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| CAS No.: | 7439-96-5 |
|---|---|
| Name: | Manganese |
| Article Data: | 374 |
| Molecular Structure: | |
|
|
|
| Formula: | Mn |
| Molecular Weight: | 54.938 |
| Synonyms: | Colloidalmanganese;Cutaval;Ele-Max Manganese;JIS-G 1213;MNE 06PB;Manganese element;Manganese-55;Teprosyn Mn; |
| EINECS: | 231-105-1 |
| Density: | 7.3 g/mL at 25 °C(lit.) |
| Melting Point: | 1244 °C(lit.) |
| Boiling Point: | 1962 °C(lit.) |
| Solubility: | soluble in water |
| Appearance: | silvery or greyish flakes or chunks |
| Hazard Symbols: |
 F,  Xi,  T
|
| Risk Codes: | 36/38-15-11-34-23/24/25 |
| Safety: | 45-43-26-36-36/37/39-27 |
| Transport Information: | UN 3264 8/PG 3 |
| PSA: | 0.00000 |
| LogP: | 0.00000 |
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- 7439-96-5
manganese
| Conditions | Yield |
|---|---|
| byproducts: bibenzyl; flash vacuum pyrolysis at 350°C and 0.1 torr; | 98% |
| Conditions | Yield |
|---|---|
| In tetrahydrofuran byproducts: KCl, C16H22; to slurry of MnCl2 (1.71 mmol) in THF at -78°C added (dmCh)K (3.42 mmol) from solid addn. funnel over 3 h (alternativly, THF soln. of (dmCh)K added dropwise over 3 h), stirred for 4 h, allowed to warm to 25°C, stirred addnl. for 12 h; THF removed, pentane added, filtered, pentane removed; | A n/a B 15% |
- 7439-96-5
manganese
| Conditions | Yield |
|---|---|
| With aluminium | |
| With silicon In neat (no solvent) Electric Arc; redn. with Si in carbon electric arc;; |
| Conditions | Yield |
|---|---|
| byproducts: N2, NaCl; vac., heating in ampoule (300-400°C); cooling, washing (MeOH), drying (vac.), powder XRD, FT IR; |
- 7439-96-5
manganese
| Conditions | Yield |
|---|---|
| With NH4SCN; H3BO3; KCl In water Electrochem. Process; under N2; Mn electrodeposited from soln. of MnCl2*4H2O, H3BO3, KCl, and NH4SCN; pH 5.0, at -2.0 - -0.7 V for 180 min; |
| Conditions | Yield |
|---|---|
| In neat (no solvent) byproducts: CO; isothermal react. under Ar, mixing of stoich. amts. of MnO and C, placing in an alumina crucible in a tube furnace, heating to 1350°C for 80 min; effects of gangue components on the reduction is studied; determination by X-ray diffraction and EDAX; |
- 7439-96-5
manganese
| Conditions | Yield |
|---|---|
| With (NH4)2SO4 In not given Electrochem. Process; electrodeposited at pH 8.0; 20-25°C; 4 A/dm**2; no agitation; |
| Conditions | Yield |
|---|---|
| byproducts: CO; at 1400-1550°C; |
- 7439-96-5
manganese
| Conditions | Yield |
|---|---|
| With sodium In neat (no solvent) redn. with Na at 25 °C;; | |
| With aluminium In neat (no solvent) heating in a vessel (coated with CaO or MgO) in presence of cryolite or CaF2;; | |
| With beryllium byproducts: BeO; redn. with Be at 25-1280 °C;; |
| Conditions | Yield |
|---|---|
| Kinetics; byproducts: Al2O3; at 1800°K; |
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Consensus Reports
Manganese and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.
Standards and Recommendations
OSHA PEL: Fume: TWA 1 mg/m3; STEL 3 mg/m3; Compounds: CL 5 mg/m3
ACGIH TLV: Fume: 1 mg/m3; STEL 3 mg/m3; Dust and Compounds: TWA 5 mg/m3; (Proposed: TWA 0.2 mg/m3)
DFG MAK: 0.5 mg/m3
Analytical Methods
For occupational chemical analysis use OSHA: #ID-125G or NIOSH: Elements (ICP), 7300.
Specification
The Manganese is an organic compound with the formula Mn. With the CAS registry number 7439-96-5, the IUPAC name of this chemical is manganese. The product's categories are Inorganics; AAS; AAS CRMsAlphabetic; AASSpectroscopy; Application CRMs; M; MA - MDSpectroscopy; Matrix Selection; Nitrate; Spectroscopy; ICP CRMsAlphabetic; ICP-OES/-MS; ICPSpectroscopy; Manganese; Metal and Ceramic Science; Metals; AA Standard SolutionsAlphabetic; NitrateSpectroscopy; Reference/Calibration Standards; Single Solution; Standard Solutions; Catalysis and Inorganic Chemistry; Chemical Synthesis; ManganeseMetal and Ceramic Science. Besides, it should be stored in a cool dry and well-ventilated place.
Preparation: this chemical can be prepared by Manganese carbonate and sulfuric acid.
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Uses of Manganese: it is a metal with important industrial metal alloy uses, particularly in stainless steels. Manganese(II) ions function as cofactors for a number of enzymes in higher organisms, where they are essential in detoxification of superoxide free radicals. The element is a required trace mineral for all known living organisms. In larger amounts, and apparently with far greater activity by inhalation, manganese can cause a poisoning syndrome in mammals, with neurological damage which is sometimes irreversible.
When you are using this chemical, please be cautious about it as the following:
It is highly flammable and toxic by inhalation, in contact with skin and if swallowed. Please take off immediately all contaminated clothing. It contacts with water liberates extremely flammable gases and can cause burns. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, this chemical is irritating to to eyes and skin. When you are using it, wear suitable gloves and eye/face protection. In case of accident or if you feel unwell seek medical advice immediately (show the label where possible).
You can still convert the following datas into molecular structure:
(1)SMILES: [Mn]
(2)InChI: InChI=1/Mn
(3)InChIKey: PWHULOQIROXLJO-UHFFFAOYAG
(4)Std. InChI: InChI=1S/Mn
(5)Std. InChIKey: PWHULOQIROXLJO-UHFFFAOYSA-N
The toxicity data is as follows:
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| man | TCLo | inhalation | 2300ug/m3 (2.3mg/m3) | BRAIN AND COVERINGS: OTHER DEGENERATIVE CHANGES BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY) BEHAVIORAL: MUSCLE WEAKNESS | American Industrial Hygiene Association Journal. Vol. 27, Pg. 454, 1966. |
| rat | LD50 | oral | 9gm/kg (9000mg/kg) | "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972Vol. -, Pg. 21, 1972. |