98004-04-7Relevant academic research and scientific papers
[3 + 2] annulation of allylic silanes in acyclic stereocontrol: Total synthesis of (9S)-dihydroerythronolide A
Peng, Zhi-Hui,Woerpel
, p. 6018 - 6019 (2007/10/03)
The [3 + 2] annulation reactions of allylic silanes can be utilized to achieve acyclic stereocontrol. This method was employed as a key step in an enantioselective total synthesis of (9S)-dihydroerythronolide A. The key annulation reaction served to estab
Chiral Synthesis of Polyketide-derived Natural Products. Part 4. Synthesis of a Left-hand Segment with Six Consecutive Chiral Centres of Dihydroerythronolide A for the Total Synthesis of Erythromycin A from D-Glucose
Oikawa, Yuji,Nishi, Takao,Yonemitsu, Osamu
, p. 7 - 18 (2007/10/02)
For the purpose of the total synthesis of erythromycin A (1) from D-glucose (2) with the aid of stereochemical control in acyclic systems and p-methoxyphenylmethyl (MPM) protection, (2R,3S,4S,5R,6R,7R)-1-hydroxy-5,6-isopropylidenedioxy-3,7-bis(4-methoxybe
