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Name |
1,2-Diethoxyethane |
EINECS | 211-076-1 |
CAS No. | 629-14-1 | Density | 0.842 g/cm3 |
PSA | 18.46000 | LogP | 1.05940 |
Solubility | slightly soluble in water | Melting Point |
-74 °C |
Formula | C6H14O2 | Boiling Point | 119.4 °C at 760 mmHg |
Molecular Weight | 118.176 | Flash Point | 20.6 °C |
Transport Information | UN 1153 | Appearance | Clear colorless liquid |
Safety | 16-26-36 | Risk Codes | 10-37/38-41 |
Molecular Structure | Hazard Symbols | Xi | |
Synonyms |
1,2-Diethoxyethane;2-Ethoxyethyl ethyl ether;3,6-Dioxaoctane;Ethane, 1,2-diethoxy-;Diethyl cellosolve;Glycol diethyl ether;Hisolve EME; |
Article Data | 32 |
Conditions | Yield |
---|---|
With sulfuric acid at 40 - 70℃; under 3000.3 Torr; for 3h; Autoclave; Inert atmosphere; | 74.6% |
Conditions | Yield |
---|---|
With sulfuric acid | |
With H-type ZSM-5(SiO2/Al2O3=280) at 180℃; for 3h; | |
With sulfuric acid |
1-ethoxy-2-vinyloxy-ethane
monoethylene glycol diethyl ether
Conditions | Yield |
---|---|
With nickel Hydrogenation.von gasfoermigem oder in Alkoholen geloestem; | |
With nickel Hydrogenation.von gasfoermigem oder in Alkoholen geloestem; |
Conditions | Yield |
---|---|
With ethanol |
1-ethoxy-2-trityloxy-ethane
A
2-ethoxy-ethanol
B
monoethylene glycol diethyl ether
C
triphenylmethane
D
acetaldehyde
Conditions | Yield |
---|---|
at 325 - 330℃; |
Conditions | Yield |
---|---|
With copper | |
With tetrahydrofuran; magnesium | |
With tetrahydrofuran; sodium | |
With diethyl ether; sodium |
Conditions | Yield |
---|---|
With benzyl bromide In tetrahydrofuran at -30℃; |
IUPAC Name: 1,2-Diethoxyethane
CAS NO:629-14-1
Molecular Formula:C6H14O2
Molecular Weight:118.174160 g/mol
EINECS: 211-076-1
Index of Refraction: 1.391
Surface Tension: 23.8 dyne/cm
Density: 0.842 g/cm3
Flash Point: 20.6 °C
Enthalpy of Vaporization: 36.28 kJ/mol
Boiling Point: 119.4 °C at 760 mmHg
Vapour Pressure: 19.1 mmHg at 25 °C
Melting Point: -74 °C
Storage temp: Flammables area
Water Solubility: Slightly soluble
Appearance: a clear colorless liquid with a faint ether-like odor.
Synonyms of Ethylene glycol diethyl ether (CAS NO.629-14-1): 1,2-Ethanediol, diethyl ether ; 2-Ethoxyethyl ethyl ether ; Diethyl cellosolve ; Ethane, 1,2-diethoxy-
Ethylene glycol diethyl ether (CAS NO.629-14-1) is used as solvents of nitrocellulose, rubber, resin,etc, as well as the reaction medium in organic synthesis.
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
guinea pig | LD50 | oral | 2440mg/kg (2440mg/kg) | BEHAVIORAL: GENERAL ANESTHETIC GASTROINTESTINAL: OTHER CHANGES KIDNEY, URETER, AND BLADDER: OTHER CHANGES | Journal of Industrial Hygiene and Toxicology. Vol. 23, Pg. 259, 1941. |
rat | LCLo | inhalation | 8000ppm/4H (8000ppm) | Journal of Industrial Hygiene and Toxicology. Vol. 31, Pg. 343, 1949. | |
rat | LD50 | oral | 4390mg/kg (4390mg/kg) | BEHAVIORAL: GENERAL ANESTHETIC GASTROINTESTINAL: OTHER CHANGES KIDNEY, URETER, AND BLADDER: OTHER CHANGES | Journal of Industrial Hygiene and Toxicology. Vol. 23, Pg. 259, 1941. |
Reported in EPA TSCA Inventory. Glycol ether compounds are on the Community Right-To-Know List.
Hazard Codes :Xi
Risk Statements: 10-37/38-41
R10:Flammable.
R37/38:Irritating to respiratory system and skin.
R41:Risk of serious damage to the eyes.
Safety Statements: 16-26-36
S16:Keep away from sources of ignition.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36:Wear suitable protective clothing.
RIDADR: UN 1153 3/PG 2
WGK Germany: 2
RTECS :KI1225000
HazardClass: 3
PackingGroup: II
Moderately toxic by ingestion. Mildly toxic by inhalation. An experimental teratogen. Experimental reproductive effects. An eye irritant. An aprotic solvent. A very dangerous fire hazard when exposed to heat or flame; can react with oxidizing materials. To fight fire, use CO2, dry chemical.
Ethylene glycol diethyl ether (CAS NO.629-14-1) can react with oxidizers. Ethylene glycol diethyl ether is incompatible with strong acids.It causes irritation of nose and throat. Contact with liquid irritates eyes but has little or no effect on skin. Ingestion causes irritation of mouth and stomach. Ethylene glycol diethyl ether (CAS NO.629-14-1) will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.