533-73-3Relevant articles and documents
Titanosilicate molecular sieve for size-screening photocatalytic conversion
Shiraishi, Yasuhiro,Saito, Naoya,Hirai, Takayuki
, p. 8304 - 8306 (2005)
Titanosilicate molecular sieves, when activated by ultraviolet light irradiation in water in the presence of molecular oxygen, catalyze a conversion of molecules having a size close to the pore of the catalysts but are inactive for molecules having much larger or smaller size. This unprecedented size-screening photocatalytic activity is triggered by a combination of H2O-induced shortened lifetime of active species (charge-transfer excited state of tetrahedrally coordinated titanium oxide) and restricted diffusion of a molecule inside the pore. This catalytic property demonstrates a potential utility of the catalyst for selective transformation of molecules that is associated with a size reduction of molecules, so-labeled molecular shave transformation. Copyright
Preparation method of sesamol
-
Paragraph 0022; 0026; 0030-0031, (2021/11/21)
The invention belongs to the technical field of compound synthesis, and particularly relates to a preparation method of sesamol, which firstly prepares 2 -chloro -1, 4 -diphenol, and then 2 - chlorine -1, 4 -biphenol and sodium hydroxide in an aqueous solution to obtain the sesamol, namely 1 2, 1 2 4 - 4 -triphenol and dichloromethane. The invention provides a new method for preparing the sesame phenol, and the yield of the sesamol is remarkably improved.
Mannich bases of hydroxycoumarins: Synthesis, DFT/QTAIM computational study and assessment of biological activity
Castro, María Eugenia,Durand-Niconoff, J. Sergio,Fernández-Pomares, Cynthia,Guerrero, Tomás,Juárez-Aguilar, Enrique,Melendez, Francisco J.,Montoya-Hernández, Eva Luz,Olivares-Romero, José L.,Ortiz-Blanco, Erik,Sosa-Ortiz, Gabriela,Tovar-Miranda, Ricardo
, p. 31260 - 31271 (2021/11/30)
The synthesis of six Mannich bases derived from hydroxycoumarins was carried out in moderate yields, two of these derivatives were described for the first time. Conformational analysis was performed through DFT theoretical calculations explaining the formation of stable six membered rings based on intramolecular hydrogen bonds within the structure. These findings were correlated with the antiproliferative activity. The biological activity of the Mannich bases through their antiproliferative activity in the HeLa cancer cell line is described for the first time, showing that the compounds were able to inhibit proliferation in cervical cancer by more than 60%. Likewise, the theoretical modeling of the photophysical properties was realized with promising results, showing that the HOMO-LUMO energies of the new compounds present the lowest electronic gap values for those with donor groups in their structure, which makes them potential fluorophores. This journal is
Synthesis of renewable C-C cyclic compounds and high-density biofuels using 5-hydromethylfurfural as a reactant
Cai, Taimei,Deng, Qiang,Deng, Shuguang,Gao, Rui,Peng, Hailong,Wang, Jun,Zeng, Zheling,Zhong, Jin,Zou, Ji-Jun
, p. 2468 - 2473 (2020/05/14)
The major challenge in the synthesis of high-density biofuels is to identify the bio-based source for C-C cyclic compounds and C-C coupling reactions with a suitable selectivity. Herein, we selectively synthesize 1,2,4-benzenetriol (BTO) with a yield of 51.4% from cellulose-derived 5-hydromethylfurfural via a ring-rearrangement reaction. The cellulose-derived route is a more meaningful route for the C-C cyclic compounds compared to the traditional hemicellulose- and lignin-derived routes. Furthermore, BTO is very easily dimerized via a C-C oxidative coupling reaction, showing a yield of 94.4% and selectivity of nearly 100% under environmentally friendly reaction conditions. After hydrodeoxygenation, bicyclohexane is obtained with a yield of 87.4%. This work not only provides a promising route to produce C-C cyclic fine compounds based on a cellulose-derived route, but also shows a highly efficient synthesis route for high-density biofuels via the C-C oxidative coupling reaction.