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2-ACETYLAMINO-5-NITROTHIAZOLE
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Name

2-ACETYLAMINO-5-NITROTHIAZOLE

 EINECS N/A
CAS No. 140-40-9 Density 1.598g/cm3
PSA 116.05000 LogP 1.60590
Solubility N/A Melting Point 263°C (dec.)
Formula C5H5 N3 O3 S Boiling Point 303.8°Cat760mmHg
Molecular Weight 187.179 Flash Point 137.5°C
Transport Information N/A Appearance N/A
Safety Poison by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of SOx and NOx. Risk Codes 22
Molecular Structure Molecular Structure of 140-40-9 (2-ACETAMIDO-5-NITROTHIAZOLE) Hazard Symbols
Synonyms

Thiazole,2-acetamido-5-nitro- (6CI,7CI); 2-(Acetylamino)-5-nitrothiazole;2-Acetamido-5-nitrothiazole; 5-Nitro-2-acetamidothiazole; Acetyl enheptin;Acinitrazol; Acinitrazole; Ametoterina; Aminitrozol; Aminitrozole; CL 5279;Cyzine Premix; Enheptin A; Gynofon; Lavoflagin;N-(5-Nitro-2-thiazolyl)acetamide; NSC 31539; NSC 45914; Nitazol; Nitazole;Nithiamide; Pleocide; Trichlorad; Trichocid; Trichoman; Trichorad; Trichoral;Tricogen; Tricolaval; Tricoral; Tricosteril; Trikolaval; Tritheon

Article Data 12

2-ACETYLAMINO-5-NITROTHIAZOLE Synthetic route

121-66-4

2-amino-5-nitro-1,3-thiazole

108-24-7

acetic anhydride

140-40-9

Nitazole

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃;91%
2719-23-5

2-acetamidothiazole

625-58-1

ethyl nitrate

140-40-9

Nitazole

Conditions
ConditionsYield
With sulfuric acid; potassium nitrate
2719-23-5

2-acetamidothiazole

140-40-9

Nitazole

Conditions
ConditionsYield
With sulfuric acid; nitric acid
With nitric acid; acetic anhydride
With ammonium nitrate; sulfuric acid at 20 - 30℃; for 2.5h; Yield given;
121-66-4

2-amino-5-nitro-1,3-thiazole

140-40-9

Nitazole

Conditions
ConditionsYield
With acetic anhydride
With pyridine
With sulfuric acid
7336-54-1

2-acetamido-5-bromothiazole

140-40-9

Nitazole

Conditions
ConditionsYield
With nitric acid; acetic anhydride; acetic acid
108-24-7

acetic anhydride

57530-25-3

thiazol-2-ylamine; nitrate

140-40-9

Nitazole

Conditions
ConditionsYield
(i) Na2CO3, CCl4, (ii) H2SO4; Multistep reaction;
140-40-9

Nitazole

121-66-4

2-amino-5-nitro-1,3-thiazole

Conditions
ConditionsYield
With hydrogenchloride
140-40-9

Nitazole

5875-25-2

2-bromo-propionic acid amide

23599-21-5

2-(2-acetylimino-5-nitro-thiazol-3-yl)-propionamide

Conditions
ConditionsYield
With sodium hydride; N,N-dimethyl-formamide
140-40-9

Nitazole

5326-97-6

2-Bromo-N-(n-octyl)acetamide

38922-42-8

2-(2-acetylimino-5-nitro-thiazol-3-yl)-N-octyl-acetamide

Conditions
ConditionsYield
With sodium hydride; N,N-dimethyl-formamide
140-40-9

Nitazole

105-36-2

ethyl bromoacetate

A

38922-43-9

N-acetyl-N-(5-nitro-thiazol-2-yl)-glycine ethyl ester

B

23599-22-6

(2-acetylimino-5-nitro-thiazol-3-yl)-acetic acid ethyl ester

Conditions
ConditionsYield
With sodium hydride; N,N-dimethyl-formamide

2-ACETYLAMINO-5-NITROTHIAZOLE Chemical Properties

The MF of 2-ACETYLAMINO-5-NITROTHIAZOLE(140-40-9): C5H5N3O3S
The MW of 2-ACETYLAMINO-5-NITROTHIAZOLE(140-40-9): 187.18
EINECS: 205-414-7
Melting point: 263 °C (dec.)
Water Solubility: 1610 mg/L 25 °C
Other names: acinitrazole; N-(5-nitrothiazol-2-yl)acetamide; 2-Acetamido-5-nitrothiazole
The Structure of 2-ACETYLAMINO-5-NITROTHIAZOLE(140-40-9):

2-ACETYLAMINO-5-NITROTHIAZOLE Toxicity Data With Reference

1.   

mmo-sat 500 nmol/L

   MUREAV    Mutation Research. 118 (1983),153.
2.   

mmo-esc 20 µmol/L

   MUREAV    Mutation Research. 118 (1983),153.
3.   

mmo-klp 20 µmol/L

   MUREAV    Mutation Research. 118 (1983),153.
4.   

mrc-smc 200 ppm

   MUREAV    Mutation Research. 118 (1983),153.
5.   

orl-rat LD50:>400 mg/kg

   ANTCAO    Antibiotics and Chemotherapy. 5 (1955),540.
6.   

ipr-rat LD50:>200 mg/kg

   ANTCAO    Antibiotics and Chemotherapy. 5 (1955),540.
7.   

scu-rat LD:>3200 mg/kg

   ANTCAO    Antibiotics and Chemotherapy. 5 (1955),540.
8.   

orl-mus LD50:1 g/kg

   FRPSAX    Farmaco, Edizione Scientifica. 19 (1964),301.
9.   

ipr-mus LD50:>300 mg/kg

   ANTCAO    Antibiotics and Chemotherapy. 5 (1955),540.
10.   

scu-mus LD:>3200 mg/kg

   ANTCAO    Antibiotics and Chemotherapy. 5 (1955),540.
11.   

orl-dog LD50:125 mg/kg

   ANTCAO

2-ACETYLAMINO-5-NITROTHIAZOLE Safety Profile

Poison by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of SOx and NOx.
Hazard Codes: Xn
Risk Statements: 22: Harmful if swallowed 
Safety Statements: 22-36/37
22:  Do not breathe dust 
36/37:  Wear suitable protective clothing and gloves 
RTECS: XJ1570000
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