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Tetrahydrofurfuryl alcohol
methacrylic acid methyl ester
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate
Conditions | Yield |
---|---|
With 4-acetylamino-2,2,6,6-tetramethyl-1-piperidinoxy; di(n-butyl)tin oxide In 2-Methylpentane; cyclohexane at 85 - 100℃; for 12h; Temperature; | 95% |
2-methyl-propan-2-ol; lanthanum tri-tert-butylate at 25℃; for 2h; | 32 %Chromat. |
sodium ethanolate | 15 %Chromat. |
With sulfuric acid; benzene |
Tetrahydrofurfuryl alcohol
methyl methacrylate
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate
Conditions | Yield |
---|---|
With sulfuric acid |
Tetrahydrofurfuryl alcohol
poly(methacrylic acid)
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate
Conditions | Yield |
---|---|
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; |
Conditions | Yield |
---|---|
In 2-methyltetrahydrofuran at 90℃; for 4h; Inert atmosphere; Sealed tube; Green chemistry; regioselective reaction; | 79% |
tert.-butylhydroperoxide
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate
β-naphthaldehyde
Conditions | Yield |
---|---|
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]} In decane; 1,2-dichloro-ethane at 20℃; for 6h; Inert atmosphere; | 75% |
tert.-butylhydroperoxide
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate
4-methoxy-benzaldehyde
Conditions | Yield |
---|---|
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]} In decane; 1,2-dichloro-ethane at 20℃; for 6h; Inert atmosphere; | 74% |
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate
D,L-cis-phenylcyclopropylamine
Conditions | Yield |
---|---|
With C60H100N4O12Rh2 In hexane at 20℃; for 18h; Schlenk technique; Inert atmosphere; | A 11% B 74% |
tert.-butylhydroperoxide
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate
3-methoxy-benzaldehyde
Conditions | Yield |
---|---|
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]} In decane; 1,2-dichloro-ethane at 20℃; for 6h; Inert atmosphere; | 73% |
tert.-butylhydroperoxide
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate
benzaldehyde
(tetrahydrofuran-2-yl)methyl 2-(tert-butylperoxy)-2-methyl-4-oxo-4-phenylbutanoate
Conditions | Yield |
---|---|
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]} In decane; 1,2-dichloro-ethane at 20℃; for 6h; Inert atmosphere; | 70% |
With iron(II) chloride In decane; acetonitrile at 85℃; for 1h; Inert atmosphere; | 61% |
tert.-butylhydroperoxide
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate
4-fluorobenzaldehyde
Conditions | Yield |
---|---|
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]} In decane; 1,2-dichloro-ethane at 20℃; for 6h; Inert atmosphere; | 67% |
Molecular Structure of Tetrahydrofurfuryl methacrylate (CAS No.2455-24-5):
Molecular Formula: C9H14O3
Molecular Weight:
CAS No: 2455-24-5
H bond acceptors: 3
H bond donors: 0
Freely Rotating Bonds: 4
Polar Surface Area: 35.53 Å2
Index of Refraction: 1.452
Molar Refractivity: 44.62 cm3
Molar Volume: 165.2 cm3
Surface Tension: 33.7 dyne/cm
Density: 1.03 g/cm3
Flash Point: 105.6 °C
Enthalpy of Vaporization: 50.29 kJ/mol
Boiling Point: 265 °C at 760 mmHg
Vapour Pressure: 0.0094 mmHg at 25°C
IUPAC Name: Oxolan-2-ylmethyl 2-methylprop-2-enoate
InChI: InChI=1/C9H14O3/c1-7(2)9(10)12-6-8-4-3-5-11-8/h8H,1,3-6H2,2H3
InChIKey: LCXXNKZQVOXMEH-UHFFFAOYAZ
Std. InChI: InChI=1S/C9H14O3/c1-7(2)9(10)12-6-8-4-3-5-11-8/h8H,1,3-6H2,2H3
Std. InChIKey: LCXXNKZQVOXMEH-UHFFFAOYSA-N
Product Categories: FuransMonomers;Acrylic Monomers;Building Blocks;Heterocyclic Building Blocks;Methacrylate
Risk Statements: 10-36/37/38
R10:Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 36
S36:Wear suitable protective clothing.
RIDADR: 3272
WGK Germany: 1
HazardClass: 3
PackingGroup: III
Hazardous Substances Data: 2455-24-5
Tetrahydrofurfuryl methacrylate (CAS No.2455-24-5), its synonyms are 2-Propenoic acid, 2-methyl-, (tetrahydro-2-furanyl)methyl ester ; Methacrylic acid, tetrahydrofurfuryl ester (8CI) ; Tetrahydro-2-furanylmethyl methacrylate ; Tetrahydrofuran-2-ylmethyl 2-methylprop-2-enoate ; Tetrahydrofuran-2-ylmethyl methacrylate ; 2-Methyl-acrylic acid tetrahydro-furan-2-ylmethyl ester .