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Cas Database

Name	4-Methoxypyridoxine	EINECS	N/A
CAS No.	1464-33-1	Density	g/cm³
PSA	62.58000	LogP	0.73430
Solubility	N/A	Melting Point	181°C
Formula	C9H13 N O3	Boiling Point	404.2°Cat760mmHg
Molecular Weight	183.207	Flash Point	198.3°C
Transport Information	N/A	Appearance	N/A
Safety	Poison by ingestion, intravenous, and intraperitoneal routes. When heated to decomposition it emits toxic fumes of NO_x.	Risk Codes	N/A
Molecular Structure		Hazard Symbols	N/A
Synonyms	4-Methoxypyridoxine;4'-Methoxypyridoxine; 4'-O-Methylpyridoxine;5-Hydroxy-3-(hydroxymethyl)-4-(methoxymethyl)-6-methylpyridine; Ginkgotoxin; a4-O-Methylpyridoxol	Article Data	6

4-Methoxypyridoxine Synthetic route

: 67-56-1
methanol

: 65-23-6
5-hydroxy-6-methyl-3,4-pyridinedimethanol

: 1464-33-1
ginkgotoxin

Conditions

Conditions	Yield
In neat (no solvent) at 105℃; for 96h; regioselective reaction;	58%
In water at 15℃; Irradiation;	15%

: 67-56-1
methanol

: pyridoxine hydrochloride

: 1464-33-1
ginkgotoxin

Conditions

Conditions	Yield
With toluene-4-sulfonic acid at 110℃; for 3h; Sealed tube; Microwave irradiation;	56%

: 186581-53-3, 908094-01-9
diazomethane

: 1464-33-1
ginkgotoxin

: 19175-11-2
2-Methyl-3-methoxy-4-methoxymethyl-5-hydroxymethylpyridine

Conditions

Conditions	Yield
In diethyl ether; ethanol at 5 - 10℃;

: 1464-33-1
ginkgotoxin

: 65-23-6
5-hydroxy-6-methyl-3,4-pyridinedimethanol

Conditions

Conditions	Yield
With sulfuric acid at 150℃; for 12h;	85.5 % Chromat.

: 1464-33-1
ginkgotoxin

: 4'-O-methylpyridoxine-5'-phosphate

Conditions

Conditions	Yield
Stage #1: ginkgotoxin With phosphorus pentoxide at 60℃; for 3.5h; Stage #2: With water for 0.583333h; Heating; Further stages.;

4-Methoxypyridoxine Chemical Properties

IUPAC Name: 5-(Hydroxymethyl)-4-(methoxymethyl)-2-methylpyridin-
Synonyms: 3-Pyridinemethanol, 5-hydroxy-4-(methoxymethyl)-6-methyl- ; 4-(Methoxymethyl)pyridoxine hydrochloride ; 4-(Methoxymethyl)pyridoxol hydrochloride ; 4-Methoxymethylpyridoxine ; 4-Methoxypyridoxine ; 4-O-methoxypyridoxine
The Molecular Formula of 4-Methoxypyridoxine (CAS NO.1464-33-1):C₉H₁₃NO₃
The Molecular Weight of 4-Methoxypyridoxine (CAS NO.1464-33-1):183.2044g/mol
The Molecular Structure of 4-Methoxypyridoxine (CAS NO.1464-33-1):
Index of Refraction: 1.562
Molar Refractivity: 48.79 cm³
Molar Volume: 150.3 cm³
Surface Tension: 52 dyne/cm
Density: 1.218 g/ cm³
Flash Point: 198.3 °C
Enthalpy of Vaporization: 69.14 kJ/mol
Boiling Point: 404.2 °C at 760 mmHg
Vapour Pressure: 2.93E-07 mmHg at 25°C

4-Methoxypyridoxine Uses

4-Methoxypyridoxine ,whose cas register No. is 1464-33-1, can be used in organic synthesis.

4-Methoxypyridoxine Toxicity Data With Reference

1.	ipr-rat LD50:540 mg/kg	PSDTAP Proceedings of the European Society for the Study of Drug Toxicity. 4 (1964),179.
2.	orl-mus LD50:32 mg/kg	PSDTAP Proceedings of the European Society for the Study of Drug Toxicity. 4 (1964),179.
3.	ipr-mus LD50:23 mg/kg	PSDTAP Proceedings of the European Society for the Study of Drug Toxicity. 4 (1964),179.
4.	ivn-mus LD50:20 mg/kg	PSDTAP Proceedings of the European Society for the Study of Drug Toxicity. 4 (1964),179.
5.	ipr-dog LD50:8 mg/kg	PSDTAP Proceedings of the European Society for the Study of Drug Toxicity. 4 (1964),179.
6.	ipr-cat LD50:9 mg/kg	PSDTAP Proceedings of the European Society for the Study of Drug Toxicity. 4 (1964),179.
7.	ipr-rbt LD50:17 mg/kg	PSDTAP Proceedings of the European Society for the Study of Drug Toxicity. 4 (1964),179.

4-Methoxypyridoxine Safety Profile

Poison by ingestion, intravenous, and intraperitoneal routes. When heated to decomposition it emits toxic fumes of NO_x.

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