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CAS No.: | 677-69-0 |
---|---|
Name: | Heptafluoroisopropyl iodide |
Article Data: | 34 |
Molecular Structure: | |
Formula: | C3F7I |
Molecular Weight: | 295.926 |
Synonyms: | 2-Iodoheptafluoropropane;2-Iodoperfluoropropane;Bis(trifluoromethyl)fluoroiodomethane;Fluoro(iodo)bis(trifluoromethyl)methane;Heptafluoro-2-iodopropane;Propane,1,1,1,2,3,3,3-heptafluoro-2-iodo-;Isoheptafluoropropyliodide;Perfluoro-2-iodopropane;Perfluoroisopropyl iodide;Propane,heptafluoro-2-iodo- (6CI,7CI,8CI);1,1,1,2,3,3,3-Heptafluoro-2-iodopropane; |
EINECS: | 211-643-3 |
Density: | 2.189 g/cm3 |
Melting Point: | -58 °C |
Boiling Point: | 40.8 °C at 760 mmHg |
Flash Point: | 4.7 °C |
Solubility: | insoluble in water |
Appearance: | clear colorless to yellowish liquid |
Hazard Symbols: | Xn, Xi, T |
Risk Codes: | 20-36/37/38 |
Safety: | 26-36-37/39 |
Transport Information: | UN 2810 |
PSA: | 0.00000 |
LogP: | 3.21180 |
Conditions | Yield |
---|---|
With hydrogen fluoride; boron trifluoride; Iodine monochloride at 50℃; for 18h; | 79% |
With iodine; antimony(III) fluoride; iodine pentafluoride at 20℃; Rate constant; Kinetics; var. temp.; | |
(i) CF3CO2Ag, CsF, (ii) I2; Multistep reaction; |
perfluoropropylene
iodotrifluoromethane
A
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane
B
perfluoroisobutylene
C
perfluoroisopropyl iodide
D
2-trifluoromethyl-perfluoropropyl iodide
E
perfluoro-tert-butyl iodide
Conditions | Yield |
---|---|
at 360℃; Product distribution; nickel reactor; other temperatures, influence of reactor material; |
perfluoropropylene
iodotrifluoromethane
A
perfluoroisopropyl iodide
B
2-trifluoromethyl-perfluoropropyl iodide
C
perfluoro-tert-butyl iodide
Conditions | Yield |
---|---|
at 360℃; Yield given. Further byproducts given. Yields of byproduct given; |
perfluoropropylene
A
perfluoroisopropyl iodide
B
2-hydrohexafluoropropyl fluorosulfate
C
2-iodo-hexafluoropropyl fluorosulfate
Conditions | Yield |
---|---|
With iodine; antimony pentafluoride; fluorosulphonic acid at 20℃; for 72h; | A 11 g B 6 g C 4.5 g |
Conditions | Yield |
---|---|
With iodine In gas at 286.9 - 426.9℃; under 30 - 300 Torr; Equilibrium constant; |
1,1,1,2,3,3,3-Heptafluoro-2-(1,2,2,2-tetrafluoro-1-iodo-ethoxy)-propane
A
iodotrifluoromethane
B
trifluoroacetyl fluoride
C
perfluoro(2,3-dimethylbutane)
D
perfluoroisopropyl iodide
Conditions | Yield |
---|---|
at 250℃; under 7500.6 Torr; Pyrex tube; |
1,1,1,2,3,3,3-Heptafluoro-2-(1,2,2,2-tetrafluoro-1-iodo-ethoxy)-propane
A
trifluoroacetyl fluoride
B
perfluoroisopropyl iodide
Conditions | Yield |
---|---|
at 250℃; under 7500.6 Torr; Pyrex tube; |
C3F17IO2Te2
A
tetradecafluorohexane
B
perfluoroisopropyl iodide
C
Hexafluoroacetone
Conditions | Yield |
---|---|
at 120℃; for 10h; |
1,1,1,2,2,4,5,5,5-nonafluoro-3-pentafluoroethyl-3,4-bis-trifluoromethyl-pentane
A
perfluoroisopropyl iodide
Conditions | Yield |
---|---|
With iodine at 201℃; for 48h; | |
With iodine at 201℃; for 48h; Rate constant; Thermodynamic data; other temp., activation energy; |
perfluoro-2,4-dimethyl-3-ethylpentane
A
perfluoroisopropyl iodide
B
1,1,1,2,2,3,4,5,5,5-decafluoro-3-iodo-4-trifluoromethyl-pentane
Conditions | Yield |
---|---|
With iodine at 261℃; for 48h; |
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Structure of Heptafluoroisopropyl iodide (CAS NO.677-69-0):
Molecular Formula: C3F7I
Molecular Weight: 295.93
EINECS: 211-643-3
Index of Refraction: 1.361
Molar Refractivity: 29.96 cm3
Molar Volume: 135.1 cm3
Polarizability: 11.87 10 -24 cm3
Surface Tension: 17.7 dyne/cm
Density: 2.189 g/cm3
Melting Point: -58 °C
Boiling Point: 40.8 °C at 760 mmHg
Flash Point: 4.7 °C
Enthalpy of Vaporization: 27.34 kJ/mol
Vapour Pressure: 429 mmHg at 25°C
storage temp.: Keep Cold
Water Solubility: insoluble
Product Categories: Organic Fluorides
IUPAC Name: 1,1,1,2,3,3,3-heptafluoro-2-iodopropane
Synonyms: Perfluoroisopropyl iodide ; 1,1,1,2,3,3,3-Heptafluoro-2-iodopropane ; Propane, 1,1,1,2,3,3,3-heptafluoro-2-iodo-
The Hazard Codes of Heptafluoroisopropyl iodide (CAS NO.677-69-0): Xn, Xi , T
The Risk Statements information of Heptafluoroisopropyl iodide (CAS NO.677-69-0):
20: Harmful by inhalation
36/37/38: Irritating to eyes, respiratory system and skin
The Safety Statements information of Heptafluoroisopropyl iodide (CAS NO.677-69-0):
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing
37/39: Wear suitable gloves and eye/face protection
Hazard Note: Irritant
HazardClass: 6.1(b)
RIDADR: 2810
WGK Germany: 3
RTECS: TZ3925000
F: 8
TSCA: T