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7447-39-4

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Basic Information
CAS No.: 7447-39-4
Name: Copper(II) chloride
Article Data: 3
Molecular Structure:
Molecular Structure of 7447-39-4 (Copper(II) chloride)
Formula: CuCl2
Molecular Weight: 134.452
Synonyms: Copperbichloride;Copper(II) chloride;Copper dichloride;Copper(2+) chloride;Copper(II)chloride;Cupric chloride anhydrous;Cupric dichloride;GBC 4L;NSC 165706;
EINECS: 231-210-2
Density: 3.386 g/cm3
Melting Point: 498 °C
Boiling Point: 993 °C
Solubility: in water: 706 g/L (0 °C), 757 g/L (25 °C)
Appearance: Brownish yellow crystalline powder
Hazard Symbols: ToxicT, DangerousN
Risk Codes: 25-36/37/38-50/53
Safety: 26-29-37/39-45-57
Transport Information: UN 2802 8/PG 3
PSA: 0.00000
LogP: -5.99450
Synthetic route
7782-50-5

chlorine

copper(l) chloride

7447-39-4

copper(II) chloride

Conditions
ConditionsYield
In gaseous matrix passing of Cl2 in Ar gas (5%) over solid Cu(I)Cl (650°C, alumina crucible, backing pressure 1.5 atm);
Conditions
ConditionsYield
In neat (no solvent) copper wire was heated in a small excess of Cl2 in a sealed cell;;
In gaseous matrix passing of Cl2 in Ar gas (5%) over Cu powder (850°C, alumina crucible, backing pressure 1.5 atm);
In neat (no solvent) reaction of Cu powder with Cl2 gas at 750°C; laser induced fluorescence;
872-05-9

1-Decene

7487-88-9

magnesium sulfate

7447-39-4

copper(II) chloride

palladium dichloride

24323-23-7

2-methyl decanoic acid

Conditions
ConditionsYield
With hydrogenchloride; carbon monoxide In tetrahydrofuran; sodium hydroxide; water100%

3-chloro-1-thiocyanato-2-propene

7447-39-4

copper(II) chloride

196406-44-7

3-chloro-1-isothiocyanato-1-propene

Conditions
ConditionsYield
In 5,5-dimethyl-1,3-cyclohexadiene90.7%
dilithium copper tetrachloride Li2 CuCl4

dilithium copper tetrachloride Li2 CuCl4

53101-38-5

3-chloro-1-hexene

7447-39-4

copper(II) chloride

109-70-6

1,3-chlorobromopropane

629624-26-6

6-chloronon-1-ene

Conditions
ConditionsYield
With lithium chloride In tetrahydrofuran84%
66416-72-6

4-bromo-2-iodoaniline

7447-39-4

copper(II) chloride

774608-49-0

4-bromo-1-chloro-2-iodobenzene

Conditions
ConditionsYield
With tert.-butylnitrite In acetonitrile76%
540-80-7

tert.-butylnitrite

631910-12-8

4-bromo-3-methyl-5-nitroaniline

7447-39-4

copper(II) chloride

631910-13-9

2-bromo-5-chloro-1-methyl-3-nitro-benzene

Conditions
ConditionsYield
In acetonitrile72%
tert-butylnitrate

tert-butylnitrate

656-64-4

3-bromo-4-fluoroaniline

7447-39-4

copper(II) chloride

631912-19-1

3-bromo-4-fluorobenzene-1-sulfonyl chloride

Conditions
ConditionsYield
With hydrogenchloride; sulfur dioxide In methanol; 4-(dicyanomethylene)-2-methyl-6-(p-dimethylaminostyryl)-4H-pyran59%
540-80-7

tert.-butylnitrite

3073-77-6

5-nitropyrimidin-2-amine

7447-39-4

copper(II) chloride

10320-42-0

2-Chloro-5-nitropyrimidine

Conditions
ConditionsYield
With magnesium sulfate In diethyl ether; acetonitrile50%
540-80-7

tert.-butylnitrite

631909-32-5

5-Amino-4-(2'-methyl-biphenyl-3-sulfonyl)-thiophene-2-carboxylic acid methyl ester

7447-39-4

copper(II) chloride

631909-33-6

5-chloro-4-(2'-methyl-biphenyl-3-sulfonyl)-thiophene-2-carboxylic acid methyl ester

Conditions
ConditionsYield
In ethyl acetate; acetonitrile34%
Raw Materials
7782-50-5
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Consensus Reports

Copper and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.

