- Hexafluoropropylene
- Hexafluoropropylene dimer
- Hexafluoropropylene oxide
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Cas Database |
| Name |
Hexafluoropropylene |
EINECS | 204-127-4 |
| CAS No. | 116-15-4 | Density | 1.442 g/cm3 |
| PSA | 0.00000 | LogP | 2.62630 |
| Solubility |
Stability
Toxicology
Toxicity data |
Melting Point |
-153 ºC |
| Formula | C3F6 | Boiling Point | -28 ºC |
| Molecular Weight | 150.023 | Flash Point | °C |
| Transport Information | UN 1858 | Appearance | colourless gas |
| Safety | Mildly toxic by inhalation. Explosive reaction with Grignard reagents (e.g., phenylmagnesium bromide). Reacts with tetrafluorethylene + air to form explosive peroxides. When heated to decomposition it emits toxic fumes of F−. | Risk Codes | R20;R37 |
| Molecular Structure |
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Hazard Symbols |
|
| Synonyms |
Propene,hexafluoro- (8CI);1,1,2,3,3,3-Hexafluoro-1-propene;1,1,2,3,3,3-Hexafluoropropene;Esafluoropropene;F 1216;HFC 1216;Hexafluoro-1-propene;Hexafluoropropene;Hexafluoropropylene;PFC 1216;Perfluoro-1-propene;Perfluoropropene;Perfluoropropylene;Propylene hexafluoride;R 1216; |
Article Data | 136 |
Hexafluoropropylene Synthetic route
| Conditions | Yield |
|---|---|
| With silicon carbide at 450 - 850℃; for 3.33333E-05h; | 96.5% |
| at 760 - 860℃; unter vermindertem Druck; | |
| at 700℃; bei der thermischen Zersetzung; |
| Conditions | Yield |
|---|---|
| In further solvent(s) decomposition on boiling in dibutyl ether;; | A 76% B 6% |
| In further solvent(s) decomposition on boiling in dibutyl ether;; | A 76% B 6% |
| Conditions | Yield |
|---|---|
| In diethyl ether warming from -78 to 20°C and heating under reflux, 1 hour;; | 70.5% |
| In diethyl ether warming from -78 to 20°C and heating under reflux, 1 hour;; | 70.5% |
- 756-13-8
perfluoro-2-methylpentan-3-one
A
- 116-15-4
perfluoropropylene
B
- 422-61-7
perfluoropropanoyl fluoride
| Conditions | Yield |
|---|---|
| With cesium fluoride at 250℃; for 2h; Product distribution; | A 68% B n/a |
- 1526-49-4
ethyl heptafluoroisobutyrate
- 591-51-5
phenyllithium
A
- 116-15-4
perfluoropropylene
B
- 93-89-0
benzoic acid ethyl ester
C
- 56112-35-7
perfluoroisopropyl phenyl ketone
| Conditions | Yield |
|---|---|
| In diethyl ether at -110℃; for 0.166667h; C6H5Li added to ester; | A n/a B n/a C 65% |
- 355-49-7
perfluorocetane
A
- 116-14-3
polytetrafluoroethylene
B
- 116-15-4
perfluoropropylene
C
- 357-26-6
octafluoro-1-butene
| Conditions | Yield |
|---|---|
| at 195 - 500℃; under 75.7576 Torr; Temperature; Pressure; Pyrolysis; | A 62.4% B 24.3% C 6.2% |
- 661-95-0
1,2-dibromohexafluoropropane
A
- 2252-78-0
1-bromo-1,1,2,3,3,3-hexafluoro-propane
B
- 116-15-4
perfluoropropylene
C
- 431-63-0
1,1,1,2,3,3-hexafluoropropane
D
- 2252-80-4
2-bromo-1,1,1,2,3,3-hexafluoro-propane
| Conditions | Yield |
|---|---|
| With tri-n-butyl-tin hydride for 1.5h; Product distribution; Heating; | A 53% B 3% C 14% D 21% |
| Conditions | Yield |
|---|---|
