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CAS No.: | 781637-36-3 |
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Name: | 2-Propenoic acid, 2-methyl-, 3,5-bis[2,2,2-trifluoro-1-hydroxy-1-(trifluoromethyl)ethyl]cyclohexyl ester |
Article Data: | 1 |
Molecular Structure: | |
Formula: | C16H16F12O4 |
Molecular Weight: | 500.281 |
Synonyms: | MA-3,5-HFA-CHOH; |
PSA: | 66.76000 |
LogP: | 4.60200 |
poly(methacrylic acid)
3,5-HFA-CHOH
3,5-bis(1,1,1,3,3,3-hexafluoro-2-hydroxypropan-2-yl)cyclohexyl methacrylate
Conditions | Yield |
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With methanesulfonic acid In toluene at 130℃; for 3.5h; |
3,5-bis(1,1,1,3,3,3-hexafluoro-2-hydroxypropan-2-yl)cyclohexyl methacrylate
di-tert-butyl dicarbonate
C26H32F12O8
Conditions | Yield |
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With dmap; triethylamine In tetrahydrofuran at 70℃; Reflux; | 80% |
3-hydroxy-1-adamantyl methacrylate
ethyl 2-hydroxypropionate
diphenylether
propylene glycol methyl ether acetate
3,5-bis(1,1,1,3,3,3-hexafluoro-2-hydroxypropan-2-yl)cyclohexyl methacrylate
2-isopropyl-2-adamantyl methacrylate
potassium nonaflate
Conditions | Yield |
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With toluene-4-sulfonic acid In methanol; dichloromethane; water; acetonitrile |
2-methyl-2-adamantyl methacrylate
2,2'-azobis-(2,4-dimethylvaleronitrile)
3,5-bis(1,1,1,3,3,3-hexafluoro-2-hydroxypropan-2-yl)cyclohexyl methacrylate
methyltertbutyl ether
Conditions | Yield |
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In tetrahydrofuran; acetonitrile | 39.6 g (54%) |
3,5-bis(1,1,1,3,3,3-hexafluoro-2-hydroxypropan-2-yl)cyclohexyl methacrylate
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1.1: sodium hydroxide; water / 1,4-dioxane / 36.5 h / 23 - 90 °C 2.1: chlorobenzene / 0.5 h / 23 °C 2.2: 3 h / 130 °C / Molecular sieve View Scheme |
3,5-bis(1,1,1,3,3,3-hexafluoro-2-hydroxypropan-2-yl)cyclohexyl methacrylate
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1.1: sodium hydroxide; water / 1,4-dioxane / 36.5 h / 23 - 90 °C 2.1: chlorobenzene / 0.5 h / 23 °C 2.2: 3 h / 130 °C / Molecular sieve View Scheme |
3,5-bis(1,1,1,3,3,3-hexafluoro-2-hydroxypropan-2-yl)cyclohexyl methacrylate
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: sodium hydroxide; water / 1,4-dioxane / 36.5 h / 23 - 90 °C 2: pyridine / tetrahydrofuran / 4 h / 40 °C View Scheme |
3,5-bis(1,1,1,3,3,3-hexafluoro-2-hydroxypropan-2-yl)cyclohexyl methacrylate
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1.1: sodium hydroxide; water / 1,4-dioxane / 36.5 h / 23 - 90 °C 2.1: pyridine / tetrahydrofuran / 4 h / 40 °C 3.1: potassium carbonate; potassium iodide / N,N-dimethyl-formamide / 1.5 h / 23 - 40 °C 3.2: 7 h / 40 °C View Scheme |
3,5-bis(1,1,1,3,3,3-hexafluoro-2-hydroxypropan-2-yl)cyclohexyl methacrylate
3,5-HFA-CHOH
Conditions | Yield |
---|---|
With water; sodium hydroxide In 1,4-dioxane at 23 - 90℃; for 36.5h; |
3,5-bis(1,1,1,3,3,3-hexafluoro-2-hydroxypropan-2-yl)cyclohexyl methacrylate
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1.1: sodium hydroxide; water / 1,4-dioxane / 36.5 h / 23 - 90 °C 2.1: chlorobenzene / 0.5 h / 23 °C 2.2: 3 h / 130 °C / Molecular sieve View Scheme |