99975-12-9Relevant academic research and scientific papers
Triethylborane-induced bromine atom-transfer radical addition in aqueous media: Study of the solvent effect on radical addition reactions
Yorimitsu,Shinokubo,Matsubara,Oshima,Omoto,Fujimoto
, p. 7776 - 7785 (2001)
A mixture of ethyl bromoacetate and 1-octene was treated with triethylborane in water at ambient temperature to provide ethyl 4-bromodecanoate in good yield. The bromine atom-transfer radical addition in benzene was not satisfactory. The addition proceede
Light-mediated dual phosphine-/copper-catalyzed atom transfer radical addition reaction
Fedorov, Oleg V.,Scherbinina, Sofya I.,Levin, Vitalij V.,Dilman, Alexander D.
, p. 11068 - 11079 (2019/09/30)
The atom transfer radical addition reaction catalyzed by triphenylphosphine and copper(I) halide is described. The reaction proceeds under irradiation with 365 nm light using a light-emitting diode and was performed in regular glassware. The proposed mech