| at 195 - 600℃; under 75.7576 Torr; Temperature; Pressure; Pyrolysis; | A 50.3% B 28.9% |
- 34557-54-5
methane
- 115-25-3
Octafluorocyclobutane
A
- 116-14-3
polytetrafluoroethylene
B
- 116-15-4
perfluoropropylene
C
- 75-38-7
Vinylidene fluoride
D
- 754-12-1
2,3,3,3-tetrafluoro-propene
E
- 359-11-5
1,1,2-trifluoroethylene
| Conditions | Yield |
|---|---|
| at 250 - 800℃; under 150.015 Torr; for 0.000175h; Temperature; | A 45.8% B 7.4% C 10.4% D 8.4% E 9.5% |
- 355-49-7
perfluorocetane
A
- 116-14-3
polytetrafluoroethylene
B
- 116-15-4
perfluoropropylene
C
- 115-25-3
Octafluorocyclobutane
| Conditions | Yield |
|---|---|
| at 195 - 550℃; under 75.7576 Torr; Temperature; Pressure; Pyrolysis; | A 36.1% B 42.7% C 6.1% |
Hexafluoropropylene Consensus Reports
Hexafluoropropylene Standards and Recommendations
Hexafluoropropylene Specification
The Hexafluoropropene, with the cas registry number 116-15-4, has the systematic name of 1,1,2,3,3,3-hexafluoroprop-1-ene. This is a kind of colorless nonflammable air with no odour.
The characteristics of this chemical are as follows: (1)ACD/LogP: 1.88; (2)ACD/LogD (pH 5.5): 1.88; (3)ACD/LogD (pH 7.4): 1.88; (4)ACD/BCF (pH 5.5): 15.8; (5)ACD/BCF (pH 7.4): 15.8; (6)ACD/KOC (pH 5.5): 251.01; (7)ACD/KOC (pH 7.4): 251.01; (8)Index of Refraction: 1.253; (9)Molar Refractivity: 16.63 cm3; (10)Molar Volume: 104 cm3; (11)Polarizability: 6.59× 10-24 cm3; (12)Surface Tension: 9.6 dyne/cm ; (13)Density: 1.442 g/cm3; (14)Enthalpy of Vaporization: 21.51 kJ/mol; (15)Vapour Pressure: 4770 mmHg at 25°C; (16)Exact Mass: 149.990419 ; (17)MonoIsotopic Mass: 149.990419 ; (18)Heavy Atom Count: 9 ; (19)Complexity: 126.
Use of Hexafluoropropene: Hexafluoropropene reacts to produce 1,2-dibromo-1,1,2,3,3,3-hexafluoro-propane, with the following condition: solvent: bromine; other condition: im Licht.
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As to its usage, it is widely applied in many ways. It could be used in producing fluro fined chemistry, pharmaceutic intermediate, extinguishant and fluoropolymer material; It could also be used in the material for the PSAIM, fluorocarbon oil, HFPO and so on.
While dealing with this chemical, you should be very cautious. This is irritant to respiratory system and may cause inflammation to the skin or other mucous membranes; Then it may cause damage to health, and if in case of fire and/or explosion, do not breathe fumes.
Additionally, the following datas could be converted into the molecular structure:
(1)SMILES:F/C(F)=C(/F)C(F)(F)F
(2)InChI:InChI=1/C3F6/c4-1(2(5)6)3(7,8)9
Below are the toxicity information of this chemical:
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| mouse | LC50 | inhalation | 750ppm/4H (750ppm) | Archives des Maladies Professionnelles de Medecine du Travail et de Securite Sociale. Vol. 27, Pg. 509, 1966. | |
| rat | LC50 | inhalation | 11200mg/m3/4H (11200mg/m3) | BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY) | Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 15(2), Pg. 38, 1971. |
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