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CAS No.: | 15195-58-1 |
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Name: | manganese(4+) tetrafluoride |
Article Data: | 10 |
Molecular Structure: | |
Formula: | F4Mn |
Molecular Weight: | 130.932 |
Synonyms: | Manganesetetrafluoride |
Density: | g/cm3 |
Boiling Point: | °Cat760mmHg |
Flash Point: | °C |
PSA: | 0.00000 |
LogP: | -11.98400 |
Conditions | Yield |
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600°C, some min; | >99 |
Conditions | Yield |
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In neat (no solvent) N2 carrier gas; T > 793 K; |
manganese(III) fluoride
terbium tetrafluoride
A
manganese tetrafluoride
B
terbium(III) fluoride
Conditions | Yield |
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In neat (no solvent) react. MnF3 and TbF4 at 650-780 K; |
Conditions | Yield |
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In neat (no solvent) Kinetics; pelletized MnF2 (pretreated at 400°C), 450 - 700°C, partial pressure of fluorine 1.0 - 10.1 kPa, linear gas-flow rate 2 - 3 cm/s (mixt. F2 + N2); determined gravimetrically; elem. anal.; |
Conditions | Yield |
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In hydrogen fluoride |
Conditions | Yield |
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In hydrogen fluoride byproducts: Kr, F2, KrF2; HF (liquid); react. with excess KrF2 at room temp.; volatiles pumped off, elem. anal.; | |
In hydrogen fluoride HF (liquid); KrF2 added to soln. of MnF2 in HF at -196°C, slowly warmed to room temp.; volatiles pumped off, elem. anal.; |
Conditions | Yield |
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In neat (no solvent) Kinetics; pelletized MnF2 (pretreated at 400°C), 450 - 540°C, partial pressure of fluorine 1.0 - 10.1 kPa, linear gas-flow rate 2 - 3 cm/s (mixt. F2 + N2); determined gravimetrically; | |
With HF; H2O2 In neat (no solvent) High Pressure; 380-400°C, F2-pressure about 3 kbar, 25-35 d;; | |
In neat (no solvent) at 550℃; Flow reactor; |
Conditions | Yield |
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In neat (no solvent) Kinetics; moist N2 or Ar (different p(H2O)), heating up to 345°C; |
Conditions | Yield |
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In neat (no solvent) Kinetics; Ar atmosphere; heating over 380°; |
Conditions | Yield |
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In melt byproducts: MnCl2; the mixture of SrCl2 and MnF2 was heated at 1000 °C, the melt was leached out with cold water for several times to remove MnCl2;; the residue was washed with alcohol and dried;; |