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Cas Database

Name	3'-Aminoacetophenone	EINECS	202-722-3
CAS No.	99-03-6	Density	1.096 g/cm³
PSA	43.09000	LogP	2.05260
Solubility	7.056g/L(37.5 oC)	Melting Point	94-98 °C(lit.)
Formula	C₈H₉NO	Boiling Point	290.3 °C at 760 mmHg
Molecular Weight	135.166	Flash Point	129.4 °C
Transport Information	N/A	Appearance	yellow to light brown crystalline powder
Safety	36/37-36-26	Risk Codes	22-36/37/38
Molecular Structure		Hazard Symbols	Xn,Xi
Synonyms	Acetophenone,3'-amino- (8CI);1-(3-Aminophenyl)ethanone;1-Acetyl-3-aminobenzene;3-Acetylaniline;3-Acetylphenylamine;3-Methylcarbonylaniline;NSC 7637;m-Acetylaniline;m-Aminoacetophenone;b-Aminoacetophenone;3-Aminoacetophenone;	Article Data	158

3'-Aminoacetophenone Synthetic route

: 121-89-1
3-Nitroacetophenone

: 99-03-6
1-(3-aminophenyl)ethanone

Conditions

Conditions	Yield
With cadmium sulphide; ammonium formate In water at 20℃; for 14h; Inert atmosphere; Irradiation; Sealed tube; chemoselective reaction;	100%
With water; oxalic acid; titanium(IV) oxide for 3h; Wavelength; Irradiation; Inert atmosphere; Sealed tube; Green chemistry; chemoselective reaction;	100%
With hydrogen In methanol at 70℃; under 3750.38 - 7500.75 Torr; for 4h; Temperature; Reagent/catalyst; Solvent;	99%

: 54060-30-9
3-acetylenephenylamine

: 99-03-6
1-(3-aminophenyl)ethanone

Conditions

Conditions	Yield
With silver hexafluoroantimonate In methanol; water at 120℃; for 24h; Sealed tube;	97%
With C22H20AuN3O2P(1+)*CF3O3S(1-); water; silver trifluoromethanesulfonate; acetic acid at 100℃; for 10h;	91%
With water at 200℃; for 0.333333h; microwave irradiation;	90%

: 94066-64-5
bis-(3-acetyl-phenyl)-diazene

: 99-03-6
1-(3-aminophenyl)ethanone

Conditions

Conditions	Yield
With zinc; hydrazinium monoformate In methanol for 0.1h; Heating;	93%
With ammonium formate; magnesium In methanol at 20℃; for 0.15h;	91%
With ammonium chloride; zinc In methanol at 20℃; for 0.2h;	91%

: 121-89-1
3-Nitroacetophenone

A: 99-03-6
1-(3-aminophenyl)ethanone

B: 75-07-0
acetaldehyde

C H2: H2

Conditions

Conditions	Yield
With ethanol; titanium(IV) oxide for 0.25h; Irradiation;	A 92% B n/a C n/a

: 998-39-0
tributylgermanium hydride

: 70334-60-0
3-(azidophenyl) methyl ketone

A: 1-(3-amino-2-tributylgermanyl-phenyl)-ethanone

B: 1-(3-amino-4-tributylgermanyl-phenyl)-ethanone

C: 99-03-6
1-(3-aminophenyl)ethanone

Conditions

Conditions	Yield
With thiophenol In toluene for 0.5h; Heating;	A 1% B 2% C 92%

: 2142-63-4
1-(3-Bromophenyl)ethanone

: 99-03-6
1-(3-aminophenyl)ethanone

Conditions

Conditions	Yield
With copper(I) oxide; ammonium hydroxide In 1-methyl-pyrrolidin-2-one at 80℃; for 15h;	92%
With copper(I) oxide; ammonium hydroxide; N1-(furan-2-ylmethyl)-N2-(2-methylnaphthalen-1-yl)oxalamide; potassium hydroxide In ethanol at 80℃; for 24h; Schlenk technique; Inert atmosphere;	64%
Stage #1: 1-(3-Bromophenyl)ethanone With copper(l) iodide; D-glucosamine hydrochloride; potassium carbonate In water; acetone at 90℃; for 0.166667h; Stage #2: With ammonia In water; acetone at 90℃; for 30h;	62%

: [3-(2-methyl-[1,3]dioxolan-2-yl)-phenyl]-carbamic acid 2,2,2-trichloro-ethyl ester

: 99-03-6
1-(3-aminophenyl)ethanone

Conditions

Conditions	Yield
With indium; ammonium chloride In ethanol for 2.5h; Heating;	91%

: 151224-49-6
(E)-1,1'-(diazene-1,2-diyl)bis(1,3-phenylene)bis(ethan-1-one)

: 99-03-6
1-(3-aminophenyl)ethanone

Conditions

Conditions	Yield
With nickel; hydrazinium monoformate In methanol for 0.15h; Heating;	90%

: 70334-60-0
3-(azidophenyl) methyl ketone

: 99-03-6
1-(3-aminophenyl)ethanone

Conditions

Conditions	Yield
With samarium diiodide In tetrahydrofuran for 1.25h; Ambient temperature;	89%
With tellurium; water at 275℃; for 4h;	89%
With ammonium formate; copper In water for 8h; Reflux; chemoselective reaction;	84%

: 3-acetylphenylboronic acid

: 99-03-6
1-(3-aminophenyl)ethanone

Conditions

Conditions	Yield
With N-Bromosuccinimide; CYANAMID; bis-[(trifluoroacetoxy)iodo]benzene In acetonitrile at 20℃; for 1h; Reagent/catalyst; chemoselective reaction;	87%
With N-Bromosuccinimide; N-methoxylamine hydrochloride; bis-[(trifluoroacetoxy)iodo]benzene In acetonitrile at 20℃;	78%

3'-Aminoacetophenone Chemical Properties

Molecular Formula: C₈H₉NO
Molecular Weight: 135.16
Melting point: 95-98 ^oC
Boiling point: 289-290 ^oC
Color: Brown.
pH (1% soln/WATER): Basic.
Solubility:
Soluble in methanol, diethyl ether.
Insoluble in cold WATER, hot WATER.

3'-Aminoacetophenone Uses

3-amino acetophenone is used in synthesizing adrianol drugs, hypnotic; also used as material for organic synthesis etc.

3'-Aminoacetophenone Toxicity Data With Reference

Toxicological Data on Ingredients: 3-Aminoacetophenone: ORAL (LD50): Acute: 1870 mg/kg [Rat.]. DERMAL (LD50):
Acute: 4340 mg/kg [Rabbit.].

Hazardous in case of eye contact (irritant), of inhalation. Slightly hazardous in case of skin contact (irritant,permeator), of ingestion.

Toxicity of 3-amino acetophenone of Biodegradation: 3-amino acetophenone of degradation are more toxic.

3'-Aminoacetophenone Safety Profile

Hazard Symbols: Xn
Risk Codes: R22

3'-Aminoacetophenone Standards and Recommendations

Main content(wt%): ≥99.0%
2'-AMINOACETOPHENONE(wt%): ≤0.2%
Other(wt%): ≤0.3%

3'-Aminoacetophenone Specification

Conditions to Avoid: Incompatible materials, strong oxidants.
Incompatibilities with Other Materials: Strong oxidizing agents, strong reducing agents, acids, acid anhydrides, chloroformates, acid chlorides.
Hazardous Decomposition Products: NITROGEN oxides, CARBON monoxide, CARBON dioxide.

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