98386-24-4Relevant academic research and scientific papers
Conversion of D-Glucose to L-Glucose: Oxidative Decarboxylation of α-Oxy Carboxylic Acids via Their Diacyl Peroxides
Shiozaki, Masao
, p. 528 - 532 (2007/10/02)
D-Glucose was converted to an L-glucose derivative.The key step was the oxidative decarboxylation of carboxylic acid 12 via its diacyl peroxide derivative.This synthetic scheme proceeds through C-glycosidic compounds and is applicable to other sugar confi
Anodic Oxidation of O-Benzoylated α-Hydroxyacetic Acids - A Contribution to the Reactivity of Anodic Oxidated Carboxylate Ions - "Umpolung"
Thomas, H. Guenter,Kessel, Stephan
, p. 2777 - 2788 (2007/10/02)
Anodic oxidation of O-benzoylated α-hydroxyacetic acid 1 at graphite electrodes in methanol leads to the corresponding mixed acylals 2 and methyl benzoates 3.The rate 2:3 depends on the substitution of the aromatic ring and can be correlated to Hammett's ?-values.
