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4459-18-1

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Basic Information
CAS No.: 4459-18-1
Name: PERFLUORO-TERT-BUTYL IODIDE
Article Data: 11
Molecular Structure:
Molecular Structure of 4459-18-1 (PERFLUORO-TERT-BUTYL IODIDE)
Formula: C4F9I
Molecular Weight: 345.934
Synonyms: Perfluoro(2-iodo-2-methylpropane);iodoperfluoro-tert-butane;nonafluoro-tert-butyl iodide;PC5906G;1,1,1,3,3,3-hexafluoro-2-iodo-2-trifluoromethyl-propane;perfluoro-tert-butyl iodide;Iodononafluoro-t-butane;nonafluoro-t-butyl iodide;
Density: 2.127g/cm3
Melting Point: 60oC
Boiling Point: 70.6°Cat760mmHg
Flash Point: 20°C
Hazard Symbols: Xi,T
Risk Codes: R36/37/38
PSA: 0.00000
LogP: 3.84710
Related products
Synthetic route
754-43-8

2-bromo-1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane

A

382-24-1

1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane

B

4459-18-1

perfluoro-tert-butyl iodide

Conditions
ConditionsYield
With sodium iodide In acetonitrile for 5h; Heating;A 75.7%
B 5.3%
27746-96-9

2-chlorocarbonyloxy-1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane

4459-18-1

perfluoro-tert-butyl iodide

Conditions
ConditionsYield
With potassium iodide at 150 - 180℃; for 3h;30.8%
2314-97-8

iodotrifluoromethane

3024-50-8

3,3-bis(trifluoromethyl)diazirine

4459-18-1

perfluoro-tert-butyl iodide

Conditions
ConditionsYield
at 150 - 155℃; for 10h;9.8%
382-21-8

perfluoroisobutylene

4459-18-1

perfluoro-tert-butyl iodide

Conditions
ConditionsYield
With potassium fluoride; iodine; nitrobenzene
354-93-8

1,1,1,3,3,3-hexafluoro-2-nitroso-2-trifluoromethyl-propane

4459-18-1

perfluoro-tert-butyl iodide

Conditions
ConditionsYield
With iodine
116-15-4

perfluoropropylene

2314-97-8

iodotrifluoromethane

A

754-34-7

1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

B

382-21-8

perfluoroisobutylene

C

677-69-0

perfluoroisopropyl iodide

D

1542-18-3

2-trifluoromethyl-perfluoropropyl iodide

E

4459-18-1

perfluoro-tert-butyl iodide

F

1,1,1,2-Tetrafluoro-2-iodo-butane

Conditions
ConditionsYield
at 360℃; Product distribution; nickel reactor; other temperatures, influence of reactor material;
...Expand
116-15-4

perfluoropropylene

2314-97-8

iodotrifluoromethane

A

677-69-0

perfluoroisopropyl iodide

B

1542-18-3

2-trifluoromethyl-perfluoropropyl iodide

C

4459-18-1

perfluoro-tert-butyl iodide

D

1,1,1,2-Tetrafluoro-2-iodo-butane

Conditions
ConditionsYield
at 360℃; Yield given. Further byproducts given. Yields of byproduct given;
...Expand
754-43-8

2-bromo-1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane

A

2314-97-8

iodotrifluoromethane

B

4459-18-1

perfluoro-tert-butyl iodide

Conditions
ConditionsYield
With iodine Product distribution; Irradiation; multiple-photon IR laser excitation; different laser frequency and energy fluence;
With iodine Irradiation; Yield given. Yields of byproduct given;
369-58-4

benzenediazonium hexafluorophosphate

C8F18I(1-)*C6H18N3S(1+)

A

38771-38-9

2-phenylazo-2-trifluoromethylperfluoropropane

B

4459-18-1

perfluoro-tert-butyl iodide

C

C6H18N3S(1+)*F6P(1-)

Conditions
ConditionsYield
In tetrahydrofuran at 25℃;
...Expand

C8F18I(1-)*C6H18N3S(1+)

333-27-7

methyl trifluoromethanesulfonate

A

4459-18-1

perfluoro-tert-butyl iodide

B

36553-69-2

1,1,1,3,3,3-hexafluoro-2-methyl-2-trifluoromethyl-propane

C

C6H18N3S(1+)*CF3O3S(1-)

Conditions
ConditionsYield
In dichloromethane at 25℃;
...Expand
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