|
1.
1.1
IDENTIFICATION
OF
THE
SUBSTANCE/MIXTURE
AND
OF
THE
COMPANY/UNDERTAKING
Product
identifiers
Product
name
Product
Number
Brand
Index-No.
CAS-No.
:
:
:
:
:
Formaldehyde
solution,
36.5-38%
F8775
605-001-00-5
50-00-0
1.2
Relevant
identified
uses
of
the
substance
or
mixture
and
uses
advised
against
Identified
uses
:
Laboratory
chemicals,
Manufacture
of
substances 2.
2.1
2.2
HAZARDS
IDENTIFICATION
Classification
of
the
substance
or
mixture
Classification
according
to
Regulation
(EC)
No
1272/2008
[EU-GHS/CLP]
Acute
toxicity,
Oral
(Category
3)
Acute
toxicity,
Inhalation
(Category
3)
Acute
toxicity,
Dermal
(Category
3)
Skin
corrosion
(Category
1B)
Skin
sensitization
(Category
1)
Carcinogenicity
(Category
2)
Specific
target
organ
toxicity
-
single
exposure
(Category
1)
Specific
target
organ
toxicity
-
single
exposure
(Category
3)
Classification
according
to
EU
Directives
67/548/EEC
or
1999/45/EC
Toxic
by
inhalation,
in
contact
with
skin
and
if
swallowed.
Toxic:
danger
of
very
serious
irreversible
effects
through
inhalation,
in
contact
with
skin
and
if
swallowed.
Causes
burns.
Limited
evidence
of
a
carcinogenic
effect.
May
cause
sensitization
by
skin
contact.
Label
elements
Labelling
according
Regulation
(EC)
No
1272/2008
[CLP]
Pictogram
Signal
word
Hazard
statement(s)
H301
H311
-
F8775
Danger
Toxic
if
swallowed.
Toxic
in
contact
with
skin.
H314
H317
H331
H335
H351
H370
Precautionary
statement(s)
P260
P280
P301
+
P310
P305
+
P351
+
P338
P310
Supplemental
Hazard
Causes
severe
skin
burns
and
eye
damage.
May
cause
an
allergic
skin
reaction.
Toxic
if
inhaled.
May
cause
respiratory
irritation.
Suspected
of
causing
cancer.
Causes
damage
to
organs.
Do
not
breathe
dust/
fume/
gas/
mist/
vapours/
spray.
Wear
protective
gloves/
protective
clothing/
eye
protection/
face
protection.
IF
SWALLOWED:
Immediately
call
a
POISON
CENTER
or
doctor/
physician.
IF
IN
EYES:
Rinse
cautiously
with
water
for
several
minutes.
Remove
contact
lenses,
if
present
and
easy
to
do.
Continue
rinsing.
Immediately
call
a
POISON
CENTER
or
doctor/
physician.
none
Statements
According
to
European
Directive
67/548/EEC
as
amended.
Hazard
symbol(s)
R-phrase(s)
R23/24/25
R34
R39/23/24/25
R40
R43
S-phrase(s)
S26
S36/37/39
S45
Toxic
by
inhalation,
in
contact
with
skin
and
if
swallowed.
Causes
burns.
Toxic:
danger
of
very
serious
irreversible
effects
through
inhalation,
in
contact
with
skin
and
if
swallowed.
Limited
evidence
of
a
carcinogenic
effect.
May
cause
sensitization
by
skin
contact.
In
case
of
contact
with
eyes,
rinse
immediately
with
plenty
of
water
and
seek
medical
advice.
Wear
suitable
protective
clothing,
gloves
and
eye/face
protection.
In
case
of
accident
or
if
you
feel
unwell,
seek
medical
advice
immediately
(show
the
label
where
possible).
2.3
3.
3.2
Other
hazards
Lachrymator.,
Rapidly
absorbed
through
skin.
COMPOSITION/INFORMATION
ON
INGREDIENTS
Mixtures
Synonyms
Formula
Molecular
Weight
:
:
:
Formalin
CH2O
30,03
g/mol
Component
Formaldehyde
Classification
Concentration
CAS-No.
EC-No.
Index-No.
50-00-0
200-001-8
605-001-00-5
Acute
Tox.
3;
Skin
Corr.
1B;
Skin
Sens.
1;
Carc.
2;
H301
+
H311
+
H331,
H314,
H317,
25
-
50
%
H351
T,
Carc.Cat.3,
R23/24/25
-
R34
-
R40
-
R43
Methanol
-
F8775
CAS-No.
