98405-79-9

Basic information

• Product Name: 3-Butenenitrile, 2,2-dimethyl-4-phenyl-, (E)-
• CAS NO: 98405-79-9
• Molecular Formula: C12H13N
• Molecular Weight: 171.242
• Mol File: 98405-79-9.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: 3-Butenenitrile, 2,2-dimethyl-4-phenyl-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Butenenitrile, 2,2-dimethyl-4-phenyl-, (E)-(98405-79-9)
• EPA Substance Registry System: 3-Butenenitrile, 2,2-dimethyl-4-phenyl-, (E)-(98405-79-9)

Safety Data

• Hazardous Substances Data: 98405-79-9(Hazardous Substances Data)

Upstream product

• 108-85-0 1-bromocyclohexane 
• 66680-87-3 (2-phenylvinyl)tributylstannane 
• 10368-81-7 methyl 4-O-benzoyl-6-bromo-6-deoxy-α-D-glucopyranoside 
• 539-74-2 Ethyl 3-bromopropionate 
• 7677-24-9 trimethylsilyl cyanide 
• 100103-33-1 (E)-(3-methoxy-3-methylbut-1-en-1-yl)benzene 
• 2032-35-1 Bromoacetaldehyde diethyl acetal 
• 540-51-2 2-bromoethanol 
• 78-67-1 2,2'-azobis(isobutyronitrile) 
• 536-74-3 phenylacetylene 
• 637-44-5 phenylpropyolic acid 
• 100-42-5 styrene 
• 103-64-0 bromostyrene 
• 102-96-5 (2-nitroethenyl)benzene 

Downstream Products

• 15732-83-9 (E)-2,2-dimethyl-4-phenyl-3-buten-1-ol 
• 15732-85-1 2,2-dimethyl-4-phenyl-butan-1-ol 
• 15732-89-5 (E)-2,2-dimethyl-4-phenylbut-3-enoic acid 

Relevant articles and documents

Copper-catalyzed decarboxylative cross-coupling of cinnamic acids and ACCN via single electron transfer

A novel and convenient method for the synthesis of β,γ-unsaturated nitriles using ACCN (1,1′-azobis(cyclohexane-1-carbonitrile)) as a cyano source was described. This reaction was amenable to a broad range of substrates and provided the desired β,γ-unsatu

Metal-Free-Catalyzed Synthesis of Allyl Nitriles via Csp2-Csp3 Coupling between Olefins and Azobis (Alkyl-carbonitrile)

The metal-free-catalyzed synthesis of allyl nitriles from Csp2-Csp3 coupling between olefins and azobis was carried out. Key on this work was that the synthesis of allyl nitriles directly using olefin as a start

Reversible Structural Transformations of Metal–Organic Frameworks as Artificial Switchable Catalysts for Dynamic Control of Selectively Cyanation Reaction

The synthesis of molecular-level artificial switchable catalysts, of which activity in different chemical processes can be switched by controlling different stimuli, has provided a new paradigm to perform mechanical tasks and measurable work. In this work, to obtain highly effective and regioselective artificial switchable catalysts, a hierarchical anion-pillared framework {(H3O)[Cu(CPCDC)(4,4′-bpy)]}n (1; H3CPCDC=9-(4-carboxyphenyl)-9H-carbazole-3,6-dicarboxylic acid, 4,4′-bpy=4,4′-bipyridine), including free [H3O]+ ions as guest molecules, was constructed. Upon dissolve–exchange–crystallization behavior, fascinating reversible structural transformations proceeded between anion framework 1 and neutral 2D stair-stepping framework {[Cu(CPCDC)(4,4′-bpe)]}n (2; 4,4′-bpe=4,4′-vinylenedipyridine). Moreover, frameworks 1 and 2 can act as heterogeneous artificial switchable catalysts to selectively promote the direct cyanation reaction of terminal alkynes and azobisisobutyronitrile. The results indicated that 1 and 2 exhibited excellent selectivity to generate vinyl isobutyronitrile skeletons or propiolonitrile frameworks, respectively, as unique products. Furthermore, indicating paper, GC-MS, energy-dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy analysis demonstrated that the reversible structural transformations endowed 1 and 2 with well-defined platforms to stabilize the isobutyronitrile and CN sources through the different catalytic pathways.