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Butylmagnesium chloride
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Name

Butylmagnesium chloride

 EINECS 211-739-5
CAS No. 693-04-9 Density 0.962 g/mL at 25 °C
PSA 0.00000 LogP 2.44360
Solubility reacts with water Melting Point -17°C
Formula C4H9ClMg Boiling Point 66 °C
Molecular Weight 116.873 Flash Point 115 °F
Transport Information UN 3399 4.3/PG 2 Appearance green-brown to brown solution
Safety 16-26-29-36/37/39-45-46-62 Risk Codes 11-14/15-19-34-48/20-63-65-67
Molecular Structure Molecular Structure of 693-04-9 (Butylmagnesium chloride) Hazard Symbols FlammableF,CorrosiveC
Synonyms

Butylmagnesiumchloride (6CI);Butylchloromagnesium;Butylmagnesiumm chloride;n-Butylmagnesium chloride;

Article Data 21

Butylmagnesium chloride Synthetic route

109-69-3

n-Butyl chloride

693-04-9

butyl magnesium bromide

Conditions
ConditionsYield
With magnesium In tetrahydrofuran-d8 at 80℃; under 5171.62 Torr; Inert atmosphere; Flow reactor;95%
With magnesium anthracene * 3 THF 1.) toluene, 90 deg C, 2.) r.t., 12 h; Yield given. Multistep reaction;
With magnesium In tetrahydrofuran at 23℃; Kinetics;
109-69-3

n-Butyl chloride

86901-19-1

9,10-dihydro-9,10-anthracendiyl-tris(THF)magnesium

A

47205-57-2

9,10-dibutyl-9,10-dihydro-anthracene

B

10394-60-2

9-butyl-9,10-dihydro-anthracene

C

693-04-9

butyl magnesium bromide

D

126694-91-5

2-butyl-1,2-dihydroanthracene

Conditions
ConditionsYield
In toluene for 24h; Ambient temperature; Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
...Expand
109-69-3

n-Butyl chloride

A

47205-57-2

9,10-dibutyl-9,10-dihydro-anthracene

B

10394-60-2

9-butyl-9,10-dihydro-anthracene

C

693-04-9

butyl magnesium bromide

D

126694-91-5

2-butyl-1,2-dihydroanthracene

Conditions
ConditionsYield
With magnesium anthracene * 3 THF In toluene at 50 - 80℃; for 2h; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
60-29-7

diethyl ether

109-69-3

n-Butyl chloride

magnesium

magnesium

693-04-9

butyl magnesium bromide

Conditions
ConditionsYield
Einfluss verschiedener Aktivatoren;
97-93-8

triethylaluminum

62202-86-2

n-butyl-ethylmagnesium

A

14989-29-8

hydridomagnesium chloride

B

(AlEt3)2*MgEt2

C

693-04-9

butyl magnesium bromide

D

2386-64-3

ethylmagnesium chloride

E

7786-30-3

magnesium chloride

Conditions
ConditionsYield
In 2-Methylpentane for 4383h; Reactivity;
...Expand
109-69-3

n-Butyl chloride

7439-95-4

magnesium

693-04-9

butyl magnesium bromide

Conditions
ConditionsYield
In tetrahydrofuran
With iodine In tetrahydrofuran for 0.5h; Heating / reflux;
With dibutyl ether at 50 - 60℃; for 5h;
4781-99-1

butyltriethoxy silane

EtOMgCl

A

78-10-4

tetraethoxy orthosilicate

B

693-04-9

butyl magnesium bromide

Conditions
ConditionsYield
In tert-butyl methyl ether; toluene at 20℃; Equilibrium constant; Solvent; Inert atmosphere;
109-69-3

n-Butyl chloride

magnesium

magnesium

693-04-9

butyl magnesium bromide

Conditions
ConditionsYield
With diethyl ether
693-58-3

1-Bromononane

693-04-9

butyl magnesium bromide

629-50-5

Tridecane

Conditions
ConditionsYield
With buta-1,3-diene; nickel dibromide In tetrahydrofuran at 0℃; for 0.25h; Kinetics; Reagent/catalyst; Temperature; Concentration;100%
With 1-Phenylprop-1-yne; copper dichloride In tetrahydrofuran at 25℃; for 0.25h;99 % Chromat.
With LaFe0.80Ni0.20O3; buta-1,3-diene at 20℃; for 5h;91 %Chromat.
With 1-Phenylprop-1-yne; copper dichloride In tetrahydrofuran at 40℃; for 48h; Catalytic behavior; Temperature;40 %Chromat.
With dicarbonyl(cyclopentadienyl)iron(II) chloride; buta-1,3-diene In tetrahydrofuran at 0 - 20℃; for 24h; Grignard Reaction; Inert atmosphere; Schlenk technique;54 %Chromat.
1071227-13-8

[3S,5S,7aR]-5-isopropyl-3-phenyl-hexahydropyrrolo[2,1-b]oxazole

693-04-9

butyl magnesium bromide

1071226-98-6

(2S)-2-((2R,5S)-2-butyl-5-isopropylpyrrolidin-1-yl)-2-phenylethanol

Conditions
ConditionsYield
Stage #1: [3S,5S,7aR]-5-isopropyl-3-phenyl-hexahydropyrrolo[2,1-b]oxazole; butyl magnesium bromide In tetrahydrofuran at 0 - 20℃; Inert atmosphere;
Stage #2: With ammonium chloride In tetrahydrofuran optical yield given as %de;		100%

Butylmagnesium chloride Specification

This chemical is called Magnesium, butylchloro-, and its CAS registry number is 693-04-9. With the molecular formula of C4H9ClMg, its product categories are Classes of Metal Compounds; Grignard Reagents; Grignard Reagents & Alkyl Metals; Mg (Magnesium) Compounds; Synthetic Organic Chemistry;T ypical Metal Compounds; AlkylChemical Synthesis; Organic Bases; Organometallic Reagents; Synthetic Reagents. In addition, this chemical should be sealed in the cool and dry place, away from oxides, acid , H2O, CO2.

Other characteristics of the Magnesium, butylchloro- can be summarised as followings: (1)#H bond acceptors: 0 #H bond donors: 0; (2)#Freely Rotating Bonds: 3.

Uses of this chemical: The Magnesium, butylchloro- could react with benzoic acid methyl ester, and obtain the 5-phenyl-nonan-5-ol. This reaction needs the solvent of diethyl ether. The yield is 60 %.

When you are using this chemical, please be cautious about it as the following: This chemical is flammable. It causes burns. You should wear suitable protective clothing if you use it. In case of contacting with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
1.SMILES: CCCC[Mg]Cl
2.InChI: InChI=1/C4H9.ClH.Mg/c1-3-4-2;;/h1,3-4H2,2H3;1H;/q;;+1/p-1/rC4H9ClMg/c1-2-3-4-6-5/h2-4H2,1H3
3.InChIKey: UUNGXYVLXYGZKH-PEDMJPSNAP

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