EC-No.
Index-No.
Registration
number
67-56-1
200-659-6
603-001-00-X
01-2119433307-44-XXXX
Flam.
Liq.
2;
Acute
Tox.
3;
STOT
SE
1;
H225,
H301
+
H311
+
H331,
H370
F,
T,
R11
-
R23/24/25
-
10
-
20
%
R39/23/24/25
For
the
full
text
of
the
H-Statements
and
R-Phrases
mentioned
in
this
Section,
see
Section
16
4.
4.1
4.2
4.3
5.
5.1
5.2
5.3
5.4
6.
6.1
6.2
6.3
6.4
7.
7.1
FIRST
AID
MEASURES
Description
of
first
aid
measures
General
advice
Consult
a
physician.
Show
this
safety
data
sheet
to
the
doctor
in
attendance.
If
inhaled
If
breathed
in,
move
person
into
fresh
air.
If
not
breathing,
give
artificial
respiration.
Consult
a
physician.
In
case
of
skin
contact
Wash
off
with
soap
and
plenty
of
water.
Take
victim
immediately
to
hospital.
Consult
a
physician.
In
case
of
eye
contact
Rinse
thoroughly
with
plenty
of
water
for
at
least
15
minutes
and
consult
a
physician.
If
swallowed
Do
NOT
induce
vomiting.
Never
give
anything
by
mouth
to
an
unconscious
person.
Rinse
mouth
with
water.
Consult
a
physician.
Most
important
symptoms
and
effects,
both
acute
and
delayed
Warning:
contains
methanol.
May
be
fatal
or
cause
blindness
if
swallowed.
Cannot
be
made
nonpoisonous.
Indication
of
any
immediate
medical
attention
and
special
treatment
needed
no
data
available
FIREFIGHTING
MEASURES
Extinguishing
media
Suitable
extinguishing
media
Use
water
spray,
alcohol-resistant
foam,
dry
chemical
or
carbon
dioxide.
Special
hazards
arising
from
the
substance
or
mixture
Carbon
oxides
Advice
for
firefighters
Wear
self
contained
breathing
apparatus
for
fire
fighting
if
necessary.
Further
information
Use
water
spray
to
cool
unopened
containers.
ACCIDENTAL
RELEASE
MEASURES
Personal
precautions,
protective
equipment
and
emergency
procedures
Wear
respiratory
protection.
Avoid
breathing
vapors,
mist
or
gas.
Ensure
adequate
ventilation.
Remove
all
sources
of
ignition.
Evacuate
personnel
to
safe
areas.
Beware
of
vapours
accumulating
to
form
explosive
concentrations.
Vapours
can
accumulate
in
low
areas.
Environmental
precautions
Prevent
further
leakage
or
spillage
if
safe
to
do
so.
Do
not
let
product
enter
drains.
Discharge
into
the
environment
must
be
avoided.
Methods
and
materials
for
containment
and
cleaning
up
Contain
spillage,
and
then
collect
with
an
electrically
protected
vacuum
cleaner
or
by
wet-brushing
and
place
in
container
for
disposal
according
to
local
regulations
(see
section
13).
Keep
in
suitable,
closed
containers
for
disposal.
Reference
to
other
sections
For
disposal
see
section
13.
HANDLING
AND
STORAGE
Precautions
for
safe
handling
Avoid
contact
with
skin
and
eyes.
Avoid
inhalation
of
vapour
or
mist.
-
F8775
Keep
away
from
sources
of
ignition
-
No
smoking.Take
measures
to
prevent
the
build
up
of
electrostatic
charge.
7.2
7.3
8.
8.1
8.2
Conditions
for
safe
storage,
including
any
incompatibilities
Store
in
cool
place.
Keep
container
tightly
closed
in
a
dry
and
well-ventilated
place.
Containers
which
are
opened
must
be
carefully
resealed
and
kept
upright
to
prevent
leakage.
Specific
end
uses
no
data
available
EXPOSURE
CONTROLS/PERSONAL
PROTECTION
Control
parameters
Components
with
workplace
control
parameters
Exposure
controls
Appropriate
engineering
controls
Avoid
contact
with
skin,
eyes
and
clothing.
Wash
hands
before
breaks
and
immediately
after
handling
the
product.
Personal
protective
equipment
Eye/face
protection
Tightly
fitting
safety
goggles.
Faceshield
(8-inch
minimum).
Use
equipment
for
eye
protection
tested
and
approved
under
appropriate
government
standards
such
as
NIOSH
(US)
or
EN
166(EU).
