98083-43-3Relevant articles and documents
Conjugate base catalysed one-pot synthesis of pyrazoles from β-formyl enamides
Saikia, Anil,Barthakur, Madan G.,Borthakur, Moyurima,Saikia, Chandan J.,Bora, Utpal,Boruah, Romesh C.
, p. 43 - 46 (2006)
A novel one-pot synthesis of pyrazoles has been accomplished by the reaction of β-formyl enamides with hydroxylamine hydrochloride catalysed by potassium dihydrogenphosphate in acid medium.
Azoles. Part 14: On the behaviour of 5-chloro-2-nitroindazole against aliphatic and cyclic amines
Wrzeciono,Dudzinska-Usarewicz,Majewska,et al.
, p. 105 - 108 (2007/10/02)
The authors describe the synthesis of 5-chloro-1- (7) and 5-chloro-2-nitroindazole (5). 5 reacts with methyl, dimethyl and diethyl amine, pyrrolidine, piperidine and morpholine to form besides 5-chloro-3-nitroindazole (6) and 8 the corresponding 3-amino-5-chloroindazoles 9-12. The isomerization of 5 to 6 takes place under the influence of light and temperature too.
Aromatic Diazonium Salts, X. - A One-Pot Procedure for the Jacobson Synthesis of Indazole
Ruechardt, Christoph,Hassmann, Volker
, p. 908 - 927 (2007/10/02)
Procedures are described for a one-pot synthesis of 1H-indazole and substituted indazoles 3 in good yield (Table 1) from o-toluidines 2, alkyl nitrite or nitrous oxides, potassium acetate, and acetic anhydride in benzene.The spectroscopic properties of substituted indazoles (Tables 2-4) are discussed. - 4-Phenylcinnoline (18) is prepared by the same procedure from o-(α-methylenebenzyl)aniline.