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| CAS No.: | 13826-35-2 |
|---|---|
| Name: | 3-Phenoxybenzyl alcohol |
| Article Data: | 48 |
| Molecular Structure: | |
|
|
|
| Formula: | C13H12O2 |
| Molecular Weight: | 200.237 |
| Synonyms: | Benzylalcohol, m-phenoxy- (7CI,8CI);(3-Phenoxyphenyl)methanol;1-Hydroxymethyl-3-phenoxybenzene;3-(Hydroxymethyl)diphenyl ether;3-Phenoxybenzenemethanol;m-Phenoxybenzyl alcohol; |
| EINECS: | 237-525-1 |
| Density: | 1.151 g/cm3 |
| Melting Point: | 4-7°C |
| Boiling Point: | 377.8 °C at 760 mmHg |
| Flash Point: | 151.3 °C |
| Solubility: | insoluble in water |
| Appearance: | colourless liquid |
| Hazard Symbols: |
 Xn,  Xi
|
| Risk Codes: | 22 |
| Safety: | 26-36/37 |
| PSA: | 29.46000 |
| LogP: | 2.97120 |
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3-Phenoxybenzaldehyde
- 13826-35-2
3-Phenoxybenzyl alcohol
| Conditions | Yield |
|---|---|
| With sodium tetrahydroborate In methanol at 0 - 20℃; for 1.5h; | 99% |
| With hydrogen In methanol at 20℃; for 4.3h; chemoselective reaction; | 99% |
| With sodium tetrahydroborate In tetrahydrofuran; 1,2-dimethoxyethane for 3h; Cooling with ice; | 99.2% |
- 50789-44-1
3-phenoxybenzyl acetate
- 13826-35-2
3-Phenoxybenzyl alcohol
| Conditions | Yield |
|---|---|
| 97.2% |
- 13826-35-2
3-Phenoxybenzyl alcohol
| Conditions | Yield |
|---|---|
| With copper dichloride In methanol at 20℃; Hydrolysis; | 95% |
| With CuCl2*2H2O In methanol at 20℃; for 1.25h; | 95% |
- 50789-44-1
3-phenoxybenzyl acetate
- 13826-35-2
3-Phenoxybenzyl alcohol
| Conditions | Yield |
|---|---|
| With hydrogenchloride; sodium hydroxide In methanol; dichloromethane; water | 95% |
| With hydrogenchloride; sodium hydroxide In methanol; dichloromethane; water | 90% |
| With sodium hydroxide In methanol; dichloromethane; water | 90% |
- 3739-38-6
3-phenoxybenzoic acid
- 13826-35-2
3-Phenoxybenzyl alcohol
| Conditions | Yield |
|---|---|
| In ethanol; sulfuric acid; water electrochemical reduction; | 93% |
| Multi-step reaction with 3 steps 1: phosphorus (V)-chloride 2: toluene; palladium/barium sulfate 3: concentrated aqueous KOH / 60 °C View Scheme | |
| Multi-step reaction with 2 steps 1: sulfuric acid / 3 h / 60 °C 2: methanol; sodium tetrahydroborate / tetrahydrofuran / 0.5 h / Reflux View Scheme |
| Conditions | Yield |
|---|---|
| With sodium chloride; sulfuric acid; sodium hydrogencarbonate; potassium carbonate; copper(I) chloride In chlorobenzene | 93% |
| With sodium chloride; sulfuric acid; sodium hydrogencarbonate; potassium carbonate; copper(I) chloride In chlorobenzene |
| Conditions | Yield |
|---|---|
| With potassium phosphate; copper(l) iodide; N1-benzyl-N2-(5-methyl-[1,1'-biphenyl]-2-yl)oxalamide In dimethyl sulfoxide at 120℃; for 24h; Inert atmosphere; | 92% |
| With potassium carbonate; 8-quinolinol; copper(l) chloride In various solvent(s) at 150 - 170℃; for 15h; | 88 % Chromat. |
| With potassium carbonate; 8-quinolinol; copper(l) chloride In dimethyl sulfoxide at 150 - 170℃; for 15h; Product distribution; solvents varied; | 58 % Chromat. |
| Conditions | Yield |
|---|---|
| With potassium phosphate; copper(l) iodide; N,N’-bis(2-phenylphenyl)oxalic acid In N,N-dimethyl-formamide at 90℃; for 24h; Schlenk technique; Inert atmosphere; Sealed tube; | 92% |
- 620-24-6
3-Hydroxybenzyl alcohol
A
- 112-35-6
triethylene glucol monomethyl ether
B
- 13826-35-2
3-Phenoxybenzyl alcohol
| Conditions | Yield |
|---|---|
| A n/a B 87% |
| Conditions | Yield |
|---|---|
| With sodium dodecyl-sulfate; potassium carbonate In water at 80℃; under 760.051 Torr; for 10h; Ullmann Condensation; Green chemistry; chemoselective reaction; | 84% |
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Chemistry
IUPAC Name: 3-Phenoxybenzyl alcohol
The MF of 3-Phenoxybenzyl alcohol (13826-35-2) is C13H12O2.
The MW of 3-Phenoxybenzyl alcohol (13826-35-2) is 200.23.
Synonyms of 3-Phenoxybenzyl alcohol (13826-35-2): (3-Phenoxyphenyl)methanol ; Benzenemethanol, 3-phenoxy- ; 3-(Hydroxymethyl)diphenyl ether
Product Categories: Benzhydrols,Benzyl & Special Alcohols;Alcohols;Oxygen Compounds
Form: colourless liquid
Index of Refraction: 1.595
EINECS: 237-525-1
Density: 1.151 g/ml
Flash Point: 151.3 °C
Boiling Point: 377.8 °C
Melting Point: 4-7 °C
Water Solubility: Insoluble
BRN: 475312
Stability: Stable
Uses
3-Phenoxybenzyl alcohol (13826-35-2) is permethrin, phenothrin and permethrin and other pesticides in the middle of ether, pharmaceutical intermediates.
Toxicity Data With Reference
| 1. | orl-rat LD50:3 g/kg | GTPZAB Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 35 (1)(1991),47. | ||
| 2. | orl-mus LD50:2040 mg/kg | GTPZAB Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 35 (1)(1991),47. | ||
| 3. | ipr-mus LD50:575 mg/kg | JAFCAU Journal of Agricultural and Food Chemistry. 25 (1977),9. |
Consensus Reports
Reported in EPA TSCA Inventory.
Safety Profile
Moderately toxic by ingestion and intraperitoneal routes. When heated to decomposition it emits acrid smoke and irritating vapors.
Safety information of 3-Phenoxybenzyl alcohol (13826-35-2):
Hazard Codes 
Xn,Xi
Risk Statements
22 Harmful if swallowed
Safety Statements
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37 Wear suitable protective clothing and gloves
WGK Germany 3
RTECS DP0775400
Hazard Note Irritant