98169-71-2Relevant academic research and scientific papers
Structural isomers of bis(diphenylarsino)methane-dichloroplatinum(II)
Babai, Arash,Deacon, Glen B.,Meyer, Gerd
, p. 399 - 402 (2004)
From a range of preparative methods, three geometric isomers of bis(diphenylarsino)methane-dichloroplatinum(II) have been isolated, viz. cis-PtCl2(dpam), trans, trans-Pt2Cl4(dpam) 2 and cis, trans-Pt2Cl4(dpam)2. Their structures were determined by single-crystal X-ray diffraction.
The Synthesis of Mono- and Bi-metallic Complexes containing the Ligand Bis(diphenylarsino)methane
Jacobsen, Grant B.,Shaw, Bernard L.
, p. 151 - 154 (2007/10/02)
Treatment of (cod = cyclo-octa-1,5-diene) with bis(diphenylarsino)methane (dpam) gives the binuclear complex and none of the mononuclear complex .Treatment of with dpam results in an equilibrium mixture containing the bis-monodentate complex cis-.The chelate complexes (X = Cl, Br, or I) have been prepared, which on further treatment with one equivalent of dpam gave the neutral complexes trans- (X = Cl or Br).The complex trans- gives the heterobimetallic complex trans- on treatment with HgCl2.Treatment of trans- with the methoxycyclo-octenyl complex gives the PtI dimer , which on further treatment with CO yields .
A Comparison of the Ligand Behaviour of Ph2AsCH2AsPh2 (dpam) with that of Ph2PCH2PPh2 (dppm) in Mono- and Bi-metallic Platinum Complexes
Jacobsen, Grant B.,Shaw, Bernard L.
, p. 692 - 693 (2007/10/02)
cis,cis- is more stable than , the reverse is the case for dppm, and trans- is formed from + dpam whereas gives (2+).
