Detail of > 101-84-8
- MSDS Download

- CAS Number:
- 101-84-8
- Name:
Diphenyl ether
- Formula:
- C12H10O
- Molecular Structure:

- Synonyms:
- Phenylether (8CI);1,1'-Oxybis[benzene];Barrel Therm 330;Benzene, phenoxy-;Biphenyl oxide;Chemcryl JK-EB;Diphenyl oxide;NSC 19311;Oxybisbenzene;Phenoxybenzene;Phenyl oxide;Benzene, 1,1'-oxybis-;
- Molecular Weight:
- 170.21
- EINECS:
- 202-981-2
- Density:
- 1.063 g/cm3
- Melting Point:
- 26 °C
- Boiling Point:
- 258.3 °C at 760 mmHg
- Flash Point:
- 99.3 °C
- Solubility:
- Insoluble in water
- Appearance:
- clear pale yellowish liquid after melting
- Hazard Symbols:
N,
Xi,
T- Risk Codes:
- 51/53-36/37/38-39/23/24/25-23/24/25-36/38
- Safety:
- 60-61-57-37/39-26-45-36/37Details
- Transport Information:
- UN 3077 9/PG 3
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Reference
- Thermooxidative decomposition of poly(ether ether ketone)
- Thermooxidative decomposition of poly(ether ether ketone). Prime, R. Bruce; Seferis, James C. (Gen. Prod. Div., IBM, San Jose, CA 95193, USA). J. Polym. Sci., Part C: Polym. Lett., 24(12), 641-4 (English) 1986. CODEN: JSCLE2. DOCUMENT TYPE: Journal CA Section: 35 (Chemistry of Synthetic High Polymers) The thermal stability of PEEK [31694-16-3] decreased in the presence of Cu powder and/or air. The degrdn. rate of PEEK in air at 375° increased by 4-5 times in the presence of Cu. The activation energy for thermal degrdn. increased from ~100 kJ/mol for neat PEEK to ~142 kJ/mol for Cu-contg. PEEK. The degrdn. products were benzoquinone [106-51-4], benzophenone [119-61-9], PhOH [108-95-2], and Ph2O [101-84-8].
- Synthesis of polyetherketones in trifluoromethanesulfonic acid: some structure-reactivity relationships
- Synthesis of polyetherketones in trifluoromethanesulfonic acid: some structure-reactivity relationships. Colquhoun, H. M. (New Sci. Group, Imp. Chem. Ind. PLC, Runcorn WA7 4QE, UK). Polym. Prepr. (Am. Chem. Soc., Div. Polym.Several reagents such as 1493-13-6 is used here. Chem.), 25(2), 17-18 (English) 1984. CODEN: ACPPAY. ISSN: 0032-3934. DOCUMENT TYPE: Journal CA Section: 35 (Chemistry of Synthetic High Polymers) Polyether-ketones having predominately para-linkages and high mol. wts. were prepd. using CF3SO3H [1493-13-6] as solvent/catalyst by treating arom. diethers with dicarboxylic acids or polymg. 4-(4-phenoxyphenoxy)benzoic acid or 4-(4-phenoxyphenyl)benzoic acid. Polymeric products had intrinsic viscosities ranging from 2.31 to 6.54, Tgs in the range 152-216°, and m.p.s from 334° to 478°. Kinetic studies for the acrylation of anisole [100-66-3] with various para-substituted benzoic acid derivs. indicated the rate-detg. reaction was the formation of the acylium ion, which was destabilized by electron-withdrawing substituents. Other model systems studied include the reaction of 4-fluorobenzoic acid [456-22-4] with di-Ph ether [101-84-8] and 1,4-diphenoxybenzene [3061-36-7], resp. .
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