Standards and Recommendations

ACGIH TLV: TWA (fume) 0.2 mg/m3; (dust, mist) 1 mg(Cu)/m3
DOT Classification:  8; Label: Corrosive

Specification

Cupric chloride anhydrous, with the CAS register number 7447-39-4, is also called as Copper dichloride. The substance is a yellow-brown solid with the chemical formula CuCl2. Its EINECS register number is 231-210-2. Cupric chloride anhydrous is stable, but reacts violently with potassium and sodium. If contacts with acetylene may form explosive acetylides. Hygroscopic. This is a light brown solid, which slowly absorbs moisture to form a blue-green dihydrate.

Properties: Cupric chloride anhydrous reacts with hydrochloric acid or other chloride sources to form complex ions: the red CuCl3-, and the yellow CuCl42-. Using sulfur dioxide as the reductant, copper(II) chloride can be reduced into copper(I) derivatives.

2 CuCl2 + SO2 + 2 H2O → 2 CuCl + 2 HCl + H2SO4

Cupric chloride anhydrous will decompose to CuCl and Cl2 at 1000 °C:

2 CuCl2 → 2 CuCl + Cl2

Cupric chloride anhydrous also can form a variety of coordination complexes with ligands such as pyridine and triphenylphosphine oxide:

CuCl2 + 2 C5H5N → [CuCl2(C5H5N)2] (tetragonal)
CuCl2 + 2 (C6H5)3P=O → [CuCl2((C6H5)3P=O)2] (tetrahedral)

Preparation: Cupric chloride anhydrous may be prepared directly by union of the elements, copper and chlorine. It can also be generated by treatment of the hydroxide, oxide, or copper(II) carbonate with hydrochloric acid. In addition, Cupric chloride anhydrous is prepared commercially by the action of chlorination of copper:

Cu + Cl2 + 2 H2O → CuCl2(H2O)2

Uses: Cupric chloride anhydrous can be used as catalyst, antifungal and astringent drug, and feed additive. A major industrial application for Cupric chloride is as a co-catalyst with palladium(II) chloride in the Wacker process. In this process, ethene (ethylene) is converted to ethanal using water and air. During the reaction, PdCl2 is reduced to Pd, and the CuCl2 serves to re-oxidize this back to PdCl2. Air can then oxidize the resultant CuCl back to CuCl2, completing the cycle.

C2H4 + PdCl2 + H2O → CH3CHO + Pd + 2 HCl
Pd + 2 CuCl2 → 2 CuCl + PdCl2
4 CuCl + 4 HCl + O2 → 4 CuCl2 + 2 H2O

Cupric chloride anhydrous has a variety of specialized applications in the synthesis of organic compounds. It catalyzes the chlorination in the production of vinyl chloride and dichloroethane. Cupric chloride is also used in pyrotechnics as a blue/green coloring agent. In a flame test, Cupric chloride, like all copper compounds, emit green-blue. Cupric chloride can also oxidize phenols in the presence of oxygen.

When you are using Cupric chloride anhydrous, you should be very cautious about it. The substance is toxic if swallowed and dangerous for the environment. In addition, it is irritating to eyes, respiratory system and skin. Cupric chloride anhydrous is very toxic to aquatic organisms which may cause long-term adverse effects in the aquatic environment. In case of contact with eyes, you can rinse immediately with plenty of water and seek medical advice. Whenever you will use or contact it, you need wear suitable gloves and eye/face protection. In case of accident or if you feel unwell seek medical advice immediately.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: Cl[Cu]Cl
(2)InChI: InChI=1S/2ClH.Cu/h2*1H;/q;;+2/p-2
(3)InChIKey: ORTQZVOHEJQUHG-UHFFFAOYSA-L

Toxicity of Cupric chloride anhydrous:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 7400ug/kg (7.4mg/kg)   Naunyn-Schmiedeberg's Archiv fuer Experimentelle Pathologie und Pharmakologie. Vol. 244, Pg. 17, 1962.
mouse LD50 intravenous 17500ug/kg (17.5mg/kg)   European Journal of Medicinal Chemistry--Chimie Therapeutique. Vol. 19, Pg. 425, 1984.
mouse LD50 oral 233mg/kg (233mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991.
rat LD50 intraperitoneal 14700ug/kg (14.7mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991.
rat LD50 intravenous 5mg/kg (5mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991.
rat LD50 oral 584mg/kg (584mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991.