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L-Glucose

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Name

L-Glucose

EINECS 213-068-3
CAS No. 921-60-8 Density 1.732 g/cm3
PSA 118.22000 LogP -3.37880
Solubility H2O: 0.1 g/mL, clear, colorless Melting Point 153-156 ºC(lit.)
Formula C6H12O6 Boiling Point 410.8 ºC at 760 mmHg
Molecular Weight 180.158 Flash Point 202.2 ºC
Transport Information UN 2910 7 Appearance white powder
Safety 16-26-36-53-36/37-25 Risk Codes 11-36/37/38-63-62-46-36/38-21
Molecular Structure Molecular Structure of 921-60-8 (L-Glucose) Hazard Symbols FlammableFIrritantXi,HarmfulXn,RadioactiveR
Synonyms

L(-)-Glucose;Glucose, (L)-isomer;

Article Data 95

L-Glucose Synthetic route

2,3:4,5-di-O-isopropylidene-D-gulose

921-60-8

L-glucose

Conditions
ConditionsYield
With DOWEX(α)50WX8-200 In water at 20℃; for 48h;100%

2-Chloro-9-((3aR,4R,6R,6aR)-2,2,3a,6-tetramethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-9H-purin-6-ylamine

921-60-8

L-glucose

Conditions
ConditionsYield
With mercaptoethyl alcohol; Tris*HCl buffer; manganese(ll) chloride; fucose isomerase at 25℃; for 72h;28.9%

6'-O-(3''-O-methylgalloyl)arbutin

A

50-99-7

D-glucose

B

921-60-8

L-glucose

Conditions
ConditionsYield
With hydrogenchloride In water at 90℃; for 1h;A 26%
B n/a
5328-37-0

L-arabinose

921-60-8

L-glucose

Conditions
ConditionsYield
With pyridine; hydrogen cyanide Beim Behandeln des Reaktionsprodukts mit wss.Salzsaeure unter gleichzeitigem Hydrieren an Palladium/Bariumsulfat;
Multi-step reaction with 2 steps
1: sodium methylate
2: aqueous NaOH-solution / beim anschliessend mit wss.Schwefelsaeure
View Scheme
69257-51-8

1-Desoxy-1-nitro-L-gluco-hexitol

921-60-8

L-glucose

Conditions
ConditionsYield
With sodium hydroxide beim anschliessend mit wss.Schwefelsaeure;

(2S,3R,4S,5S)-6-Benzhydryloxy-2,3,4,5-tetrahydroxy-hexanal

921-60-8

L-glucose

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal In methanol Yield given;
L-gluconic acid-lactone

L-gluconic acid-lactone

921-60-8

L-glucose

Conditions
ConditionsYield
With sodium amalgam; sulfuric acid
With sodium amalgam; sodium hydrogen oxalate
157663-13-3

L-gluconic acid

sodium amalgam

sodium amalgam

921-60-8

L-glucose

Conditions
ConditionsYield
das Lacton reagiert;
52153-09-0

L-glucono-1,5-lactone

74464-44-1

γ lactone of/the/ l-gluconic acid

921-60-8

L-glucose

Conditions
ConditionsYield
Stage #1: L-glucono-1,5-lactone; γ lactone of/the/ l-gluconic acid With sodium tetrahydroborate In water at -5 - 5℃; for 0.333333h;
Stage #2: With acetic acid In water
1351356-85-8

2-hydroxybenzoyl-β-L-glucopyranosyl (2->1)-β-L-glucopyranosyl (2->1)-β-L-glucopyranosyl (2->1) β-Lglucopyranoside

A

921-60-8

L-glucose

B

69-72-7

salicylic acid

Conditions
ConditionsYield
Acidic conditions;

L-Glucose Specification

L-Glucose(CAS NO.921-60-8), its Synonyms are Glucose, (L)-isomer; L(-)-Glucose. It is an organic compound with formula C6H12O6 or H–(C=O)–(CHOH)5–H, specifically one of the aldohexose monosaccharides. L-Glucose does not occur naturally in higher living organisms, but can be synthesized in the laboratory.

Physical properties about L-Glucose are: (1)ACD/LogP: -2.49; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): -2.49; (4)ACD/LogD (pH 7.4): -2.49; (5)ACD/BCF (pH 5.5): 1.00; (6)ACD/BCF (pH 7.4): 1.00; (7)ACD/KOC (pH 5.5): 1.05; (8)ACD/KOC (pH 7.4): 1.05; (9)#H bond acceptors: 6; (10)#H bond donors: 5; (11)#Freely Rotating Bonds: 6; (12)Index of Refraction: 1.635; (13)Molar Refractivity: 37.254 cm3; (14)Molar Volume: 104.015 cm3; (15)Polarizability: 14.769 10-24cm3; (16)Surface Tension: 81.7509994506836 dyne/cm; (17)Density: 1.732 g/cm3; (18)Flash Point: 202.243 °C; (19)Enthalpy of Vaporization: 76.626 kJ/mol; (20)Boiling Point: 410.797 °C at 760 mmHg;

Uses of L-Glucose: L-Glucose was once proposed as a low-calorie sweetener and it is suitable for patients with diabetes mellitus. L-Glucose was also found to be a laxative, and has been proposed as a colon-cleansing agent which would not produce the disruption of fluid and electrolyte levels associated with the significant liquid quantities of bad-tasting osmotic laxatives conventionally used in preparation for colonoscopy.

When you are using this chemical, please be cautious about it as the following:
1. Keep away from sources of ignition - No smoking;
2. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice;
3. Wear suitable protective clothing;
4. Avoid exposure - obtain special instruction before use;
5. Wear suitable protective clothing and gloves;
6. Avoid contact with eyes;

You can still convert the following datas into molecular structure:
(1)InChI=1S/C6H12O6/c7-1-3(9)5(11)6(12)4(10)2-8/h1,3-6,8-12H,2H2/t3-,4+,5+,6+/m1/s1 ;
(2)InChIKey=GZCGUPFRVQAUEE-VANKVMQKSA-N;
(3)SmilesO=C[C@H]([C@@H]([C@H]([C@@H](O)CO)O)O)O

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