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Lead dioxide

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Name

Lead dioxide

EINECS 215-174-5
CAS No. 1309-60-0 Density 9.38 g/cm3
PSA 34.14000 LogP -0.61840
Solubility insoluble in water Melting Point 290 °C
Formula PbO2 Boiling Point N/A
Molecular Weight 239.199 Flash Point N/A
Transport Information UN 1872 5.1/PG 3 Appearance black powder
Safety 53-45-60-61 Risk Codes 61-8-20/22-33-50/53-62
Molecular Structure Molecular Structure of 1309-60-0 (Lead(IV) oxide) Hazard Symbols OxidizingO, ToxicT, DangerousN
Synonyms

dioxolead;Lead Dioxide;

 

Lead dioxide Synthetic route

116801-42-4

2,2-bis(4-pyrrolidinophenyl)propionic acid

1309-60-0

lead(IV) oxide

1,1-bis(4-pyrrolidinophenyl)ethylene

Conditions
ConditionsYield
With sodium hydroxide In toluene76%

2,2-bis(4-dimethylaminophenyl)propionic acid

1309-60-0

lead(IV) oxide

7478-69-5

1,1-Bisethylene

Conditions
ConditionsYield
With sodium hydroxide In benzene74%

2,2-bis(4-morpholinophenyl)propionic acid

1309-60-0

lead(IV) oxide

1,1-bis(4-morpholinophenyl)ethylene

Conditions
ConditionsYield
With sodium hydroxide In toluene46.3%
106-44-5

p-cresol

1309-60-0

lead(IV) oxide

77249-33-3

4-fluoro-4-methylcyclohexa-2,5-dien-1-one

Conditions
ConditionsYield
With HF In pyridine; dichloromethane36%
371-41-5

4-Fluorophenol

1309-60-0

lead(IV) oxide

4,4-difluorohexadienone

Conditions
ConditionsYield
With HF In pyridine; dichloromethane26%
1309-60-0

lead(IV) oxide

95-57-8

2-monochlorophenol

105277-17-6

2-chloro-4,4-difluorocyclohexadienone

Conditions
ConditionsYield
With HF In pyridine; pentane25%
1309-60-0

lead(IV) oxide

108-39-4

3-methyl-phenol

105277-19-8

4,4-difluoro-3-methylcyclohexadienone

Conditions
ConditionsYield
With HF In pyridine; dichloromethane17%
1309-60-0

lead(IV) oxide

106-48-9

4-chloro-phenol

4-chloro-4-fluorocyclohexa-2,5-dienone

Conditions
ConditionsYield
With HF In pyridine; dichloromethane; pentane15%
1121-78-4

5-Hydroxy-2-methylpyridine

1309-60-0

lead(IV) oxide

34237-07-5

3,3'-Dihydroxy-6,6'-dimethyl-2,2'-bipyridine

Conditions
ConditionsYield
In toluene9.3%
1309-60-0

lead(IV) oxide

122-79-2

Phenyl acetate

42539-98-0

4,4-difluorocyclohexa-2,5-dienone

Conditions
ConditionsYield
With HF In pyridine; dichloromethane9.2%

Lead dioxide Consensus Reports

Reported in EPA TSCA Inventory. Lead and its compounds are on the Community Right-To-Know List.

Lead dioxide Standards and Recommendations

OSHA PEL: TWA 0.05 mg(Pb)/m3
ACGIH TLV: TWA 0.15 mg(Pb)/m3
NIOSH REL: (Inorganic Lead) TWA 0.10 mg(Pb)/m3
DOT Classification:  5.1; Label: Oxidizer

Lead dioxide Specification

The Lead dioxide, with the CAS registry number 1309-60-0, is also known as Bioxyde de plomb. It belongs to the product category of Inorganics. Its EINECS registry number is 215-174-5. This chemical's molecular formula is PbO2 and molecular weight is 239.1988. Its IUPAC name is called dioxolead. This chemical is brown to black powder. Lead dioxide is a strong oxidizing agent which is used in the manufacture of matches, pyrotechnics, dyes and other chemicals. It also has several important applications in electrochemistry, in particular as a component of lead acid batteries.

Physical properties of Lead dioxide: (1)H-Bond Donor: 0; (2)H-Bond Acceptor: 2; (3)Rotatable Bond Count: 0; (4)Exact Mass: 239.966465; (5)MonoIsotopic Mass: 239.966465; (6)Topological Polar Surface Area: 34.1; (7)Heavy Atom Count: 3; (8)Formal Charge: 0; (9)Complexity: 18.3; (10)Isotope Atom Count: 0; (11)Defined Atom StereoCenter Count: 0; (12)Undefined Atom StereoCenter Count: 0; (13)Defined Bond StereoCenter Count: 0; (14)Undefined Bond StereoCenter Count: 0; (15)Covalently-Bonded Unit Count: 1.

Preparation of Lead dioxide: this chemical can be prepared by PbAC2·3H2O and AR concentrated solution of sodium carbonate. This reaction will need reagent Cl2.

 Pb(CH3COO)2+2Na2CO3+Cl2=PbO2↓+2CH3COONa+2NaCl+2CO2↑

Uses of Lead dioxide: Lead dioxide is well known for being a good oxidizing agent with example reaction listed below:

2 MnSO4 + 5 PbO2 + 6 HNO3 → 2 HMnO4 + 2 PbSO4↓ + 3 Pb(NO3)2 + 2 H2O
2 Cr(OH)3 + 10 KOH + 3 PbO2↓ → 2 K2CrO4 + 3 K2PbO2 + 8 H2O

When you are using this chemical, please be cautious about it as the following:
This chemical can react exothermically with other chemicals. This chemical that at low level will cause damage to health. It may present an immediate or delayed danger to one or more components of the environment. In addition, it is harmful by inhalation and if swallowed and harmful to aquatic organisms which may cause long-term adverse effects in the aquatic environment. In case of accident or if you feel unwell seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: O=[Pb]=O
(2)InChI: InChI=1S/2O.Pb
(3)InChIKey: YADSGOSSYOOKMP-UHFFFAOYSA-N

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
guinea pig LD50 intraperitoneal 220mg/kg (220mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
 

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