99833-12-2Relevant academic research and scientific papers
UEBERGANGSMETALL-THIOKETEN-KOMPLEXE. IX. DARSTELLUNG, STRUCTUR UND EIGENSCHAFTEN VON ZWEIKERNIGEN THIOACYL- UND THIOALDEHYD-EISEN-KOMPLEXEN
Umland, Henning,Behrens, Ulrich
, p. 109 - 122 (1985)
The thioketene iron cluster (C11H18S)Fe2(CO)6 (II) reacts with H- to give the anionic thioacyl complex - (IV). (PPh3)Au+ and Hg2+ are taken up by IV to form the neutral thioacyl clusters V and
