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Basic information

  • Name:
  • Methanesulfonic acid

  • CAS No.:
  • 75-75-2

  • Molecular Structure:
  • Formula:
  • CH4O3S
  • Molecular Weight:
  • 96.10
  • Deleted CAS:
  • 115449-98-4|125756-91-4|44209-64-5|44209-72-5|62203-24-1|87128-90-3|98527-29-8
  • Synonyms:
  • Methane Sulfonic Acid;MCAT1201;Methylsulfonic acid;NSC 3718;Methanesulfonicacid;
  • EINECS:
  • 200-898-6
  • Density:
  • 1.511 g/cm3
  • Melting Point:
  • 19 °C
  • Boiling Point:
  • 167 °C (10 torr)
  • Flash Point:
  • >230 °F
  • Appearance:
  • colourless or light yellow liquid
  • Hazard Symbols:
  • CorrosiveC
  • Risk Codes:
  • 34-22
  • Safety Description:
  • 26-36-45-1/2-36/37/39 Details
  • Transport Information:
  • UN 3265 8/PG 2

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Chemistry

Methanesulfonic acid is a colorless liquid with the chemical formula CH3SO3H. It is the simplest of the alkylsulfonic acids. Salts and esters of methanesulfonic acid are known as mesylates.
Odor: Faint sulfur trioxide odor to odorless.
Melting point: 20 °C
Boiling point:167 °C (13.33kPa)
density: 1.4812 g/mL at 18 °C

Uses

Methanesulfonic acid may be considered an intermediate compound between sulfuric acid (H2SO4), and methylsulfonylmethane ((CH3)2SO2), effectively replacing an -OH group with a -CH3 group at each step. This pattern can extend no further in either direction without breaking down the -SO2 group.
Methanesulfonic acid can be used in the generation of BH3. By reacting methanesulfonic acid with NaBH4 in an aprotic solvent such as THF or DMS, the complex of BH3 and the solvent is formed.

Safety Profile

Methanesulfonic acid is corrosive. It is harmful if it is swallowed or inhaled, and its vapor is severely irritating to eyes and respiratory tract.
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