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1,1,2,2-Tetrachloro-1,2-difluoroethane

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Name

1,1,2,2-Tetrachloro-1,2-difluoroethane

EINECS N/A
CAS No. 76-12-0 Density 1,634 g/cm3
PSA 0.00000 LogP 3.18820
Solubility N/A Melting Point 24°C
Formula C2Cl4 F2 Boiling Point 92,8°C
Molecular Weight 203.831 Flash Point 12.3°C
Transport Information N/A Appearance N/A
Safety A poison by inhalation. Moderately toxic by ingestion. A skin and eye irritant. When heated to decomposition it emits toxic fumes of F and Cl. See also CHLORINATED HYDROCARBONS, ALIPHATIC; and FLUORIDES.

Analytical Methods:

   

For occupational chemical analysis use NIOSH: see 1,1,2,2-TETRACHLORO-1,2-DIFLUOROETHANE.

Risk Codes R36/37/38
Molecular Structure Molecular Structure of 76-12-0 (1,1,2,2-Tetrach lorodifluoroethane) Hazard Symbols Toxic by inhalation. TLV: 500 ppm.
Synonyms

1,1,2,2-Tetrachloro-1,2-difluoroethane;1,1,2,2-Tetrachlorodifluoroethane; 1,2-Difluoro-1,1,2,2-tetrachloroethane;1,2-Difluorotetrachloroethane; CFC 112; CFC 122; Daiflon 112; Daiflon S 2; F112; FC 112; Freon 112; Fron 112; Genetron 112; R 112;Tetrachloro-1,2-difluoroethane; Ucon 112; sym-Tetrachlorodifluoroethane

Article Data 59

1,1,2,2-Tetrachloro-1,2-difluoroethane Chemical Properties

IUPAC Name: 1,1,2,2-Tetrachloro-1,2-difluoroethane
The MF of 1,2-Difluorotetrachloroethane (CAS NO.76-12-0) is C2Cl4F2.

                                      
The MW of 1,2-Difluorotetrachloroethane (CAS NO.76-12-0) is 203.83.
Synonyms of 1,2-Difluorotetrachloroethane (CAS NO.76-12-0): Tetrachloro-1,2-difluoroethane ; 1,1,2,2-Tetrachloro-1,2-difluoroethane ; Ethane, 1,1,2,2-tetrachloro-1,2-difluoro- ; 1,2-Difluoro-1,1,2,2-tetrachloroethane ; 2-Difluoro-1
Product Categories: Industrial/Fine Chemicals;CFC;refrigerants
Apperance: Colorless low-melting solid or liquid with a slight ethereal odor
Index of Refraction: 1.437 
EINECS: 200-935-6
Density: 1.726 g/ml 
Flash Point: 12.3 °C
Boiling Point: 94.1 °C 
Melting Point: 26.5 °C

1,1,2,2-Tetrachloro-1,2-difluoroethane Uses

 1,2-Difluorotetrachloroethane (CAS NO.76-12-0) is used as a refrigerant, a solvent extractant, and in dry cleaning.Also used to produce cattle liver fluke treatment of insect repellent. With Freon 112 as raw material obtained methoxy halothane,it is a new type of inhalation anesthetic agents.

1,1,2,2-Tetrachloro-1,2-difluoroethane Production

 Hexachloroethane react with hydrogen fluoride in the presence of antimony pentachloride catalyst.Trifluoro-trichloroethane are formed by alkaline cleaning, washing, fractionation, purification with Freon 112 as a byproduct.

1,1,2,2-Tetrachloro-1,2-difluoroethane Toxicity Data With Reference

1.    

skn-gpg 100%/24H open MLD

    AIHAAP    American Industrial Hygiene Association Journal. 27 (1966),332.
2.    

eye-gpg 100 mg/20S rns MLD

    AIHAAP    American Industrial Hygiene Association Journal. 27 (1966),332.
3.    

ihl-rat LC50:2 pph/15M

    HUTODJ    Human Toxicology. 1 (1982),239.
4.    

orl-mus LD50:800 mg/kg

    85GMAT    Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT,1982,54.

1,1,2,2-Tetrachloro-1,2-difluoroethane Consensus Reports

Reported in EPA TSCA Inventory.

1,1,2,2-Tetrachloro-1,2-difluoroethane Safety Profile

A poison by inhalation. Moderately toxic by ingestion. A skin and eye irritant. When heated to decomposition it emits toxic fumes of F and Cl. See also CHLORINATED HYDROCARBONS, ALIPHATIC; and FLUORIDES.Safety information of 1,2-Difluorotetrachloroethane (CAS NO.76-12-0):
Hazard Codes  IrritantXi
Risk Statements 
36/37/38 Irritating to eyes, respiratory system and skin
Safety Statements 
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36 Wear suitable protective clothing
Hazard Note  Irritant

1,1,2,2-Tetrachloro-1,2-difluoroethane Standards and Recommendations

OSHA PEL: TWA 500 ppm
ACGIH TLV: TWA 500 ppm
DFG MAK: 200 ppm (1700 mg/m3)
NIOSH REL: (1,1,2,2-Tetrachloro-1,2-difluoroethane) TWA 500 ppm

1,1,2,2-Tetrachloro-1,2-difluoroethane Analytical Methods

For occupational chemical analysis use NIOSH: see 1,1,2,2-TETRACHLORO-1,2-DIFLUOROETHANE.

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