CAS No.1462-37-9,BENZYL 2-BROMOETHYL ETHER Suppliers

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Basic Information

Molecular Structure:
CAS No.:	1462-37-9
Name:	BENZYL 2-BROMOETHYL ETHER
Article Data:	32

Formula:	C₉H₁₁BrO
Molecular Weight:	215.09
Synonyms:	Ether,benzyl 2-bromoethyl (7CI,8CI);1-(Benzyloxy)-2-bromoethane;1-[(2-Bromoethoxy)methyl]benzene;2-(Benzyloxy)-1-bromoethane;2-(Benzyloxy)ethyl bromide;2-Bromoethyl benzyl ether;2-Bromoethylphenylmethyl ether;[(2-Bromoethoxy)methyl]benzene;1-bromo-2-benzyloxyethane;
EINECS:	629-202-2
Density:	1.358 g/cm³
Boiling Point:	258.6 °C at 760 mmHg
Flash Point:	111.7 °C
Solubility:	Slightly soluble in water
Appearance:	Clear colorless to pale yellow liquid
Hazard Symbols:	Xn
Risk Codes:	22
Safety:	24/25
PSA:	9.23000
LogP:	2.59810

Synthetic route

: 622-08-2
2-Benzyloxyethanol

: 1462-37-9
bromoethyl-2-benzyl ether

Conditions

Conditions	Yield
With carbon tetrabromide; triphenylphosphine In tetrahydrofuran at 0 - 20℃;	98%
With N-Bromosuccinimide; triphenylphosphine In dichloromethane at -78 - 20℃; Inert atmosphere; Darkness;	98%
With N-Bromosuccinimide; triphenylphosphine In dichloromethane at 20℃; for 13h;	89%

: 7285-83-8
2,4,6-tris(benzyloxy)-1,3,5-triazine

: 540-51-2
2-bromoethanol

: 1462-37-9
bromoethyl-2-benzyl ether

Conditions

Conditions	Yield
With trifluorormethanesulfonic acid In 1,4-dioxane at 20℃; for 5h; Inert atmosphere;	98%

: 540-51-2
2-bromoethanol

: 100-51-6
benzyl alcohol

: 1462-37-9
bromoethyl-2-benzyl ether

Conditions

Conditions	Yield
With [bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold (I) at 150℃; for 0.5h; Inert atmosphere; Microwave irradiation;	98%

: 4981-83-3
2-(Benzyloxy)ethyl p-toluenesulfonate

: 1462-37-9
bromoethyl-2-benzyl ether

Conditions

Conditions	Yield
With lithium bromide In acetonitrile at 70 - 80℃; for 2.5h; Reagent/catalyst; Solvent; Temperature;	94.3%

: 123455-81-2
Pyridine-2-sulfonic acid 2-benzyloxy-ethyl ester

A: 1462-37-9
bromoethyl-2-benzyl ether

B: C5H4NO3S(1-)*Br(1-)*Mg(2+)

Conditions

Conditions	Yield
With magnesium bromide ethyl etherate In diethyl ether; dichloromethane at 0℃; for 0.5h;	A 94% B n/a

: 58841-52-4
2-(benzyloxy)ethyl methanesulfonate

: 1462-37-9
bromoethyl-2-benzyl ether

Conditions

Conditions	Yield
With sodium bromide In dimethyl sulfoxide at 80 - 100℃; for 1h;	93.5%

: 2-(benzyloxy)-4,6-dimethoxy-1,3,5-triazine

: 540-51-2
2-bromoethanol

: 1462-37-9
bromoethyl-2-benzyl ether

Conditions

Conditions	Yield
With trifluorormethanesulfonic acid In 1,4-dioxane at 20℃; for 0.0166667h; Molecular sieve; Inert atmosphere;	89%

: 622-08-2
2-Benzyloxyethanol

: 603-35-0
triphenylphosphine

: 1462-37-9
bromoethyl-2-benzyl ether

Conditions

Conditions	Yield
In hexane; dichloromethane	85%
In N-Bromosuccinimide; hexane; dichloromethane	85%

: 622-08-2
2-Benzyloxyethanol

A: 1462-37-9
bromoethyl-2-benzyl ether

B: 100-39-0
benzyl bromide

Conditions

Conditions	Yield
With bromine In acetonitrile at 0℃; for 0.5h; Bromination;	A 77% B n/a

: 558-13-4
carbon tetrabromide

: 622-08-2
2-Benzyloxyethanol

: 1462-37-9
bromoethyl-2-benzyl ether

Conditions

Conditions	Yield
With pyridine; triphenylphosphine In methanol; dichloromethane; ethyl acetate	76%

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Specification

The Benzene,[(2-bromoethoxy)methyl]-, with CAS registry number 1462-37-9, belongs to the following product categories: (1)Protection & Derivatization Reagents (for Synthesis); (2)Synthetic Organic Chemistry; (3)Ethers; (4)Organic Building Blocks; (5)Oxygen Compounds. It has the systematic name of [(2-bromoethoxy)methyl]benzene. This chemical is a kind of clear colorless to pale yellow liquid. And this chemical is harmful if swallowed.

Physical properties of Benzene,[(2-bromoethoxy)methyl]-: (1)ACD/LogP: 3.00; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 3; (4)ACD/LogD (pH 7.4): 3; (5)ACD/BCF (pH 5.5): 112.5; (6)ACD/BCF (pH 7.4): 112.5; (7)ACD/KOC (pH 5.5): 1022.91; (8)ACD/KOC (pH 7.4): 1022.91; (9)#H bond acceptors: 1; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 4; (12)Polar Surface Area: 9.23 Å²; (13)Index of Refraction: 1.543; (14)Molar Refractivity: 49.91 cm³; (15)Molar Volume: 158.3 cm³; (16)Polarizability: 19.78×10^-24cm³; (17)Surface Tension: 38.9 dyne/cm; (18)Density: 1.358 g/cm³; (19)Flash Point: 111.7 °C; (20)Enthalpy of Vaporization: 47.62 kJ/mol; (21)Boiling Point: 258.6 °C at 760 mmHg; (22)Vapour Pressure: 0.022 mmHg at 25°C.

Preparation: this chemical can be prepared by 2-benzyloxy-ethanol. This reaction will need reagents NBS, PPh₃ and solvent CH₂Cl₂. The reaction time is 13 hour(s) with reaction temperature of 20 ℃. The yield is about 89%.

You can still convert the following datas into molecular structure:
(1)SMILES: BrCCOCc1ccccc1
(2)InChI: InChI=1/C9H11BrO/c10-6-7-11-8-9-4-2-1-3-5-9/h1-5H,6-8H2
(3)InChIKey: FWOHDAGPWDEWIB-UHFFFAOYAV
(4)Std. InChI: InChI=1S/C9H11BrO/c10-6-7-11-8-9-4-2-1-3-5-9/h1-5H,6-8H2
(5)Std. InChIKey: FWOHDAGPWDEWIB-UHFFFAOYSA-N