113. Deoxy-nitrosugars. 11th Communication. Reaction of 1-C-Nitroglycosyl Halides and 1-C-Nitroglycosyl Sulfones with Dialkyl-Phosphite Anions: Nucleophilic Attack vs. Single-Electron Transfer

DOI: 10.1002/hlca.19850680426

Source and publish data:

Helvetica Chimica Acta p. 997 - 1009 (1985)

Update date:2022-08-17

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Authors:

Meuwly, Roger

Vasella, Andrea

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Article abstract of DOI:10.1002/hlca.19850680426

Treatment of the chloro-nitro-ribofuranose 7 with KPO(OMe)2 gave the O-amino phosphate 8 (5percent) and the nitrile 9 (62percent).Compound 9 was also obtained by the reaction of 8 with KPO(OMe)2, and its structure was established by X-ray analysis.Treatme

Full text of DOI:10.1002/hlca.19850680426

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