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Cas Database |
| Name |
trans-1,4-Diaminocyclohexane |
EINECS | 640-403-4 |
| CAS No. | 2615-25-0 | Density | 0.939 g/cm3 |
| PSA | 52.04000 | LogP | 1.61560 |
| Solubility | N/A | Melting Point |
67-72 °C |
| Formula | C6H14N2 | Boiling Point | 199.4 °C at 760 mmHg |
| Molecular Weight | 114.191 | Flash Point | 80 °C |
| Transport Information | UN 3259 8/PG 2 | Appearance | off-white to brown crystals or chunks |
| Safety | 26-36/37/39-45 | Risk Codes | 22-34-20/21/22 |
| Molecular Structure |
|
Hazard Symbols |
 C
|
| Synonyms |
trans-1,4-Bisaminocyclohexane;trans-1,4-Cyclohexanediamine;1,4-trans-Diaminocyclohexane; |
Article Data | 14 |
trans-1,4-Diaminocyclohexane Synthetic route
- 556-48-9
1,4-Cyclohexanediol
A
- 2615-25-0
trans-1,4-cyclohexyldiamine
B
- 15827-56-2
cis-1,4-cyclohexanediamine
| Conditions | Yield |
|---|---|
| With dodecacarbonyl-triangulo-triruthenium; 4,5-bis((diisopropylphosphanyl)methyl)acridine; ammonia In tert-Amyl alcohol at 170℃; for 21h; Temperature; Inert atmosphere; Schlenk technique; Autoclave; | A 64.4% B 35.6% |
| Conditions | Yield |
|---|---|
| With nickel; methyl cyclohexane at 180℃; under 73550.8 Torr; Hydrogenation; | |
| With 1,4-dioxane; nickel at 180℃; under 110326 Torr; Hydrogenation; | |
| With nickel; decalin at 180℃; under 110326 Torr; Hydrogenation; |
- 54657-09-9
trans-1,4-di(carboxamido)cyclohexane
- 2615-25-0
trans-1,4-cyclohexyldiamine
| Conditions | Yield |
|---|---|
| With sodium hydroxide; bromine |
- 32175-29-4
trans-1.4-bis-methoxycarbonylamino-cyclohexane
- 2615-25-0
trans-1,4-cyclohexyldiamine
| Conditions | Yield |
|---|---|
| With hydrogenchloride |
| Conditions | Yield |
|---|---|
| at 180℃; under 73550.8 Torr; Hydrogenation; |
- 2615-25-0
trans-1,4-cyclohexyldiamine
| Conditions | Yield |
|---|---|
| With hydrogenchloride at 120℃; 7-stdg. Erhitzen; | |
| With hydrogenchloride at 100℃; 24-stdg. Erhitzen; |
- 2615-25-0
trans-1,4-cyclohexyldiamine
| Conditions | Yield |
|---|---|
| With water nachfolgendes Behandeln mit Wasser unter Druck bei 120grad und Erhitzen des Reaktionsproduktes mit konz.Salzsaeure unter Druck auf 140grad; |
- 106-50-3
1,4-phenylenediamine
A
- 2615-25-0
trans-1,4-cyclohexyldiamine
B
- 15827-56-2
cis-1,4-cyclohexanediamine
C
- 6850-65-3
p-hydroxycyclohexylamine
D
- 108-91-8
cyclohexylamine
E
- 108-93-0
cyclohexanol
| Conditions | Yield |
|---|---|
| With Ru/Al2O3; water; hydrogen In isopropyl alcohol at 90℃; under 30003 Torr; for 0.75h; Autoclave; Inert atmosphere; |
- 106-50-3
1,4-phenylenediamine
A
- 2615-25-0
trans-1,4-cyclohexyldiamine
B
- 15827-56-2
cis-1,4-cyclohexanediamine
| Conditions | Yield |
|---|---|
| With Ru/Al2O3; hydrogen In water; isopropyl alcohol at 90℃; under 30003 Torr; for 4h; Solvent; Temperature; Pressure; Autoclave; Inert atmosphere; |
- 106-50-3
1,4-phenylenediamine
A
- 2615-25-0
trans-1,4-cyclohexyldiamine
B
- 15827-56-2
cis-1,4-cyclohexanediamine
C
- 108-91-8
cyclohexylamine
| Conditions | Yield |
|---|---|
| With Ru/Al2O3; hydrogen In water; isopropyl alcohol at 90℃; under 30003 Torr; for 4h; Temperature; Autoclave; Inert atmosphere; |
trans-1,4-Diaminocyclohexane Chemical Properties
Molecular Structure of Trans-1,4-Diaminocyclohexane (CAS NO.2615-25-0):
IUPAC Name: Cyclohexane-1,4-diamine
CAS Registry Number: 2615-25-0
Molecular formula: C6H14N2
Molecular Weight: 114.19
Melting Point: 67-72 °C
Density: 0.939 g/cm3
Flash Point: 80 °C
Boiling Point: 199.4 °C at 760 mmHg
Index of Refraction: 1.483
Molar Refractivity: 34.77 cm3
Molar Volume: 121.5 cm3
Polarizability: 13.78×10-24cm3
Surface Tension: 37 dyne/cm
Enthalpy of Vaporization: 43.56 kJ/mol
Vapour Pressure: 0.342 mmHg at 25°C
Appearance: Off-white to brown crystals or chunks
Product Categories: Heterocycles series.
trans-1,4-Diaminocyclohexane Safety Profile
Hazard Codes:
C: 
Risk Statements about Trans-1,4-Diaminocyclohexane (CAS NO.2615-25-0):
R22: Harmful if swallowed.
R34: Causes burns.
R20/21/22: Harmful by inhalation, in contact with skin and if swallowed.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible).
F10: Keep under argon.
F34: Sensitive to CO2.
RIDADR: UN 3259 8/PG 2
WGK Germany: 2
HazardClass: 8
PackingGroup: II
trans-1,4-Diaminocyclohexane Specification
Trans-1,4-Diaminocyclohexane with CAS number of 2615-25-0 is also called for Timtec-bb sbb008553 ; Trans-1,4-cyclohexyldiamine ; Trans-1,4-cyclohexanediamine ; Trans-1,4-diaminocyclohexane ; Trans-hexahydro-1,4-phenylenediamine ; Tran(s)-cyclohexane-1,4-diamine ; Trans-1,4-diaminocyclohexane,99% ; 1,4-Cyclohexanediamine . Some useful information: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood. Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Corrosives area.
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