54208-05-8

Basic information

• Product Name: Phosphorane, nonylidenetriphenyl-
• CAS NO: 54208-05-8
• Molecular Formula: C27H33P
• Molecular Weight: 388.533
• Mol File: 54208-05-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Phosphorane, nonylidenetriphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphorane, nonylidenetriphenyl-(54208-05-8)
• EPA Substance Registry System: Phosphorane, nonylidenetriphenyl-(54208-05-8)

Safety Data

• Hazardous Substances Data: 54208-05-8(Hazardous Substances Data)

Upstream product

• 39589-66-7 (1-nonyl)triphenylphosphonium iodide 
• 60902-45-6 nonyltriphenylphosphonium bromide 

Downstream Products

• 83851-38-1 Leukotriene A₃ 
• 438037-26-4 [2-(2S)-(2-methoxymethoxydodecyloxy)ethoxymethyl]benzene 
• 289666-45-1 [2-((R)-2-Methoxymethoxy-dodecyloxy)-ethoxymethyl]-benzene 
• 438037-25-3 (2S)-1-(2-benzyloxyethoxy)dodecan-2-ol 
• 289666-44-0 (R)-1-(2-Benzyloxy-ethoxy)-dodecan-2-ol 
• 85514-84-7 (2R)-dodecane-1,2-diol 
• 318466-98-7 (3S,5Z)-3-[{3-[(5-bromopentyl)(2-nitrobenzenesulfonyl)amino]propyl}(2-nitrobenzenesulfonyl)amino]tetradec-5-enoic acid [3-(2-nitrobenzenesulfonylamino)propyl]amide 
• 318466-99-8 (8S,2Z)-1,9,13-tris(2-nitrobenzenesulfonyl)-8-(undec-2-enyl)-1,5,9,13-tetraazacyclooctadecan-6-one 
• 1026351-15-4 C₃₉H₅₇BrN₄O₁₁S₂ 
• 318466-96-5 (3S,5Z)-3-[{3-[(5-bromopentyl)(2-nitrobenzenesulfonyl)amino]propyl}(2-nitrobenzenesulfonyl)amino]tetradec-5-enoic acid allyl ester 
• 318466-97-6 (3S,5Z)-3-[{3-[(5-bromopentyl)(2-nitrobenzenesulfonyl)amino]propyl}(2-nitrobenzenesulfonyl)amino]tetradec-5-enoic acid 
• 318466-95-4 (3S,5Z)-3-[{3-[(5-bromopentyl)(2-nitrobenzenesulfonyl)amino]propyl}(2-nitrobenzenesulfonyl)amino]tetradec-5-enoic acid methyl ester 
• 318466-94-3 (3S,5Z)-3-(2-nitrobenzenesulfonylamino)tetradec-5-enoic acid methyl ester 
• 85514-85-8 (2S)-dodecane-1,2-diol 

Relevant articles and documents

γ-METHYL-γ,δ-EPOXY-α,β-UNSATURATED ALDEHYDE COMPOUND AND FLAVOR COMPOSITION CONTAINING THAT COMPOUND

PROBLEM TO BE SOLVED: To provide a new compound useful as a flavor ingredient or the like, and a flavor composition containing the compound. SOLUTION: The invention provides: a γ-methyl-γ,δ-epoxy-α,β-unsaturated aldehyde compound represented by the general formula (1) in the figure useful as a flavor ingredient and the like; and a flavor composition containing the compound. (In the formula, the solid line, the double line, H, C, O, R1 and R2 are as defined in the specification.) SELECTED DRAWING: None COPYRIGHT: (C)2021,JPOandINPIT

A convergent total synthesis of (-)-mucocin: An acetogenin from Annonaceae

A total synthesis of the Annonaceous acetogenin mucocin has been accomplished. The synthesis follows a convergent strategy, wherein at a very late stage the left part of the molecule is connected with the right part. The key reaction is the stereocontrolled addition of an organomagnesium compound 2 to the aldehyde 3. The THP ring of mucocin is build by a 6-endo epoxide cyclization of an epoxyacetonide precursor (16 → 17). The new modular synthetic approach developed herein should be useful for the synthesis of other related natural products as well as pharmacologically interesting analogues.