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CAS No.: | 10213-09-9 |
---|---|
Name: | vanadium dichloride oxide |
Article Data: | 7 |
Molecular Structure: | |
Formula: | Cl2O V |
Molecular Weight: | 137.847 |
Synonyms: | Vanadium chloride(VOCl2) (6CI); Dichlorooxovanadium; NSC 79526; Oxovanadium(IV) chloride;Vanadium chloride oxide (VCl2O); Vanadium chloride oxide (VOCl2); Vanadiumdichloride oxide; Vanadium oxychloride (VOCl2); Vanadium oxydichloride; Vanadylchloride; Vanadyl chloride (VOCl2); Vanadyl dichloride |
Density: | g/cm3 |
Boiling Point: | °Cat760mmHg |
Flash Point: | °C |
Solubility: | slowly decomposed in water; soluble absolute alcohol, glacial acetic acid [MER06] |
Hazard Symbols: | Strong irritant to tissue. |
Safety: | Mutation data reported. See also VANADIUM COMPOUNDS and CHLORIDES. Reacts violently with K. When heated to decomposition it emits toxic fumes of Cl− and VOx. |
PSA: | 17.07000 |
LogP: | 1.26020 |
vanadium(V) oxychloride
A
vanadium(II) oxide
B
vanadium oxychloride
C
vanadyl chloride
Conditions | Yield |
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In gas byproducts: Cl2; Irradiation (UV/VIS); irradiation of VOCl3 by pulsed CO2 laser radiation; detected by luminescence spectroscopy; |
vanadyl chloride
Conditions | Yield |
---|---|
With oxygen In not given | |
With O2 In not given |
vanadyl-p-toluene sulfinate
vanadyl chloride
Conditions | Yield |
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With hydrogenchloride In 1,4-dioxane |
Conditions | Yield |
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In neat (no solvent) byproducts: VCl3, O2; 600-1000°C; |
Conditions | Yield |
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In solid heating in range 220-500°C; not isolated; |
Conditions | Yield |
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In ethanol at 25℃; for 1h; |
Conditions | Yield |
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In ethanol byproducts: NaCl; vacuum., mixing of alcoholic VOCl2 and soln. of NaO(i-Pr) in EtOH, room temp.; removal of pptd. NaCl (freezing, liquid N2), evapn. (ca. 40°C); elem. anal.; | 95% |
Conditions | Yield |
---|---|
In ethanol byproducts: NaCl; vacuum., mixing of alcoholic VOCl2 and soln. of NaOEt in EtOH, room temp.; removal of pptd. NaCl (freezing, liquid N2), evapn. (ca. 40°C); elem. anal.; | 95% |
4’-ferrocenyl-2,2’:6’,2’’-terpyridine
1,7-bis(3-methoxyphenyl)-1,6-heptadiene-3,5-dione
vanadyl chloride
Conditions | Yield |
---|---|
Stage #1: 1,7-bis(3-methoxyphenyl)-1,6-heptadiene-3,5-dione; vanadyl chloride With sodium hydroxide In water for 0.5h; Stage #2: 4’-ferrocenyl-2,2’:6’,2’’-terpyridine In methanol; chloroform; water for 0.5h; Stage #3: sodium perchlorate In methanol; chloroform; water | 80% |
Conditions | Yield |
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Stage #1: curcumin; vanadyl chloride With sodium hydroxide In water for 0.5h; Stage #2: 4'-phenyl-2,2':6',2-terpyridine In methanol; chloroform; water for 0.5h; Stage #3: sodium perchlorate In methanol; chloroform; water | 72% |
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Chemical Name: Vanadium dichloride oxide
IUPAC NAME: Oxovanadium dihydrochloride
CAS No.: 10213-09-9
EINECS: 233-517-7
Molecular Formula: Cl2H2OV
Molecular Weight: 139.86 g/mol
Following is the structure of Dichlorooxovanadium (10213-09-9):
The chemical synonymous of Dichlorooxovanadium (10213-09-9) are Vanadium dichloride oxide ; Vanadium oxydichloride ; Vanadyl dichloride ; Vanadyloxychloride ; Vanadyloxydichloride ; Dichlorooxovanadium ; Dichlorooxo-vanadium ; Dichlorooxovanadium(Iv)
1. | mrc-bcs 400 mmol/L | MUREAV Mutation Research. 77 (1980),109. |
EPA Genetic Toxicology Program.
Mutation data reported. See also VANADIUM COMPOUNDS and CHLORIDES. Reacts violently with K. When heated to decomposition it emits toxic fumes of Cl− and VOx.
ACGIH TLV: TWA 0.05 mg(V2O5)/m3
NIOSH REL: (Vanadium Compounds) CL 0.05 mg(V)/m3/15M