Skin
protection
Handle
with
gloves.
Gloves
must
be
inspected
prior
to
use.
Use
proper
glove
removal
technique
(without
touching
glove's
outer
surface)
to
avoid
skin
contact
with
this
product.
Dispose
of
contaminated
gloves
after
use
in
accordance
with
applicable
laws
and
good
laboratory
practices.
Wash
and
dry
hands.
The
selected
protective
gloves
have
to
satisfy
the
specifications
of
EU
Directive
89/686/EEC
and
the
standard
EN
374
derived
from
it.
Immersion
protection
Material:
butyl-rubber
Minimum
layer
thickness:
0,3
mm
Break
through
time:
>
480
min
Material
tested:Butoject?
(
Z677647,
Size
M)
Splash
protection
Material:
Nitrile
rubber
Minimum
layer
thickness:
0,4
mm
Break
through
time:
>
30
min
Material
tested:Dermatril?
P
(
Z677388,
Size
M)
data
source:
KCL
GmbH,
D-36124
Eichenzell,
phone
+49
(0)6659
873000,
e-mail
sales@kcl.de,
test
method:
EN374
If
used
in
solution,
or
mixed
with
other
substances,
and
under
conditions
which
differ
from
EN
374,
contact
the
supplier
of
the
CE
approved
gloves.
This
recommendation
is
advisory
only
and
must
be
evaluated
by
an
Industrial
Hygienist
familiar
with
the
specific
situation
of
anticipated
use
by
our
customers.
It
should
not
be
construed
as
offering
an
approval
for
any
specific
use
scenario.
Body
Protection
Complete
suit
protecting
against
chemicals,
The
type
of
protective
equipment
must
be
selected
according
to
the
concentration
and
amount
of
the
dangerous
substance
at
the
specific
workplace.
Respiratory
protection
Where
risk
assessment
shows
air-purifying
respirators
are
appropriate
use
a
full-face
respirator
with
multi-purpose
combination
(US)
or
type
ABEK
(EN
14387)
respirator
cartridges
as
a
backup
to
engineering
controls.
If
the
respirator
is
the
sole
means
of
protection,
use
a
full-face
supplied
air
respirator.
Use
respirators
and
components
tested
and
approved
under
appropriate
government
standards
such
as
NIOSH
(US)
or
CEN
(EU).
-
F8775
9.
9.1
PHYSICAL
AND
CHEMICAL
PROPERTIES
Information
on
basic
physical
and
chemical
properties
a)
b)
c)
d)
e)
f)
g)
h)
Appearance
Odour
Odour
Threshold
pH
Melting
point/freezing
point
Initial
boiling
point
and
boiling
range
Flash
point
Evaporation
rate
Form:
liquid,
clear
Colour:
colourless
no
data
available
no
data
available
no
data
available
no
data
available
no
data
available
64
°C
-
closed
cup
no
data
available
i)
Flammability
(solid,
gas)
no
data
available
j)
k)
l)
Upper/lower
flammability
or
explosive
limits
Vapour
pressure
Vapour
density
Upper
explosion
limit:
73
%(V)
Lower
explosion
limit:
7
%(V)
69
hPa
at
37
°C
1,04
-
(Air
=
1.0)
m)
Relative
density
1,016
g/cm3
n)
o)
p)
q)
r)
s)
t)
Water
solubility
Partition
coefficient:
n-
octanol/water
Autoignition
temperature
Decomposition
temperature
Viscosity
Explosive
properties
Oxidizing
properties
no
data
available
no
data
available
no
data
available
no
data
available
no
data
available
no
data
available
no
data
available
9.2
10.
10.1
10.2
10.3
10.4
10.5
Other
safety
information
no
data
available
STABILITY
AND
REACTIVITY
Reactivity
no
data
available
Chemical
stability
no
data
available
Contains
the
following
stabiliser(s):
Methanol
(>=10
-
<=15
%)
Possibility
of
hazardous
reactions
no
data
available
Conditions
to
avoid
Heat,
flames
and
sparks.
Incompatible
materials
Aniline,
Phenol,
Isocyanates,
Acid
anhydrides,
Strong
acids,
Strong
bases,
Strong
oxidizing
agents,
Amines,
Peroxides
-
F8775
10.6
11.
