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| CAS No.: | 373-80-8 |
|---|---|
| Name: | TRIFLUOROMETHYLSULFUR PENTAFLUORIDE |
| Article Data: | 33 |
| Molecular Structure: | |
|
|
|
| Formula: | CF8 S |
| Molecular Weight: | 196.064 |
| Synonyms: | (Trifluoromethyl)sulfurpentafluoride (6CI); Sulfur, pentafluoro(trifluoromethyl)- (7CI,8CI);(Trifluoromethyl)pentafluorosulfur; Pentafluoro(trifluoromethyl)sulfur |
| Density: | g/cm3 |
| Melting Point: | -87°C |
| Boiling Point: | -21 °C |
| Flash Point: | °C |
| Risk Codes: | 23-34 |
| Safety: | 3/7-9-26-36/37/39-45 |
| PSA: | 25.30000 |
| LogP: | 3.80470 |
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- 372-64-5
Bis(trifluoromethyl)disulfid
- 7790-89-8
chlorine monofluoride
A
- 373-80-8
trifluoromethyl sulfur pentafluoride
B
- 25030-42-6, 42179-04-4
trans-chlorotetrafluoro(trifluoromethyl)sulfur(VI)
| Conditions | Yield |
|---|---|
| molar ratio of CF3SSCF3 and ClF = 1:8.5 to 1:9, 10 h, 25°c; | A <1 B 76.8% |
| molar ratio of CF3SSCF3 and ClF = 1:8.5 to 1:9, 10 h, 25°c; | A <1 B 76.8% |
| Conditions | Yield |
|---|---|
| 250°C; | 40% |
| 250°C; | 40% |
| Conditions | Yield |
|---|---|
| 250-275°C , diluted with N2; | 20% |
| 250-275°C , diluted with N2; | 20% |
| 190-210°C , diluted with N2; | 15% |
- 109-79-5
1-butanethiol
- 7664-39-3
hydrogen fluoride
A
- 354-67-6
pentafluoro(1,1,2,2,2-pentafluoroethyl)-λ6-sulfane
B
- 375-52-0
n-C4F9SF5
C
- 373-80-8
trifluoromethyl sulfur pentafluoride
| Conditions | Yield |
|---|---|
| In further solvent(s) Electrochem. Process; electrofluorination in anhyd. HF for 6 h 40 min 15°C, helium flow rate 60 mL/min, U=5.8-8.0 V, i=2.9 A/dm2; | A n/a B 12.3% C n/a |
| In further solvent(s) Electrochem. Process; electrofluorination in anhyd. HF for 6 h 40 min 15°C, helium flow rate 60 mL/min, U=5.8-8.0 V, i=2.9 A/dm2; | A n/a B 12.3% C n/a |
| Conditions | Yield |
|---|---|
| 48°C , T-reactor, CS2:F2:N2=1:5:75; | 9% |
| 48°C , T-reactor, CS2:F2:N2=1:5:75; | 9% |
| 40°C , diluted with N2; | |
| 40°C , diluted with N2; |
| Conditions | Yield |
|---|---|
| With hydrogen fluoride elektrochemische Fluorierung an einer Nickel-Anode; | |
| With cobalt (III) fluoride at 250℃; | |
| electrofluorination; |
- 75-15-0
carbon disulfide
A
- 373-80-8
trifluoromethyl sulfur pentafluoride
B
- 374-10-7
trifluoro(trifluoromethyl)sulfur(IV)
| Conditions | Yield |
|---|---|
| With silver(II) fluoride |
- 461-08-5
bis(trifluoromethyl)trithiocarbonate
A
- 372-64-5
Bis(trifluoromethyl)disulfid
B
- 373-80-8
trifluoromethyl sulfur pentafluoride
C
- 374-10-7
trifluoro(trifluoromethyl)sulfur(IV)
D
- 812-12-4
trifluoromethanesulfinyl fluoride
| Conditions | Yield |
|---|---|
| With silver(II) fluoride; sodium fluoride In 1,1,2-Trichloro-1,2,2-trifluoroethane | |
| With silver(II) fluoride; sodium fluoride |
- 7664-39-3
hydrogen fluoride
- 291-21-4
[1,3,5]trithiane
A
- 373-80-8
trifluoromethyl sulfur pentafluoride
B
- 1512-21-6
(difluoromethanediyl)bis(pentafluorosulfur(VI))
C
- 1543-46-0
pentafluorothiodifluoromethyl-trifluoromethylsulfurtetrafluoride
| Conditions | Yield |
|---|---|
| Electrolysis; |
| Conditions | Yield |
|---|---|
| at 200 - 250℃; |
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