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1-Chloro anthraquinone

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Name

1-Chloro anthraquinone

EINECS 201-421-4
CAS No. 82-44-0 Density 1.418 g/cm3
PSA 34.14000 LogP 3.11540
Solubility N/A Melting Point 159-160 °C(lit.)
Formula C14H7ClO2 Boiling Point 425.7 °C at 760 mmHg
Molecular Weight 242.661 Flash Point 179.7 °C
Transport Information N/A Appearance light yellow to yellow powder or chunks
Safety 26-37/39-24/25 Risk Codes 36/37/38
Molecular Structure Molecular Structure of 82-44-0 (1-Chloro anthraquinone) Hazard Symbols IrritantXi
Synonyms

Anthraquinone,1-chloro- (6CI,7CI,8CI);1-Chloro-9,10-anthracenedione;1-Chloro-9,10-anthraquinone;1-Chloroanthraquinone;NSC 30428;NSC 5138;a-Chloroanthraquinone;a-Monochloroanthraquinone;

Article Data 44

1-Chloro anthraquinone Chemical Properties

Molecular Formula:C14H7ClO2
Molar mass:242.65718 g/mol
Structure :
                 
Synonyms of 1-Chloro anthraquinone(82-44-0):Chloroanthraquinone;Anthraquinone, 1-chloro-;1-Chloranthrachinon;alpha-Monochloroanthraquinone;9,10-Anthracenedione, 1-chloro-;1-Chloranthrachinon [Czech];1-Chloro-9,10-anthraquinone
Density:1.418 g/cm3             
Flash Point:179.7 °C    
Boiling Point:425.7 °C at 760 mmHg        
Index of Refraction:1.665
Vapour Pressure:1.87E-07 mmHg at 25°C  
Melting point:157-162°C 
Solubility:slightly soluble in hot ethanol, insoluble in water,Soluble in acetic acid, nitrobenzene, hot benzene, amyl alcohol.
Appearance: Yellow needle-like crystals.

1-Chloro anthraquinone Uses

1-Chloro anthraquinone(82-44-0) can be used  as a dye intermediate.  such as dyes of Vat Brown BR.

1-Chloro anthraquinone Production

Sulfuric acid and nitric acid were mixed for nitration , and then to be sulfonated with sodium sulfite . In the boiling state ,instill sodium chlorate of hydrochloric acid solution for  chlorination,then with  filtration, drying.

1-Chloro anthraquinone Toxicity Data With Reference

1.   

eye-rbt 500 mg/24H MLD

   85JCAE    Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague,Czechoslovakia, Avicenum.: 1986,565.
2.   

ivn-mus LD50:56 mg/kg

   CSLNX*    U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#03287 .
Carcinogenicity:1-Chloro anthraquinone(82-44-0)- Not listed as a carcinogen by  NTP, IARC,ACGIH, or CA Prop 65. 
Other: See actual entry in RTECS for complete information.

1-Chloro anthraquinone Consensus Reports

Reported in EPA TSCA Inventory.

1-Chloro anthraquinone Safety Profile

Poison by intravenous route. An eye irritant. When heated to decomposition it emits very toxic fumes of Cl and NOx.
Hazard Codes:Xi
Risk Statements:
36:  Irritating to the eyes
37:  Irritating to the respiratory system
38:  Irritating to the skin
Safety Statements:
24:  Avoid contact with skin
25:  Avoid contact with eyes
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
37:  Wear suitable gloves
39:  Wear eye/face protection

1-Chloro anthraquinone Specification

Stability and Reactivity of 1-Chloro anthraquinone(82-44-0):
Conditions to Avoid:incompatible materials.
Chemical Stability:Stable under normal temperatures and pressures.
Incompatibilities with Other Materials:strong oxidizing agents.
Hazardous Decomposition Products:Hydrogen chloride, carbon dioxide,Carbon monoxide, irritating and toxic fumes and gases.
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