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Silane, diiodo-(7CI,8CI,9CI)

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Name

Silane, diiodo-(7CI,8CI,9CI)

EINECS N/A
CAS No. 13760-02-6 Density 2.834 g/mL at 25 °C(lit.)
PSA 0.00000 LogP 0.85520
Solubility N/A Melting Point -1°C
Formula H2I2Si Boiling Point 153.7 °C at 760 mmHg
Molecular Weight 283.91 Flash Point 101 °F
Transport Information N/A Appearance Clear liquid
Safety 16-26-27-28-36/37/39-45 Risk Codes 10-14-20/21/22-34
Molecular Structure Molecular Structure of 13760-02-6 (DIIODOSILANE) Hazard Symbols CorrosiveC
Synonyms

Diiodosilane;

Article Data 10

Silane, diiodo-(7CI,8CI,9CI) Synthetic route

4109-96-0

Dichlorosilane

lithium iodide

13760-02-6

diiodosilane

Conditions
ConditionsYield
In pentane at -70 - 35℃; for 16h; Temperature; Solvent; Inert atmosphere; Large scale;77%
at 40℃; under 1277.21 - 2311.54 Torr; for 0.08h; Temperature;45.3 g
12185-10-3

phosphorous

13598-42-0

iodosilane

A

13760-02-6

diiodosilane

B

128166-50-7

P(SiH3)I2

C

7440-21-3

monosilane

Conditions
ConditionsYield
In neat (no solvent) byproducts: H2; heating in evacuated, sealed tube to 100°C;;
12185-10-3

phosphorus

13598-42-0

iodosilane

A

13760-02-6

diiodosilane

B

128166-50-7

P(SiH3)I2

C

7440-21-3

monosilane

Conditions
ConditionsYield
byproducts: H2; at 100°C;
12185-10-3

phosphorus

13598-42-0

iodosilane

A

13760-02-6

diiodosilane

B

Si2H4

C

P(SiH3)4I

D

7803-51-2

phosphan

Conditions
ConditionsYield
byproducts: H2; at 20°C;A <1
B n/a
C n/a
D n/a
10034-85-2

hydrogen iodide

7440-21-3

monosilane

A

13760-02-6

diiodosilane

B

13465-72-0

triiodo silane

C

13465-84-4

silicon tetraiodide

D

13598-42-0

iodosilane

Conditions
ConditionsYield
aluminium(III) iodide In neat (no solvent) reaction at 80°C and 500 Torr;; fractional distillation and condensation;;
aluminium(III) iodide In neat (no solvent) reaction at 80°C and 500 Torr;; fractional distillation and condensation;;
775-12-2

diphenylsilane

10034-85-2

hydrogen iodide

13760-02-6

diiodosilane

Conditions
ConditionsYield
In not given according to Fritz, G., Kummer D., Chem. Ber., 94 (1961) p. 1143; at -40°C;
4109-96-0

Dichlorosilane

lithium iodide

A

13760-02-6

diiodosilane

B

21479-74-3

SiH2ClI

Conditions
ConditionsYield
In toluene at 20 - 29℃; for 18h; Temperature; Solvent;
13760-02-6

diiodosilane

870-61-1

bis(trifluoromethylseleno)mercury

69641-88-9

bis(trifluoromethylseleno)silane

Conditions
ConditionsYield
In decalin stirring, 20°C, 1 h;78%
13760-02-6

diiodosilane

2S-benzyloxymethyl-4R-acetoxy-1,3 dioxolane

154459-77-5

2S-benzyloxymethyl-4S acetoxy-1,3 dioxolane

A

2S-Benzyloxymethyl-4R-iodo-1,3-dioxolane

B

299412-06-9

2S-benzyloxymethyl-4S-iodo-1,3 dioxolane

Conditions
ConditionsYield
In dichloromethane; toluene
13760-02-6

diiodosilane

mercury

mercury(I) iodide

Conditions
ConditionsYield
In neat (no solvent) byproducts: SiH4, Si2H6, H2; at ambient temp.;;
In neat (no solvent) byproducts: SiH4, Si2H6, H2; at ambient temp.;;

Silane, diiodo-(7CI,8CI,9CI) Specification

The Silane, diiodo-(7CI,8CI,9CI) is an organic compound with the formula H2I2Si. The systematic name of this chemical is diiodosilane. With the CAS registry number 13760-02-6, it is also named as silane, diiodo-. The product's categories are Protecting and Derivatizing Reagents; Protection and Derivatization; Silicon-Based.

Physical properties about Silane, diiodo-(7CI,8CI,9CI) are: (1)Boiling Point: 153.7 °C at 760 mmHg ; (2)Vapour Pressure: 4.21 mmHg at 25°C.

When you are using this chemical, please be cautious about it as the following:
It is flammable and harmful by inhalation, in contact with skin and if swallowed. After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer). Please keep away from sources of ignition - No smoking and take off immediately all contaminated clothing. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, this chemical reacts violently with water and can cause burns. When you are using it, wear suitable gloves and eye/face protection. In case of accident or if you feel unwell seek medical advice immediately (show the label where possible).

You can still convert the following datas into molecular structure:
(1)SMILES: I[SiH2]I
(2)InChI: InChI=1/H2I2Si/c1-3-2/h3H2
(3)InChIKey: AIHCVGFMFDEUMO-UHFFFAOYAW
(4)Std. InChI: InChI=1S/H2I2Si/c1-3-2/h3H2
(5)Std. InChIKey: AIHCVGFMFDEUMO-UHFFFAOYSA-N

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