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Name	(S)-(+)-3-Hydroxytetrahydrofuran	EINECS	1308068-626-2
CAS No.	86087-23-2	Density	1.148 g/cm³
PSA	29.46000	LogP	-0.23240
Solubility	soluble in water	Melting Point	N/A
Formula	C₄H₈O₂	Boiling Point	181 °C at 760 mmHg
Molecular Weight	88.1063	Flash Point	81.1 °C
Transport Information	N/A	Appearance	clear liquid
Safety	26-37/39	Risk Codes	36/37/38
Molecular Structure		Hazard Symbols	Xi
Synonyms	3-Furanol,tetrahydro-, (S)-;(+)-3-Hydroxytetrahydrofuran;(S)-(+)-Tetrahydrofuran-3-ol;(S)-3-Hydroxytetrahydrofuran;(S)-Tetrahydro-3-furanol;3S-Hydroxytetrahydrofuran;	Article Data	28

(S)-(+)-3-Hydroxytetrahydrofuran Synthetic route

: 139013-68-6
(3S)-4-chloro-1,3-butanediol

: 86087-23-2
(S)-3-hydroxytetyrahydrofurane

Conditions

Conditions	Yield
With hydrogenchloride; sodium hydroxide In methanol; water	99.8%
With potassium hydroxide In methanol at 40℃; for 4h; Reagent/catalyst;	97%
In anhydrous ethylene glycol dimethyl ether at 110℃; for 5h; Product distribution / selectivity;	90%

: 145873-44-5
4-chloro-3-hydroxy-1-butanol

: 86087-23-2
(S)-3-hydroxytetyrahydrofurane

Conditions

Conditions	Yield
With hydrogenchloride In water at 50℃; for 4h; Solvent; Reagent/catalyst;	94.6%

: (S)-3-(4-Methoxy-benzyloxy)-tetrahydro-furan

A: 83318-92-7
ethyl p-methoxybenzyl sulfide

B: 86087-23-2
(S)-3-hydroxytetyrahydrofurane

Conditions

Conditions	Yield
With aluminium trichloride; ethanethiol In dichloromethane for 5h; Ambient temperature;	A n/a B 93%

: 42890-76-6
(S)-1,2,4-butanetriol

: 86087-23-2
(S)-3-hydroxytetyrahydrofurane

Conditions

Conditions	Yield
With toluene-4-sulfonic acid (3a preparation above 7a);	87%
toluene-4-sulfonic acid In PEG-400 at 120 - 160℃; under 10 Torr; for 12h; Product distribution / selectivity;	83%
strong acid ion exchange resin (Amberlyst 15, H+ form) In 1,4-dioxane at 90 - 120℃; under 760.051 - 5931.67 Torr; Product distribution / selectivity;	70%
With toluene-4-sulfonic acid
With toluene-4-sulfonic acid In water at 90℃;	10 g

: (S)-tetrahydrofuran-3-yl acetate

: 86087-23-2
(S)-3-hydroxytetyrahydrofurane

Conditions

Conditions	Yield
With sodium hydroxide In methanol; water at 20℃; for 3h;	83%

: (S)-3-benzyloxytetrahydrofuran

: 86087-23-2
(S)-3-hydroxytetyrahydrofurane

Conditions

Conditions	Yield
With palladium on activated charcoal; hydrogen at 40℃;	81.5%

: 86087-24-3
(R)-3-Hydroxytetrahydrofuran

: 86087-23-2
(S)-3-hydroxytetyrahydrofurane

Conditions

Conditions	Yield
Stage #1: (R)-3-Hydroxytetrahydrofuran With azodicarboxylic acid bis(2-methoxyethyl) ester; 4-diphenylphosphanobenzoic acid In tetrahydrofuran at 20℃; for 0.166667h; Stage #2: With water; sodium hydroxide In tetrahydrofuran at 20℃; stereospecific reaction;	64%

: 115914-74-4
2-(oxiran-2-yl)ethyl 4-methylbenzenesulfonate

A: 86087-23-2
(S)-3-hydroxytetyrahydrofurane

B: 2-((R)-oxiran-2-yl)ethyl 4-methylbenzenesulfonate

Conditions

Conditions	Yield
With (S,S)-(salen)cobalt(III)(OAc); water In tetrahydrofuran at 0 - 25℃; for 14h; optical yield given as %ee; enantioselective reaction;	A 48% B 47%

: 1191-99-7
2,3-dihydro-2H-furan

: 86087-23-2
(S)-3-hydroxytetyrahydrofurane

Conditions

Conditions	Yield
Yield given. Multistep reaction;

: 1708-29-8
2,5-dihydrofuran

: 86087-23-2
(S)-3-hydroxytetyrahydrofurane

Conditions

Conditions	Yield
Multistep reaction;
Yield given. Multistep reaction;

(S)-(+)-3-Hydroxytetrahydrofuran Chemical Properties

Product Name: (S)-(+)-3-Hydroxytetrahydrofuran (CAS NO.86087-23-2)

Molecular Formula: C₄H₈O₂
Molecular Weight: 88.11g/mol
Mol File: 86087-23-2.mol
Appearance: Colourless Liquid
Boiling point: 181 °C at 760 mmHg
Flash Point: 81.1 °C
Density: 1.148 g/cm³
Refractive index: n20/D 1.45(lit.)
Water Solubility: soluble
Stability: Stable. Combustible. Incompatible with strong oxidizing agents.
Index of Refraction: 1.475
Molar Refractivity: 21.64 cm³
Molar Volume: 76.7 cm³
Surface Tension: 38.7 dyne/cm
Enthalpy of Vaporization: 48.57 kJ/mol
Vapour Pressure: 0.255 mmHg at 25°C
Product Categories: Alcohols, Hydroxy Esters and Derivatives; Chiral Compounds; Starting Raw Materials & Intermediates; Small molecule; Tetrahydrofuran Series; Chiral Reagents; Furans; Chiral Building Blocks; Simple Alcohols (Chiral); Synthetic Organic Chemistry

(S)-(+)-3-Hydroxytetrahydrofuran Safety Profile

Safety Information of (S)-(+)-3-Hydroxytetrahydrofuran (CAS NO.86087-23-2):
Hazard Codes: Xi Irritant
Risk Statements: 36/37/38
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-37/39
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37/39:Wear suitable gloves and eye/face protection.
WGK Germany: 3

(S)-(+)-3-Hydroxytetrahydrofuran Specification

(S)-(+)-3-Hydroxytetrahydrofuran , its CAS NO. is 86087-23-2, the synonyms are (3S)-tetrahydrofuran-3-ol ; (S)-(+)-Tetrahydro-3-furanol .

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