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2-Amino-4-Methylbenzoic Acid

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Name

2-Amino-4-Methylbenzoic Acid

EINECS 218-976-3
CAS No. 2305-36-4 Density 1.254 g/cm3
PSA 63.32000 LogP 1.85660
Solubility N/A Melting Point 174-177 ºC
Formula C8H9 N O2 Boiling Point 329.8 °C at 760 mmHg
Molecular Weight 151.165 Flash Point 153.3 °C
Transport Information N/A Appearance white crystalline powder
Safety S26;S37/39 Risk Codes R36/37/38   
Molecular Structure Molecular Structure of 2305-36-4 (2-Amino-4-methylbenzoic acid) Hazard Symbols
Synonyms

p-Toluicacid, 2-amino- (6CI,7CI,8CI); 2-Amino-4-methylbenzoic acid; 2-Amino-p-toluicacid; 4-Methylanthranilic acid; NSC 39155

Article Data 26

2-Amino-4-Methylbenzoic Acid Synthetic route

27329-27-7

4-methyl-2-nitrobenzoic acid

2305-36-4

4-methylanthranilic acid

Conditions
ConditionsYield
With palladium 10% on activated carbon; hydrogen In ethanol at 20℃; under 760.051 Torr;100%
With platinum (IV) oxide; hydrogen In methanol for 3h;98%
With palladium on activated carbon; hydrogen In ethyl acetate at 20℃; for 14h; Saturated gas;95%
With hydrogenchloride; tin
With iron(III) chloride; hydrazine hydrate; sodium hydroxide In water at 70℃; for 1h; Temperature;
7697-27-0

2-bromo-4-methylbenzoic acid

2305-36-4

4-methylanthranilic acid

Conditions
ConditionsYield
With ammonium hydroxide; L-2-O-methyl-chiro-inositol; copper(II) acetate monohydrate In 1-methyl-pyrrolidin-2-one at 110℃; for 12h;87%
89-58-7

mononitro-p-xylene

2305-36-4

4-methylanthranilic acid

Conditions
ConditionsYield
With selenium; nitrobenzene; sodium hydroxide In methanol; water; dimethyl sulfoxide at 90℃; for 5h; Inert atmosphere;70%
53078-85-6

2-bromo-5-methylaniline

2305-36-4

4-methylanthranilic acid

Conditions
ConditionsYield
With tert.-butyl lithium In hydrogenchloride; diethyl ether; water; pentane59%
1128-47-8

6-methylindoline-2,3-dione

2305-36-4

4-methylanthranilic acid

Conditions
ConditionsYield
With sodium hydroxide; dihydrogen peroxide
33900-96-8

7-methyl-3-m-tolyl-1H-quinazoline-2,4-dione

2305-36-4

4-methylanthranilic acid

Conditions
ConditionsYield
With potassium hydroxide
39549-79-6

2-amino-4-methylbenzamide

2305-36-4

4-methylanthranilic acid

Conditions
ConditionsYield
With potassium hydroxide
26830-96-6

5-methyl-2-cyanoaniline

2305-36-4

4-methylanthranilic acid

Conditions
ConditionsYield
With potassium hydroxide
67-56-1

methanol

1128-47-8

6-methylindoline-2,3-dione

A

18595-17-0

methyl 4-methylanthranilate

B

2305-36-4

4-methylanthranilic acid

Conditions
ConditionsYield
With dihydrogen peroxide; sodium methylate 1.) 0-10 deg C 2.) room temperature, 30 min; Yield given. Multistep reaction;
1128-47-8

6-methylindoline-2,3-dione

7722-84-1

dihydrogen peroxide

furan-2,3,5(4H)-trione pyridine (1:1)

2305-36-4

4-methylanthranilic acid

2-Amino-4-Methylbenzoic Acid Chemical Properties

Molecular Formula: C8H9NO2
Molar mass:151.16256 g/mol
Structure of 2-Amino-4-methylbenzoic acid(2305-36-4):
                                       
Synonyms of2-Amino-4-methylbenzoic acid(2305-36-4):Benzoic acid, 2-amino-4-methyl-;4-METHYLANTHRANILIC ACID;Benzoic acid, 2-amino-4-methyl- (9CI)
Melting point:174-177 oC
Density:1.254 g/cm3
Flash Point:153.3 °C
Boiling Point: 329.8 °C at 760 mmHg

2-Amino-4-Methylbenzoic Acid Safety Profile

Hazard Codes:Xi
Risk Statements:
36:  Irritating to the eyes
37:  Irritating to the respiratory system
38:  Irritating to the skin 
Safety Statements:  
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
37:  Wear suitable gloves
39:  Wear eye/face protection

2-Amino-4-Methylbenzoic Acid Specification

Product Categories of 2-Amino-4-methylbenzoic acid(2305-36-4):CARBOXYLICACID;Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts;Carboxylic Acids;Carboxylic Acids;Phenyls & Phenyl-Het;Benzoic acid;Phenyls & Phenyl-Het;API intermediates
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