99855-08-0

Basic information

• Product Name: (3S,5R)-5-Methyl-3-p-tolyl-oxazolidin-2-one
• CAS NO: 99855-08-0
• Molecular Weight: 191.23
• Mol File: 99855-08-0.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: (3S,5R)-5-Methyl-3-p-tolyl-oxazolidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,5R)-5-Methyl-3-p-tolyl-oxazolidin-2-one(99855-08-0)
• EPA Substance Registry System: (3S,5R)-5-Methyl-3-p-tolyl-oxazolidin-2-one(99855-08-0)

Safety Data

• Hazardous Substances Data: 99855-08-0(Hazardous Substances Data)

Upstream product

• 622-58-2 p-Tolylisocyanate 
• 75-56-9 methyloxirane 
• 75-44-5 phosgene 
• 3077-14-3 1-[(4-methylphenyl)amino]-2-propanol 
• 106-49-0 p-toluidine 
• 124-38-9 carbon dioxide 
• 26198-63-0 1,2-Dichloropropane 
• 108-32-7 1,2-propylene cyclic carbonate 

Relevant articles and documents

Metal-Organic Framework MIL-101-NH2-Supported Acetate-Based Butylimidazolium Ionic Liquid as a Highly Efficient Heterogeneous Catalyst for the Synthesis of 3-Aryl-2-oxazolidinones

A novel heterogeneous catalyst, the ionic liquid (IL) of 1-butyl-3-methylimidazolium acetate (BmimOAc) immobilized on MIL-101-NH2, denoted as IL(OAc-)-MIL-101-NH2, was prepared by the "ship-in-a-bottle" strategy. The IL of

Synthesis of Oxazolidinones and Derivatives through Three-Component Fixation of Carbon Dioxide

An effective three-component fixation of atmospheric CO2 with readily available 1,2-dichloroethane and aromatic amine toward oxazolidinones catalyzed by in situ NHC was developed. The reaction occurred in good to excellent yields with good gene

Synthesis of N-aryl-2-oxazolidinones from cyclic carbonates and aromatic amines catalyzed by bio-catalyst

A convenient and effective method of synthesizing 3-aryl-2-oxazolidinones from cyclic carbonates and aryl amines catalyzed by bio-catalyst adenine in the presence of Et3N under solvent-free conditions is described. The protocol is suitable for the wide scope of substrates, e.g. cyclic carbonates with or without substitutes, and aryl amines with either electron-withdrawing or electron-donating group. The products were obtained in good to excellent yields under the optimal conditions, even in steric hindered cases. The effect of reaction time, temperature, loading of catalyst, and amount of starting materials in the reaction were investigated, and the reaction mechanism is discussed.