UEBERGANGSMETALL-THIOKETEN-KOMPLEXE. IX. DARSTELLUNG, STRUCTUR UND EIGENSCHAFTEN VON ZWEIKERNIGEN THIOACYL- UND THIOALDEHYD-EISEN-KOMPLEXEN

DOI: 10.1016/0022-328X(85)80073-5

Source and publish data:

Journal of Organometallic Chemistry p. 109 - 122 (1985)

Update date:2022-08-03

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Authors:

Umland, Henning

Behrens, Ulrich

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Article abstract of DOI:10.1016/0022-328X(85)80073-5

The thioketene iron cluster (C11H18S)Fe2(CO)6 (II) reacts with H^- to give the anionic thioacyl complex <(C11H19S)Fe(CO)6>^- (IV). (PPh3)Au⁺ and Hg²⁺ are taken up by IV to form the neutral thioacyl clusters V and

Full text of DOI:10.1016/0022-328X(85)80073-5

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