080-09-6 cis-3,4-bis-(4-methoxy-phenyl)-cyclopentanone 
• 19950-54-0 meso-3,4-bis-(4-methoxy-phenyl)-adipic acid 
• 110570-52-0 meso-3,4-bis-(4-methoxy-phenyl)-hexane-1,6-diol 
• 97080-09-6 3,4-bis(4-methoxyphenyl)cyclopentanone 
• 19950-53-9 racem.-3.4-bis-(4-methoxy-phenyl)-adipic acid 
• 19950-53-9 3.4-bis-(4-methoxy-phenyl)-adipic acid 

Relevant academic research and scientific papers

Stereoselective hydrocoupling of cinnamic acid esters by electroreduction: Application to asymmetric synthesis of hydrodimers

The electroreduction of Ar-substituted methyl cinnamates in acetonitrile gave all-trans cyclized hydrodimers stereoselectively (58-90% de). In all cases, small amounts (2-symmetric dl-3,4-diaryladipic acids and trans-3,4-diarylcyclopentanones. The chiral auxiliary [(1R)-exo]-3-exo-(diphenylmethyl)borneol, prepared from (1R)-(+)-camphor, was highly effective for the stereoselective hydrocoupling of its cinnamates by electroreduction. From the resulting hydrodimers, (3R,4R)-3,4-diaryladipic acid esters and (3R,4R)-3,4-diarylhexane-1,6-diols were synthesized in 87-95% ee.

Stereoselective hydrocoupling of [(1R)-exo]-3-exo-(diphenylmethyl)bornyl cinnamates by electroreduction

Equation presented The chiral auxiliary [(1R)-exo]-3-exo-(diphenylmethyl)borneol, synthesized from (1R)-(+)-camphor in three steps, was highly effective for the stereoselective hydrocoupling of its cinnamates by electroreduction. From the resulting hydrod

Photoinduced Electron Transfer Reaction of Cyclopropanone Acetals with Arylmethyl Methanesulfonate: Generation of β-Keto Radical Species and Application to C-C Bond Formation

The photoinduced electron transfer reaction of the cyclopropanone acetals 1 with arylmethyl methanesulfonates 4 or 10 as electron acceptors was found to generate a transient pair of radicals, the β-keto radical 3 and the arylmethyl radical, which underwent a novel carbon-carbon formation reaction at the sterically hindered β-position of the esters.