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Name |
2-Acetylfluorene |
EINECS | 212-310-5 |
CAS No. | 781-73-7 | Density | 1.157 g/cm3 |
PSA | 17.07000 | LogP | 3.46040 |
Solubility | water: 1 g/L (20 °C) | Melting Point |
128-129 °C(lit.) |
Formula | C15H12O | Boiling Point | 381.4 °C at 760 mmHg |
Molecular Weight | 208.26 | Flash Point | 169 °C |
Transport Information | N/A | Appearance | light yellow crystalline powder |
Safety | 24/25 | Risk Codes | N/A |
Molecular Structure | Hazard Symbols | N/A | |
Synonyms |
Ketone,fluoren-2-yl methyl (6CI,7CI,8CI);1-(9H-Fluoren-2-yl)ethanone;2-Acetyl-9H-fluorene;2-Fluorenyl methylketone;NSC 12351; |
Article Data | 45 |
Conditions | Yield |
---|---|
trifluoroacetic acid for 10h; Heating; | A 44% B 99% |
2-(4-acetylphenyl)benzyl chloride
1-(9H-fluoren-2-yl)ethanone
Conditions | Yield |
---|---|
With bis-triphenylphosphine-palladium(II) chloride; caesium carbonate; Trimethylacetic acid In tetrahydrofuran at 25℃; for 18h; Glovebox; Schlenk technique; Inert atmosphere; | 94% |
With palladium diacetate; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In 1,2-dimethoxyethane at 100℃; for 12h; Inert atmosphere; | 48% |
Conditions | Yield |
---|---|
With trifluoroacetic acid for 5h; Heating; | 89% |
Conditions | Yield |
---|---|
With N-trifluoroacetylimidazole; trifluoroacetic acid for 10h; Heating; | 82% |
With pyridin-2-yl trifluoromethanesulfonate; trifluoroacetic acid for 5h; Heating; | 81% |
Conditions | Yield |
---|---|
With trifluoroacetic acid for 5h; Heating; | 80% |
Conditions | Yield |
---|---|
With aluminum (III) chloride In 1,2-dichloro-ethane at 0℃; for 1h; Friedel Crafts acylation; | 79% |
With carbon disulfide; aluminium trichloride | |
With aluminium trichloride; nitrobenzene |
aluminium trichloride
9H-fluorene
acetic anhydride
nitrobenzene
1-(9H-fluoren-2-yl)ethanone
Conditions | Yield |
---|---|
anfangs unter Kuehlung; | |
anfangs unter Kuehlung; |
carbon disulfide
aluminium trichloride
9H-fluorene
acetyl chloride
1-(9H-fluoren-2-yl)ethanone
Conditions | Yield |
---|---|
at 5 - 10℃; |
aluminium trichloride
9H-fluorene
nitrobenzene
acetyl chloride
1-(9H-fluoren-2-yl)ethanone
Conditions | Yield |
---|---|
at 5 - 10℃; |
aluminium trichloride
9H-fluorene
acetic anhydride
1-(9H-fluoren-2-yl)ethanone
Conditions | Yield |
---|---|
anfangs unter Kuehlung; |
IUPAC Name: 2-Acetylfluorene
The MF of 2-Acetylfluorene (781-73-7) is C15H12O.
The MW of 2-Acetylfluorene (781-73-7) is 208.26.
Synonyms of 2-Acetylfluorene (781-73-7): 1-(9H-fluoren-2-yl)ethan-1-one ; Ethanone, 1- (9H-fluoren-2-yl)- ; 2-Acetofluorene ; 2-Fluorenyl methyl ketone
Product Categories: Fluorene Derivatives;Fluorenes, Flurenones;Fluorenes;Fluorenes & Fluorenones;C15 to C38;Carbonyl Compounds;Ketones
Form: light yellow crystalline powder
Index of Refraction: 1.627
EINECS: 212-310-5
Density: 1.157 g/ml
Flash Point: 169 °C
Boiling Point: 381.4 °C
Melting Point: 128-129 °C
Water Solubility: 1 g/L (20 ºC)
BRN: 1871711
2-Acetylfluorene (781-73-7) is used in organic synthesis.
In the presence of anhydrous aluminum chloride, fluorene with acetic anhydride occurs Friedel-Crafts reaction of 2 - acetyl-fluorene.
1. | dnr-esc 80 mg/L | MUREAV Mutation Research. 119 (1983),135. |
Mutation data reported. A flammable liquid. When heated to decomposition it emits acrid smoke and irritating vapors.
Safety information of 2-Acetylfluorene (781-73-7):
Safety Statements
24/25 Avoid contact with skin and eyes
WGK Germany 3
RTECS OB3800000
DOT Classification: 3; Label: Flammable Liquid
Store in a cool, dry place. Keep container closed when not in use.Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.