Mild Generation of Adamantylidenevinylidene (an Alkenylidenecarbene) from 2-Bromo-2-(trimethylsilylethynyl)adamantane and (2-Bromo-2-trimethylsilylvinylidene)adamantane

DOI: 10.1039/c39850000958

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 958 - 959 (1985)

Update date:2022-09-26

Topics:

Authors:

Eguchi, Shoji

Ikemoto, Tomoyuki

Kobayakawa, Yasuyuki

Sasaki, Tadashi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39850000958

Adamantylidenevinylidene, a new alkenylidenecarbene, was successfully generated by fluoride-initiated elimination of trimethylsilyl and bromo groups from 2-bromo-2-(trimethylsilylethynyl)adamantane and (2-bromo-2-trimethylsilylvinylidene)adamantane.

Full text of DOI:10.1039/c39850000958

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:2-(2-Phenyl-cyclopropylidenemethylene)-adamantane

Cas No:99337-53-8

R&D Labs maybe for 99337-53-8

STAR SYNTHESIS CO.,LIMITED

Contact:+(852) 301-98033

Address:Flat C, 23/F, Lucky Plaza, 315-321 Lockhart Road, Wan Chai, Hong Kong
Beijing Century Richap Chemistry Co.,Ltd

Contact:+86- 010-64455497

Address:Guannan County, Lianyungang City, Jiangsu Province, China
SPE Chemicals Co.,Ltd

Contact:

Address:ROOM 1715, No#345 Jin Xiang Road, Pudong District
Tocopharm Co., Ltd.

Contact:+86-021-6989-5597

Address:No.80 Yichuan Rd., Putuo District,Shanghai,P.R.China
Jiaxing Taixin Pharmaceutical Chemical Co., Ltd

Contact:0573-82613601

Address:Chemical Park, Jiaxing, Zhejiang, China

Relevant to this article

One-pot synthesis of fully substituted 1,3,4-oxadiazole derivatives from aromatic carboxylic acids, cyclobutanone and N-isocyaniminotriphenylphosphorane

Doi:10.3906/kim-1102-3
(2012)
Bis(quinoxaline-dithiolato)nickel(III) Complexes [Bu₄N][Ni^III(6,7-qdt)₂] and [Ph₄P][Ni^III(Ph₂6,7-qdt)₂]·CHCl₃ (6,7-qdt = Quinoxaline-6,7-dithiolate; Ph₂6,7-

Doi:10.1002/ejic.201500739
(2015)
Syntheses and QSAR studies of benzylimidazole derivatives and benzylcarbazole as potential aromatase inhibitors

Doi:10.14233/ajchem.2014.16016
(2014)
A novel one-pot synthesis of fluorinated α,β-unsaturated esters

Doi:10.1080/00397919108021289
(1991)
Synthesis and characterization of new galactosylated-based N₂O-donors tridentate ligands

Doi:10.1080/00397911.2019.1599953
(2019)
A practical synthesis of D-erythro-sphingosine using a cross-metathesis approach

Doi:10.1039/b403568b
(2004)

Article Doi