99016-98-5Relevant academic research and scientific papers
Access to both anomers of pectenotoxin spiroketals by kinetic spiroketalization
Pihko, Petri M.,Aho, Jatta E.
, p. 3849 - 3852 (2007/10/03)
A concise synthesis of both AB ring spiroisomers of the pectenotoxins is described. The nonanomeric AB spiroketal ring system of the pectenotoxins-1, -2, -3, and -6 is formed under very mild, kinetic spiroketalization conditions, along with the anomeric i
Stereocontrolled Total Synthesis of Lipoxins A
Nicolau, K. C.,Veale, C. A.,Webber, S. E.,Katerinopoulos, H.
, p. 7515 - 7518 (2007/10/02)
A stereocontrolled total synthesis of lipoxin A and a number of its isomers is reported.The strategy involves Sharpless asymmetric epoxidation and pinylborane asymmetric reduction to build the hydroxy-bearing stereocenters and a Wittig-type as well as a P