11.1
Hazardous
decomposition
products
Other
decomposition
products
-
no
data
available
TOXICOLOGICAL
INFORMATION
Information
on
toxicological
effects
Acute
toxicity
no
data
available
Skin
corrosion/irritation
no
data
available
Serious
eye
damage/eye
irritation
no
data
available
Respiratory
or
skin
sensitization
May
cause
sensitization
by
skin
contact.
Germ
cell
mutagenicity
no
data
available
Carcinogenicity
IARC:
1
-
Group
1:
Carcinogenic
to
humans
(Formaldehyde)
Reproductive
toxicity
no
data
available
Specific
target
organ
toxicity
-
single
exposure
no
data
available
Specific
target
organ
toxicity
-
repeated
exposure
no
data
available
Aspiration
hazard
no
data
available
Potential
health
effects
Inhalation
Ingestion
Skin
Eyes
Toxic
if
inhaled.
Causes
respiratory
tract
irritation.
Toxic
if
swallowed.
Toxic
if
absorbed
through
skin.
Causes
skin
burns.
May
cause
allergic
skin
reaction.
Causes
eye
burns.
Signs
and
Symptoms
of
Exposure
Warning:
contains
methanol.
May
be
fatal
or
cause
blindness
if
swallowed.
Cannot
be
made
nonpoisonous.
Additional
Information
RTECS:
LP8925000
12.
12.1
12.2
12.3
12.4
12.5
ECOLOGICAL
INFORMATION
Toxicity
no
data
available
Persistence
and
degradability
no
data
available
Bioaccumulative
potential
no
data
available
Mobility
in
soil
no
data
available
Results
of
PBT
and
vPvB
assessment
no
data
available
-
F8775
12.6
13.
13.1
14.
14.1
Other
adverse
effects
Harmful
to
aquatic
life.
DISPOSAL
CONSIDERATIONS
Waste
treatment
methods
Product
This
combustible
material
may
be
burned
in
a
chemical
incinerator
equipped
with
an
afterburner
and
scrubber.
Offer
surplus
and
non-recyclable
solutions
to
a
licensed
disposal
company.
Contaminated
packaging
Dispose
of
as
unused
product.
TRANSPORT
INFORMATION
UN
number
14.2
ADR/RID:
2209
UN
proper
shipping
name
IMDG:
2209
IATA:
2209
ADR/RID:
IMDG:
IATA:
FORMALDEHYDE
SOLUTION
FORMALDEHYDE
SOLUTION
Formaldehyde
solution
14.3
Transport
hazard
class(es)
14.4
14.5
14.6
15.
ADR/RID:
8
Packaging
group
ADR/RID:
III
Environmental
hazards
ADR/RID:
no
Special
precautions
for
user
no
data
available
REGULATORY
INFORMATION
IMDG:
8
IMDG:
III
IMDG
Marine
pollutant:
no
IATA:
8
IATA:
III
IATA:
no
This
safety
datasheet
complies
with
the
requirements
of
Regulation
(EC)
No.
1907/2006.
15.1
15.2
16.
Safety,
health
and
environmental
regulations/legislation
specific
for
the
substance
or
mixture
no
data
available
Chemical
Safety
Assessment
no
data
available
OTHER
INFORMATION
Text
of
H-code(s)
and
R-phrase(s)
mentioned
in
Section
3
Acute
Tox.
Carc.
Flam.
Liq.
H225
H301
+
H311
+
H331
H314
H317
H351
H370
Skin
Corr.
Skin
Sens.
STOT
SE
F
R11
R23/24/25
R34
-
F8775
Acute
toxicity
Carcinogenicity
Flammable
liquids
Highly
flammable
liquid
and
vapour.
Toxic
if
swallowed,
in
contact
with
skin
or
if
inhaled
Causes
severe
skin
burns
and
eye
damage.
May
cause
an
allergic
skin
reaction.
Suspected
of
causing
cancer.
Causes
damage
to
organs.
Skin
corrosion
Skin
sensitization
Specific
target
organ
toxicity
-
single
exposure
Highly
flammable
Highly
flammable.
Toxic
by
inhalation,
in
contact
with
skin
and
if
swallowed.
Causes
burns.
T
R39/23/24/25
R40
R43
Toxic
Toxic:
danger
of
very
serious
irreversible
effects
through
inhalation,
in
contact
with
skin
and
if
swallowed.
Limited
evidence
of
a
carcinogenic
effect.
May
cause
sensitization
by
skin
contact.
Further
information
The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. Lookchem shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions of sale.
| 
Formaldehyde
China (Mainland)] 
Assessed
Premium
South Africa] 
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Assessed
Assessed
Assessed
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