Mild Generation of Adamantylidenevinylidene (an Alkenylidenecarbene) from 2-Bromo-2-(trimethylsilylethynyl)adamantane and (2-Bromo-2-trimethylsilylvinylidene)adamantane

DOI: 10.1039/c39850000958

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 958 - 959 (1985)

Update date:2022-09-26

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Authors:

Eguchi, Shoji

Ikemoto, Tomoyuki

Kobayakawa, Yasuyuki

Sasaki, Tadashi

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Article abstract of DOI:10.1039/c39850000958

Adamantylidenevinylidene, a new alkenylidenecarbene, was successfully generated by fluoride-initiated elimination of trimethylsilyl and bromo groups from 2-bromo-2-(trimethylsilylethynyl)adamantane and (2-bromo-2-trimethylsilylvinylidene)adamantane.

Full text of DOI:10.1039/c39850000958

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