99853-19-7

Upstream product

• 90448-98-9 allyl dibromoacetate 
• 71-43-2 benzene 
• 103-82-2 phenylacetic acid 
• 2912-60-9 α-bromophenylacetyl bromide 
• 107-18-6 allyl alcohol 
• 145193-16-4 allyl α-phenyl-α-diazoacetate 

Downstream Products

• 1797-74-6 allyl phenylacetate 
• 99865-09-5 4-methyl-3-phenyl-dihydro-furan-2-one 
• 1296863-90-5 allyl 4-oxo-2,4-diphenylbutanoate 
• 1126793-08-5 N-methyl-N-(1-phenylbut-3-enyl)aniline 
• 956130-96-4 2-(3-cyano-4-furan-2-yl-6-thiophen-2-yl-pyridin-2-yloxy)-2-phenyl-N-(2H-tetrazol-5-yl)-acetamide 

Relevant academic research and scientific papers

Bromination of α-Diazo Phenylacetate Derivatives Using Cobalt(II) Bromide

A method for the bromination of α-diazo phenylacetate derivatives using cobalt(II) bromide is described. This bromination reaction features a short reaction time, broad substrate scope, operational simplicity, acid-free conditions, and gram-scalability. (Figure presented.).

Visible light-induced intermolecular radical addition: Facile access to γ-ketoesters from alkyl-bromocarboxylates and enamines

A highly efficient addition of alkyl α-bromocarboxylates to enamines by visible light-induced photoredox catalysis is reported. Compared with traditional methods, the reaction described here provided an alternative route for the construction of valuable γ-ketoesters in generally good yields.

Radical cyclization of allyl α-bromocarboxylates into γ-butyrolactones. Effect of the ester structure on the cyclization

Allyl dibromoacetate, allyl α-bromopropionate, and allyl phenylbromoacetate undergo cyclization in benzene in the presence of increased concentration of Fe(CO)5 - DMF as the initiating system to give the corresponding bromo-substituted butyrolactones.