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Dichlorooxovanadium
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Name

Dichlorooxovanadium

 EINECS N/A
CAS No. 10213-09-9 Density g/cm3
PSA 17.07000 LogP 1.26020
Solubility slowly decomposed in water; soluble absolute alcohol, glacial acetic acid [MER06] Melting Point N/A
Formula Cl2O V Boiling Point °Cat760mmHg
Molecular Weight 137.847 Flash Point °C
Transport Information N/A Appearance N/A
Safety Mutation data reported. See also VANADIUM COMPOUNDS and CHLORIDES. Reacts violently with K. When heated to decomposition it emits toxic fumes of Cl− and VOx. Risk Codes N/A
Molecular Structure Molecular Structure of 10213-09-9 (vanadium dichloride oxide) Hazard Symbols Strong irritant to tissue.
Synonyms

Vanadium chloride(VOCl2) (6CI); Dichlorooxovanadium; NSC 79526; Oxovanadium(IV) chloride;Vanadium chloride oxide (VCl2O); Vanadium chloride oxide (VOCl2); Vanadiumdichloride oxide; Vanadium oxychloride (VOCl2); Vanadium oxydichloride; Vanadylchloride; Vanadyl chloride (VOCl2); Vanadyl dichloride

Article Data 7

Dichlorooxovanadium Synthetic route

7727-18-6

vanadium(V) oxychloride

A

12035-98-2

vanadium(II) oxide

B

13520-87-1

vanadium oxychloride

C

10213-09-9

vanadyl chloride

Conditions
ConditionsYield
In gas byproducts: Cl2; Irradiation (UV/VIS); irradiation of VOCl3 by pulsed CO2 laser radiation; detected by luminescence spectroscopy;

(C5H5)2V(2+) Chlorid

10213-09-9

vanadyl chloride

Conditions
ConditionsYield
With oxygen In not given
With O2 In not given
184477-10-9

vanadyl-p-toluene sulfinate

10213-09-9

vanadyl chloride

Conditions
ConditionsYield
With hydrogenchloride In 1,4-dioxane

vanadia

7782-50-5

chlorine

A

10213-09-9

vanadyl chloride

B

7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
In neat (no solvent) byproducts: VCl3, O2; 600-1000°C;

VO(biur)2Cl2

A

108-19-0

BIURET

B

10213-09-9

vanadyl chloride

Conditions
ConditionsYield
In solid heating in range 220-500°C; not isolated;

oxovanadium(IV) sulfate

10361-37-2

barium(II) chloride dihydrate

10213-09-9

vanadyl chloride

Conditions
ConditionsYield
In ethanol at 25℃; for 1h;
683-60-3

sodium isopropylate

10213-09-9

vanadyl chloride

119254-23-8

vanadyl diisopropoxide

Conditions
ConditionsYield
In ethanol byproducts: NaCl; vacuum., mixing of alcoholic VOCl2 and soln. of NaO(i-Pr) in EtOH, room temp.; removal of pptd. NaCl (freezing, liquid N2), evapn. (ca. 40°C); elem. anal.;95%
141-52-6

sodium ethanolate

10213-09-9

vanadyl chloride

67332-62-1

vanadyl diethoxide

Conditions
ConditionsYield
In ethanol byproducts: NaCl; vacuum., mixing of alcoholic VOCl2 and soln. of NaOEt in EtOH, room temp.; removal of pptd. NaCl (freezing, liquid N2), evapn. (ca. 40°C); elem. anal.;95%
154270-06-1

4’-ferrocenyl-2,2’:6’,2’’-terpyridine

1393710-37-6

1,7-bis(3-methoxyphenyl)-1,6-heptadiene-3,5-dione

sodium perchlorate

10213-09-9

vanadyl chloride

[VO(4'-ferrocenyl-2,2':6',2''-terpyridine)(bDHC)](ClO4)

Conditions
ConditionsYield
Stage #1: 1,7-bis(3-methoxyphenyl)-1,6-heptadiene-3,5-dione; vanadyl chloride With sodium hydroxide In water for 0.5h;
Stage #2: 4’-ferrocenyl-2,2’:6’,2’’-terpyridine In methanol; chloroform; water for 0.5h;
Stage #3: sodium perchlorate In methanol; chloroform; water		80%
458-37-7

curcumin

58345-97-4

4'-phenyl-2,2':6',2-terpyridine

sodium perchlorate

10213-09-9

vanadyl chloride

[VO(4'-phenyl-2,2':6',2''-terpyridine)(Curc)](ClO4)

Conditions
ConditionsYield
Stage #1: curcumin; vanadyl chloride With sodium hydroxide In water for 0.5h;
Stage #2: 4'-phenyl-2,2':6',2-terpyridine In methanol; chloroform; water for 0.5h;
Stage #3: sodium perchlorate In methanol; chloroform; water		72%

Dichlorooxovanadium Chemical Properties

Chemical Name: Vanadium dichloride oxide
IUPAC NAME: Oxovanadium dihydrochloride
CAS No.: 10213-09-9
EINECS: 233-517-7
Molecular Formula: Cl2H2OV
Molecular Weight: 139.86 g/mol
Following is the structure of Dichlorooxovanadium (10213-09-9):


The chemical synonymous of Dichlorooxovanadium (10213-09-9) are Vanadium dichloride oxide ; Vanadium oxydichloride ; Vanadyl dichloride ; Vanadyloxychloride ; Vanadyloxydichloride ; Dichlorooxovanadium ; Dichlorooxo-vanadium ; Dichlorooxovanadium(Iv)

Dichlorooxovanadium Toxicity Data With Reference

1.    

mrc-bcs 400 mmol/L

     MUREAV    Mutation Research. 77 (1980),109.

Dichlorooxovanadium Consensus Reports

EPA Genetic Toxicology Program.

Dichlorooxovanadium Safety Profile

Mutation data reported. See also VANADIUM COMPOUNDS and CHLORIDES. Reacts violently with K. When heated to decomposition it emits toxic fumes of Cl− and VOx.

Dichlorooxovanadium Standards and Recommendations

ACGIH TLV: TWA 0.05 mg(V2O5)/m3
NIOSH REL: (Vanadium Compounds) CL 0.05 mg(V)/m3/15M

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